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US4568482A
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Process for making electrically conducting polymers and polymers made by such process
Assignee: Honeywell Inc
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Filing: 1983-08-23
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Granted: 1986-02-04
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Expires: 2003-08-23
Abstract
Abstract A one-step process for synthesizing electrically conducting polymers of iodine doped poly N-alkylcarbazoles is disclosed together with the conducting polymers made by the process.
Inventors
- 👤 Samson A. Jenekhe
- 👤 Barbara J. Fure
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 15:09
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/06; H01B1/12; H01B1/124; H01B1/127; C; C08; C08G; C08G61/00; C08G61/12; C08G61/122; C08G61/123; C08G61/124; H01B1/128
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
177 words
A one-step process for making solid electrically conducting organic polymers comprising the steps of: combining an amount of a monomer selected from a group consisting of N-alkyl carbazole and N-alkyldihalocarbazole monomers or combination thereof of the general formula ##STR3## where R is H or CH 3 , X is H and both Y's are Br or I, or Y is H and both X's are Br or I, with an amount of I 2 wherein said I 2 functions as a charge transfer acceptor dopant and heating said combination to form a liquid melt solution thereof; wherein the concentration of said monomers in said melt solution is in the range of 1% to 60% by weight and wherein the concentration of said I 2 is from about 99% to 40% by weight; polymerizing and chemically doping the monomer in said melt solution at a temperature between 80° C. and 200° for a time sufficient to produce the degree of polymerization desired at the temperature selected using an atmosphere selected from inert gas, air, or a partial vacuum.
Claim 2
Dependent Claim
177 words
A one-step process for making solid electrically conducting organic polymers comprising the steps of: combining an amount of a monomer selected from a group consisting of N-alkyl carbazole and N-alkyldihalocarbazole monomers or combination thereof of the general formula ##STR3## where R is H or CH 3 , X is H and both Y's are Br or I, or Y is H and both X's are Br or I, with an amount of I 2 wherein said I 2 functions as a charge transfer acceptor dopant and heating said combination to form a liquid melt solution thereof; wherein the concentration of said monomers in said melt solution is in the range of 1% to 60% by weight and wherein the concentration of said I 2 is from about 99% to 40% by weight; polymerizing and chemically doping the monomer in said melt solution at a temperature between 80° C. and 200° for a time sufficient to produce the degree of polymerization desired at the temperature selected using an atmosphere selected from inert gas, air, or a partial vacuum.
Claim 3
Dependent Claim
42 words
The process of claim 1 wherein said N-alkyl carbazole is one selected from the group consisting of carbazole and N-methyl carbazole and wherein said N-alkyldihalocarbazole is one wherein R is H or CH 3 , Y is H and X is Br.
Claim 4
Dependent Claim
44 words
The process of claim 1 wherein said n-alkyl carbazole is one selected from the group consisting of carbazole and N-methyl carbazole and wherein said N-alkyldihalocarbazole is one wherein R is H or CH 3 , Y is H and X is I 2 .
Claim 5
Dependent Claim
13 words
The process of claim 1 wherein said electrically conducting polymer is a copolymer.
Claim 6
Dependent Claim
13 words
The process of claim 2 wherein said electrically conducting polymer is a copolymer.
Claim 7
Dependent Claim
13 words
The process of claim 3 wherein said electrically conducting polymer is a copolymer.
Claim 8
Dependent Claim
13 words
The process of claim 1 wherein said electrically conducting polymer is a homopolymer.
Claim 9
Dependent Claim
13 words
The process of claim 2 wherein said electrically conducting polymer is a homopolymer.
Claim 10
Dependent Claim
13 words
The process of claim 3 wherein said electrically conducting polymer is a homopolymer.
Claim 11
Dependent Claim
14 words
The process of claim 1 wherein said heating takes place in an air atmosphere.
Claim 12
Dependent Claim
16 words
The process of claim 1 wherein said heating takes place in an atmosphere of inert gas.
Claim 13
Dependent Claim
27 words
The process of claim 1 wherein said mixture is heated and polymerized on a substrate such that a film of said polymer is formed on the substrate.
Claim 14
Dependent Claim
21 words
The process of claim 1 further comprising the step of drawing fibers of the electrically conducting polymer directly from said melt.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-02-03 | 1989-08-05 | 1990-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-02-03 | 1993-08-05 | 1994-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-02-03 | 1997-08-05 | 1998-02-04 | $7700.00 | Window Closed / Lapsed |