Naphthoquinone redox dye-releasers

Claim 2

In a photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer, said emulsion layer having associated therewith a nondiffusible, positive-working, redox dye-releaser compound capable of releasing at least one diffusible dye moiety, the improvement wherein said compound has the formula: ##STR12## wherein: (a) R 1 represents a substituted or unsubstituted alkyl group of from 1 to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms, (b) R 2 and R 3 each independently represents hydrogen or R 1 ; (c) E represents carbonyl or thiocarbonyl; (d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and (e) Dye represents a diffusible dye moiety or precursor thereof; with the proviso that at least one of R 1 , R 2 and R 3 is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition.

Claim 3

The photographic element of claim 1 wherein R 1 is said ballasting radical and R 3 is aryl.

Claim 4

The photographic element of claim 2 wherein R 1 is a substituted or unsubstituted alkyl group of at least about 12 carbon atoms and R 3 is phenyl.

Claim 5

The photographic element of claim 1 wherein Q is nitrogen, oxygen, sulfur or selenium.

Claim 6

The photographic element of claim 1 wherein Q is oxygen.

Claim 7

The photographic element of claim 1 where R 2 is hydrogen and E is carbonyl.

Claim 8

The photographic element of claim 1 wherein R 1 is said ballasting radical and comprises a substituted or unsubstituted alkyl group of at least about 12 carbon atoms, R 2 is hydrogen, R 3 is phenyl, E is carbonyl and Q is oxygen.

Claim 9

The photographic element of claim 1 wherein Dye represents an azo dye moiety.

Claim 10

The photographic element of claim 1 wherein said silver halide emulsion is negative-working and said element contains an incorporated reducing agent.

Claim 11

The photographic element of claim 1 wherein said support has thereon a dye image-receiving layer, an opaque reflecting layer, an opaque absorbing layer, and negative-working, red-, green-, and blue-sensitive silver halide emulsion layers having associated therewith, respectively, cyan, magenta and yellow positive-working, redox dye-releasers.

Claim 12

The photographic element of claim 1 wherein said compound is ##STR13##

Claim 13

The photographic element of claim 1 wherein said compound is ##STR14##

Claim 14

In a photographic assemblage to be processed with an alkaline processing composition comprising: (a) a photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer having associated therewith a nondiffusible, positive-working, redox dye-releaser capable of releasing at least one diffusible dye moiety; and (b) a dye image-receiving layer; the improvement wherein said compound has the formula: ##STR15## wherein: (a) R 1 represents a substituted or unsubstituted alkyl group of from 1 to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms; (b) R 2 and R 3 each independently represents hydrogen or R 1 ; (c) E represents carbonyl or thiocarbonyl; (d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and (e) Dye represents a diffusible dye moiety or precursor thereof; with the proviso that at least one of R 1 , R 2 and R 3 is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition.

Claim 15

In a photographic assemblage to be processed with an alkaline processing composition comprising: (a) a photographic element comprising a support having thereon at least one photosensitive silver halide emulsion layer having associated therewith a nondiffusible, positive-working, redox dye-releaser capable of releasing at least one diffusible dye moiety; and (b) a dye image-receiving layer; the improvement wherein said compound has the formula: ##STR15## wherein: (a) R 1 represents a substituted or unsubstituted alkyl group of from 1 to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms; (b) R 2 and R 3 each independently represents hydrogen or R 1 ; (c) E represents carbonyl or thiocarbonyl; (d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and (e) Dye represents a diffusible dye moiety or precursor thereof; with the proviso that at least one of R 1 , R 2 and R 3 is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition.

Claim 16

The assemblage of claim 13 which also contains an alkaline processing composition and means containing same for discharge within said assemblage.

Claim 17

The assemblage of claim 14 wherein R 1 is said ballasting radical and R 3 is aryl.

Claim 18

The assemblage of claim 15 wherein R 1 is a substituted or unsubstituted alkyl group of at least about 12 carbon atoms and R 3 is phenyl.

Claim 19

The assemblage of claim 14 wherein R 1 is said ballasting radical and comprises a substituted or unsubstituted alkyl group of at least about 12 carbon atoms, R 2 is hydrogen, R 3 is phenyl, E is carbonyl and Q is oxygen.

