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US4560667A Expired / Lapsed US ⏱️ 0.0 years remaining

Halogen glasses modified with carbon disulphide and process of preparation

Assignee: PUBLIC DIT CENTRE NATONAL E LA RECHERCHE SCIENTIFIQUE CNRS Ets
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Filing: 1984-07-20
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Granted: 1985-12-24
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Expires: 2004-07-20
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Abstract

Abstract Halogen glass is treated, while heated above its fusion temperature, with carbon disulphide. The resulting halogen glass is essentially free of parasitic absorption bands in the infra-red spectrum. The treatment with carbon disulphide apparently lowers the hydroxyl ion content and the metal-oxygen bonds sufficiently to avoid the infra-red absorption bands.

Inventors

  • 👤 Jacques Lucas
  • 👤 Gilles Fonteneau

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:05
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/32; C03C3/325; Y; Y10; Y10S; Y10S65/00; Y10S65/90

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 80 words
Improved halogen glass essentially free of parasitic absorption bands in the infra-red range comprising CS 2 modified halogen glass containing at least one halide of a metal of an atomic weight greater than 23, the glass having been heated to a temperature above its fusion temperature and subjected to the action of carbon disulfide gas in a controlled atmosphere to reduce the hydroxyl ion content and the metal-oxygen bonds sufficiently to essentially eliminate parasitic absorption bands in the infra-red range.
Claim 2
Dependent Claim 80 words
Improved halogen glass essentially free of parasitic absorption bands in the infra-red range comprising CS 2 modified halogen glass containing at least one halide of a metal of an atomic weight greater than 23, the glass having been heated to a temperature above its fusion temperature and subjected to the action of carbon disulfide gas in a controlled atmosphere to reduce the hydroxyl ion content and the metal-oxygen bonds sufficiently to essentially eliminate parasitic absorption bands in the infra-red range.
Claim 3
Dependent Claim 25 words
Improved halogen glass according to claim 1 wherein, the glass contains at least one halide of a metal of an atomic weight greater than 138.
Claim 4
Dependent Claim 16 words
Improved halogen glass according to claim 1 wherein said at least one halide is a fluoride.
Claim 5
Independent Claim 42 words
A method of preparing an improved halogen glass essentially free of parasitic absorption bands in the infra-red region comprising, subjecting a halogen glass, heated to a temperature above its fusion temperature, to the action of carbon disulphide gas, in a controlled atmosphere.
Claim 6
Independent Claim 42 words
A method of preparing an improved halogen glass essentially free of parasitic absorption bands in the infra-red region comprising, subjecting a halogen glass, heated to a temperature above its fusion temperature, to the action of carbon disulphide gas, in a controlled atmosphere.
Claim 7
Dependent Claim 37 words
A method according to claim 4 comprising, first heating a mixture of components of halogen glass to a temperature above the fusion temperature to form the halogen glass, and treating the fused glass with the carbon disulphide.
Claim 8
Dependent Claim 32 words
A method according to claim 4 wherein, the glass is at a temperature up to 200° C. above its fusion temperature while it is subjected to the action of the carbon disulphide.
Claim 9
Dependent Claim 21 words
A method according to claim 6 wherein, the temperature is 50° to 200° C. above the fusion temperature of the glass.
Claim 10
Dependent Claim 15 words
A method according to claim 4 wherein, the carbon disulphide gas is mixed with helium.
Claim 11
Dependent Claim 15 words
A method according to claim 4 wherein, the carbon disulphide gas is mixed with nitrogen.
Claim 12
Dependent Claim 17 words
A method according to claim 4 wherein, the carbon disulphide gas is mixed with an inert gas.
Claim 13
Dependent Claim 24 words
The method of claim 4 wherein the halogen glass contains at least one halide of a metal of an atomic weight greater than 23.
Claim 14
Dependent Claim 15 words
A method according to claim 11 wherein said at least one halide is a fluoride.

References Cited (Backward Citations)

FR919006A Cited
US2511224A Cited
US2466507A Cited
FR2354977A1 Cited
US4141741A Cited
FR2384724A1 Cited
US4328318A Cited
US4341873A Cited
FR2488873A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-12-23 1989-06-24 1989-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-12-23 1993-06-24 1993-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-12-23 1997-06-24 1997-12-24 $7700.00 Window Closed / Lapsed

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