US4565679A
Expired / Lapsed
US
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Method of regulating the amount of reducing agent added during catalytic reduction of NOx contained in flue gases
Assignee: L & C STEINMULLER FABRIKSTRASSE 1 D-5270 GUMMERSBACH GERMANY GmbH
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Filing: 1984-10-17
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Granted: 1986-01-21
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Expires: 2004-10-17
Abstract
Abstract A method of regulating the amount of reducing agent added, especially NH 3 in the case of the catalytic reduction of NO x of flue gases which originate from a combustion installation which is fired with fossil fuels. The adjustment value for the quantity to be added is determined in response to a prescribed reducing agent/NO x stoichiometry factor from the quantity of combustion air supplied to the combustion installation or from the exiting quantity of flue gas, and from the NO x concentration downstream ahead of the catalyzer. Regulation is effected by influencing the stoichiometry factor. The NO x concentration downstream after the catalyzer is returned to the regulation process as the primary correction value, and the reducing agent concentration downstream after the catalyzer, and the flue gas temperature ahead of the catalyzer, are returned to the regulation process as the secondary correction values. The set stoichiometry factor is influenced such that while maintaining the emission limit value as the desired value of the primary correction value, and while maintaining a reducing agent concentration downstream after the catalyzer below a prescribed fixed value in a range of from 50 to 3 ppm volume, preferably less than 10 ppm volume, the stoichiometry factor is regulated via the temperature-dependent activity curve of the catalyzer.
Inventors
- 👤 Stanislaw Michalak
- 👤 Klaus-Dieter Weber
- 👤 Jurgen Meier
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 22:48
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8696; B01D53/8621; B01D53/8625
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
182 words
In a process of regulating the amount of reducing agent added during the catalytic reduction of NO x of flue gases originating from the combustion installation fired with fossil fuels with which an adjustment value to be used for regulation of a quantity of reducing agent to be added is determined selectively, in response to a prescribed reducing agent/NO x stoichiometry factor, from the quantity of combustion air supplied to the combustion installation, as well as from the quantity of exiting flue gas, plus the NO x concentration downstream ahead of the catalyzer; the improvement therewith which includes the steps of: returning to the regulation process, as a primary correction value, the value of the NO x concentration downstream after said catalyzer; returning to the regulation process, as a secondary correction value, the reducing agent concentration downstream after said catalyzer; and while maintaining the NO x emission limit value, appropriately changing said stoichiometry factor in such a way as to regulate an excess of not-reacted reducing agent after said catalyzer over a prescribed fixed value of from 50 to 3 ppm volume.
Claim 2
Dependent Claim
182 words
In a process of regulating the amount of reducing agent added during the catalytic reduction of NO x of flue gases originating from the combustion installation fired with fossil fuels with which an adjustment value to be used for regulation of a quantity of reducing agent to be added is determined selectively, in response to a prescribed reducing agent/NO x stoichiometry factor, from the quantity of combustion air supplied to the combustion installation, as well as from the quantity of exiting flue gas, plus the NO x concentration downstream ahead of the catalyzer; the improvement therewith which includes the steps of: returning to the regulation process, as a primary correction value, the value of the NO x concentration downstream after said catalyzer; returning to the regulation process, as a secondary correction value, the reducing agent concentration downstream after said catalyzer; and while maintaining the NO x emission limit value, appropriately changing said stoichiometry factor in such a way as to regulate an excess of not-reacted reducing agent after said catalyzer over a prescribed fixed value of from 50 to 3 ppm volume.
Claim 3
Dependent Claim
37 words
A process according to claim 1, which includes the step of changing said stoichiometry factor in such a way as to regulate an excess of not-reacted reducing agent after said catalyzer to less than 10 ppm volume.
Claim 4
Dependent Claim
211 words
In a process of regulating the amount of reducing agent added during the catalytic reduction of NO x of flue gases originating from a combustion installation fired with fossil fuels with which an adjustment value to be used for regulation of a quantity of reducing agent to be added is determined selectively, in response to a prescribed reducing agent/NO x stoichiometry factor, from the quantity of combustion air supplied to the combustion installation, as well as from the quantity of exiting flue gas, plus the NO x concentration downstream ahead of the catalyzer; the improvement therewith which includes the steps of: returning to the regulation process, as a primary correction value, the value of the NO x concentration downstream after said catalyzer; returning to the regulation process, as secondary correction values, the reducing agent concentration downstream after said catalyzer, and the flue gas temperature ahead of said catalyzer; and influencing the set stoichiometry factor in such a way that, while maintaining the NO x emission limit value as the desired value of the primary correction value, and while maintaining a reducing agent concentration downstream after said catalyzer below a prescribed fixed value ranging from 50 to 3 ppm volume, said factor is regulated via the temperature-dependent activity curve of said catalyzer.
Claim 5
Dependent Claim
211 words
In a process of regulating the amount of reducing agent added during the catalytic reduction of NO x of flue gases originating from a combustion installation fired with fossil fuels with which an adjustment value to be used for regulation of a quantity of reducing agent to be added is determined selectively, in response to a prescribed reducing agent/NO x stoichiometry factor, from the quantity of combustion air supplied to the combustion installation, as well as from the quantity of exiting flue gas, plus the NO x concentration downstream ahead of the catalyzer; the improvement therewith which includes the steps of: returning to the regulation process, as a primary correction value, the value of the NO x concentration downstream after said catalyzer; returning to the regulation process, as secondary correction values, the reducing agent concentration downstream after said catalyzer, and the flue gas temperature ahead of said catalyzer; and influencing the set stoichiometry factor in such a way that, while maintaining the NO x emission limit value as the desired value of the primary correction value, and while maintaining a reducing agent concentration downstream after said catalyzer below a prescribed fixed value ranging from 50 to 3 ppm volume, said factor is regulated via the temperature-dependent activity curve of said catalyzer.
Claim 6
Dependent Claim
26 words
A process according to claim 3, in which said influencing step includes maintaining said reducing agent concentration after said catalyzer below less than 10 ppm volume.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-01-20 | 1989-07-22 | 1990-01-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-20 | 1993-07-22 | 1994-01-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-20 | 1997-07-22 | 1998-01-21 | $7700.00 | Window Closed / Lapsed |