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US4563285A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for dewatering phosphate slimes

Assignee: Columbia University
•
Filing: 1984-08-09
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Granted: 1986-01-07
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Expires: 2004-08-09
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Abstract

Abstract A method for dewatering phosphate slimes and recovering a liquid solution involves adding a calcium sulfate hemihydrate to the slimes, mixing the resulting admixture to effect formation of calcium sulfate dihydrate crystals in the admixture, and recovering a liquid solution from the resulting crystal-containing admixture. The calcium sulfate hemihydrate addition may be followed by addition of calcium sulfate dihydrate. The calcium sulfate hemihydrate addition may be preceded by acidification of the slimes to pH 1-3 with sulfuric acid, which addition may be followed by the addition of other calcium salts to the slimes. A sufficient amount of calcium oxide or calcium carbonate or both may be added to the recovered liquid solution to raise the pH of the liquid solution to a value above about 6.0. Mixing permits calcium phosphate salts to precipitate, allowing for separately recovering the calcium phosphate salts and a dephosphated liquid portion.

Inventors

  • 👤 Krishnapillai V. Nair
  • 👤 Ponisseril Somasundaran

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 15:29
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/52; C02F1/5236; C01; C01B; C01B25/00; C01B25/16; C01B25/26; C01B25/32; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/906; Y10S210/907

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 62 words
A method for dewatering phosphate slimes and recovering a water solution comprising adding calcium sulfate hemihydrate to the slimes, in an amount equivalent to the total weight percent of solids in the slime, mixing the resulting admixture to effect formation of calcium sulfate dihydrate crystals in the admixture, and dewatering the admixture to recover a water solution from the resulting crystal-containing admixture.
Claim 2
Independent Claim 62 words
A method for dewatering phosphate slimes and recovering a water solution comprising adding calcium sulfate hemihydrate to the slimes, in an amount equivalent to the total weight percent of solids in the slime, mixing the resulting admixture to effect formation of calcium sulfate dihydrate crystals in the admixture, and dewatering the admixture to recover a water solution from the resulting crystal-containing admixture.
Claim 3
Dependent Claim 33 words
A method to claim 1, wherein the calcium sulfate hemihydrate addition is followed by the addition of calcium sulfate dihydrate in an amount sufficient to enhance the separation of solids from the slime.
Claim 4
Dependent Claim 45 words
A method according to claim 1, wherein the calcium sulfate hemihydrate addition is preceded by addition of sulfuric acid to the slimes to reduce the pH of the slimes to a value from about 1 to 3 in order to solubilize phosphates in the slime.
Claim 5
Dependent Claim 16 words
A method according to claim 1, wherein the dewatering and recovering comprises filtering, decanting or centrifuging.
Claim 6
Dependent Claim 54 words
A method according to claim 3, which further comprises adding a calcium salt to the liquid solution to raise the pH of the liquid solution to a value above about 6.0, mixing the liquid solution to permit calcium phosphate salts to precipitate and separately recovering the calcium phosphate salts and a dephosphated liquid portion.
Claim 7
Dependent Claim 24 words
A method according to claim 5, wherein the calcium salt is selected from the group consisting of calcium oxide, calcium carbonate and mixtures thereof.
Claim 8
Dependent Claim 19 words
A method according to claim 6, wherein the pH is raised to a value between about 6.2 and 6.5.
Claim 9
Dependent Claim 15 words
A method according to claim 5, wherein the separately recovering comprises filtering, decanting or centrifuging.

References Cited (Backward Citations)

US3450633A Cited
US3680698A Cited
US3761239A Cited
US3763041A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-01-06 1989-07-08 1990-01-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-01-06 1993-07-08 1994-01-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-01-06 1997-07-08 1998-01-07 $7700.00 Window Closed / Lapsed

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