Claim 20

The assemblage of claim 14 wherein Dye represents an azo dye moiety.

Claim 21

The assemblage of claim 14 wherein said dye image-receiving layer is located between said support and said silver halide emulsion layer.

Claim 22

The assemblage of claim 19 where a stripping layer is located between said dye image-receiving layer and said silver halide emulsion layer.

Claim 23

The assemblage of claim 20 which also contains a transparent cover sheet which is coated with, in sequence, a neutralizing layer and a timing layer.

Claim 24

The assemblage of claim 21 wherein said discharging means is a rupturable container containing said alkaline processing composition and an opacifying agent, said container being so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said cover sheet and the layer outermost from said support.

Claim 25

The assemblage of claim 14 wherein said support having thereon said silver halide emulsion layer is opaque, and said dye image-receiving layer is located on a separate dye image-receiving element.

Claim 26

The assemblage of claim 23 wherein said dye image-receiving element has thereon, in sequence, a neutralizing layer, a timing layer, and said dye image-receiving layer.

Claim 27

The assemblage of claim 23 wherein said opaque support has thereon, in sequence, a neutralizing layer, a timing layer and said silver halide emulsion layer.

Claim 28

In an integral photographic assemblage comprising: (a) a photographic element comprising a transparent support having thereon the following layers in sequence: a dye image-receiving layer; a stripping layer, an alkaline solution-permeable, light-reflective layer; an alkaline solution-permeable, opaque absorbing layer; a red-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, cyan redox dye-releaser compound associated therewith; a green-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, magenta redox dye-releaser compound associated therewith; and a blue-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, yellow redox dye-releaser compound, associated therewith; (b) a transparent cover sheet superposed over said blue-sensitive silver halide emulsion layer and comprising a transparent support coated with, in sequence, a neutralizing layer and a timing layer; and (c) a rupturable container containing an alkaline processing composition including an electron transfer agent and an opacifying agent, said container being so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said transparent sheet and said blue-sensitive silver halide emulsion layer; the improvement wherein each said compound has the formula: ##STR16## wherein: (a) R 1 represents a substituted or unsubstituted alkyl group of from 1 ; to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms, (b) R 2 and R 3 each independently represents hydrogen or R 1 ; (c) E represents carbonyl or thiocarbonyl; (d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and (e) Dye represents a diffusible dye moiety or precursor thereof; with the proviso that at least one of R 1 , R 2 and R 3 is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition.

Claim 29

In an integral photographic assemblage comprising: (a) a photographic element comprising a transparent support having thereon the following layers in sequence: a dye image-receiving layer; a stripping layer, an alkaline solution-permeable, light-reflective layer; an alkaline solution-permeable, opaque absorbing layer; a red-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, cyan redox dye-releaser compound associated therewith; a green-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, magenta redox dye-releaser compound associated therewith; and a blue-sensitive, negative-working, silver halide emulsion layer having a nondiffusible, positive-working, yellow redox dye-releaser compound, associated therewith; (b) a transparent cover sheet superposed over said blue-sensitive silver halide emulsion layer and comprising a transparent support coated with, in sequence, a neutralizing layer and a timing layer; and (c) a rupturable container containing an alkaline processing composition including an electron transfer agent and an opacifying agent, said container being so positioned during processing of said assemblage that a compressive force applied to said container will effect a discharge of the container's contents between said transparent sheet and said blue-sensitive silver halide emulsion layer; the improvement wherein each said compound has the formula: ##STR16## wherein: (a) R 1 represents a substituted or unsubstituted alkyl group of from 1 ; to about 30 carbon atoms or a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms, (b) R 2 and R 3 each independently represents hydrogen or R 1 ; (c) E represents carbonyl or thiocarbonyl; (d) Q represents a nonmetallic atom of Group VA or VIA of the periodic table in its minus 2 or minus 3 valence state; and (e) Dye represents a diffusible dye moiety or precursor thereof; with the proviso that at least one of R 1 , R 2 and R 3 is an organic ballasting radical of such molecular size and configuration as to render said compound nondiffusible in said photographic element during development in an alkaline processing composition.