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US4568140A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical element comprising a transparent substrate and an antireflection coating for the near-infrared region of wavelengths

Assignee: US Philips Corp
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Filing: 1983-09-12
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Granted: 1986-02-04
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Expires: 2003-09-12
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Abstract

Abstract An optical element comprises a transparent substrate. An antireflection coating is provided on the substrate for reducing reflections of wavelengths from approximately 700 nm to approximately 1700 nm. The coating comprises a plurality of stacked, uniform layers with refractive indices which decrease toward the top of the stack. A base coating is arranged between the layer stack and the substrate. The effective refractive index at the top of the base coating is at least 2.5, and the base coating is a graded index layer.

Inventors

  • 👤 Pieter van der Werf
  • 👤 Jan Haisma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 04:53
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/34; C03C17/3411; C03C17/3429; G; G02; G02B; G02B1/00; G02B1/10; G02B1/11; G02B1/113; G02B1/115

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 137 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the effective refractive index at the top surface of the base coating being at least 2.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating.
Claim 2
Dependent Claim 137 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the effective refractive index at the top surface of the base coating being at least 2.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating.
Claim 3
Dependent Claim 52 words
An antireflection coating as claimed in claim 1, characterized in that: the base coating is a single layer with a refractive index of at least 2.5 at the top surface thereof; and the top coating comprises three homogeneous layers, each layer having an optical thickness equal to one-quarter of a reference wavelength.
Claim 4
Dependent Claim 160 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of Si and Si 3 N 4 .
Claim 5
Dependent Claim 160 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of Si and Si 3 N 4 .
Claim 6
Dependent Claim 129 words
An antireflection coating as claimed in claim 3, characterized in that: the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 7
Dependent Claim 163 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of Si, Si 3 N 4 , and SiO 2 .
Claim 8
Dependent Claim 163 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of Si, Si 3 N 4 , and SiO 2 .
Claim 9
Dependent Claim 129 words
An antireflection coating as claimed in claim 5, characterized in that: the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 10
Dependent Claim 156 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, and base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of GaP and GaN.
Claim 11
Dependent Claim 156 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, and base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of GaP and GaN.
Claim 12
Dependent Claim 129 words
An antireflection coating as claimed in claim 7, characterized in that: the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 13
Dependent Claim 161 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of GaP, GaN, and Ga 2 O 3 .
Claim 14
Dependent Claim 161 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of GaP, GaN, and Ga 2 O 3 .
Claim 15
Dependent Claim 129 words
An antireflection coating as claimed in claim 9, characterized in that the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 16
Dependent Claim 156 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of PbS and ZnS.
Claim 17
Dependent Claim 156 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of PbS and ZnS.
Claim 18
Dependent Claim 129 words
An antireflection coating as claimed in claim 11, characterized in that: the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 19
Dependent Claim 159 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of PbS, ZnS, and a B-Na-Al-K glass.
Claim 20
Dependent Claim 159 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating consisting of a single layer having a bottom surface against the substrate and having a top surface remote from the substrate, said base coating having a graded refractive index between the top and bottom surfaces, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate, the refractive index at the top surface of the base coating being at least 3.5; and a top coating on the top of the base coating, said top coating having a plurality of homogeneous layers having refractive indices which decrease toward the top of the top coating; characterized in that the base coating consists essentially of a mixture of PbS, ZnS, and a B-Na-Al-K glass.
Claim 21
Dependent Claim 129 words
An antireflection coating as claimed in claim 13, characterized in that: the top coating comprises first, second, and third homogeneous layers, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; the first layer has a refractive index of 1.38 and consists essentially of MgF 2 ; the second layer has a refractive index of 2.2 and consists essentially of one of the materials from the group of Nb 2 O 5 , TiN, Ta 2 O 5 , and Sb 2 O 3 ; and the third layer has a refractive index of 3.1 and consists essentially of one of the materials from the group of AlSb, amorphous Sb 2 S 3 , and a mixture of Si and Si 3 N 4 .
Claim 22
Dependent Claim 195 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating having a bottom surface against the substrate and having a top surface remote from the substrate; and a top coating on the top of the base coating, said top coating having first, second, and third homogeneous layers having refractive indices which decrease toward the top of the top coating, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; characterized in that the base coating comprises: a first inhomogeneous layer on the substrate, said layer having a graded refractive index which decreases from the bottom surface to the top surface, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate; and at least first and second homogeneous layers on the inhomogeneous layer, said layers having refractive indices which increase toward the top of the base coating; wherein the effective refractive index at the top of the base coating is at least 2.5.
Claim 23
Dependent Claim 195 words
An antireflection coating on a transparent substrate having an index of refraction, said coating suppressing reflections of wavelengths from approximately 700 nanometers to approximately 1700 nanometers, said antireflection coating comprising: a base coating on the substrate, said base coating having a bottom surface against the substrate and having a top surface remote from the substrate; and a top coating on the top of the base coating, said top coating having first, second, and third homogeneous layers having refractive indices which decrease toward the top of the top coating, each layer having an optical thickness approximately equal to one-quarter of a reference wavelength; characterized in that the base coating comprises: a first inhomogeneous layer on the substrate, said layer having a graded refractive index which decreases from the bottom surface to the top surface, the refractive index of the base coating at the bottom surface being equal to the refractive index of the substrate; and at least first and second homogeneous layers on the inhomogeneous layer, said layers having refractive indices which increase toward the top of the base coating; wherein the effective refractive index at the top of the base coating is at least 2.5.
Claim 24
Dependent Claim 185 words
An antireflection coating as claimed in claim 15, characterized in that in sequence from the top to the bottom of the antireflection coating: the first layer of the top coating has a refractive index of 1.39, has an optical thickness equal to one-quarter of the reference wavelength, and consists essentially of MgF 2 ; the second layer of the top coating has a refractive index of 2.08, has an optical thickness equal to one-quarter of the reference wavelength, and consists essentially of Nb 2 O 5 ; the third layer of the top coating has a refractive index of 2.52, has an optical thickness equal to 0.31 times the reference wavelength, and consists essentially of CdS; the first homogeneous layer of the base coating has a refractive index of 2.08, has an optical thickness equal to one-quarter of the reference wavelength, and consists essentially of Nb 2 O 5 ; and the second homogeneous layer of the base coating has a refractive index of 1.65, has an optical thickness equal to one-quarter of the reference wavelength, and consists essentially of Al 2 O 3 .

References Cited (Backward Citations)

US3804491A Cited
GB1380793A Cited
GB1406567A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-03 1989-08-05 1990-02-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-03 1993-08-05 1994-02-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-03 1997-08-05 1998-02-04 $7700.00 Window Closed / Lapsed

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