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US4559264A Expired / Lapsed US ⏱️ 0.0 years remaining

Synthetic mica products

Assignee: Corning Glass Works
•
Filing: 1983-01-27
•
Granted: 1985-12-17
•
Expires: 2003-01-27
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Abstract

Abstract There are disclosed synthetic mica papers, substrates produced by laminating such papers, and use of the substrates in printed circuit assemblies. The mica paper is composed primarily of overlapping, ion-exchanged platelets of a synthetic, lithium and/or sodium, water-swelling mica, and is impregnated with an organic resin.

Inventors

  • 👤 Syed N. Hoda
  • 👤 Anthony R. Olszewski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 01:33
CPC Classifications
D; D21; D21H; D21H13/00; D21H13/36; D21H13/38; D21H13/44; H; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/0353; H05K1/0366; H05K2201/00; H05K2201/02; H05K2201/0275; H05K2201/0293; H05K2201/06; H05K2201/068; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10T; Y10T428/00; Y10T428/25; Y10T428/251; Y10T428/29; Y10T428/2911; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31518

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 73 words
A substrate in which a plurality of synthetic mica papers impregnated with an organic resin are laminated together to produce a planar isotropic coefficient of thermal expansion in the X-Y plane, each paper being composed of overlapping, ion-exchanged platelets of a synthetic, lithium and/or sodium, water-swelling mica wherein lithium and/or sodium ions from the mica have been exchanged for larger cations, said mica platelets having a high aspect ratio and a planar orientation.
Claim 2
Dependent Claim 73 words
A substrate in which a plurality of synthetic mica papers impregnated with an organic resin are laminated together to produce a planar isotropic coefficient of thermal expansion in the X-Y plane, each paper being composed of overlapping, ion-exchanged platelets of a synthetic, lithium and/or sodium, water-swelling mica wherein lithium and/or sodium ions from the mica have been exchanged for larger cations, said mica platelets having a high aspect ratio and a planar orientation.
Claim 3
Dependent Claim 20 words
A substrate in accordance with claim 1 in which the impregnating resin constitutes 20 to 50% of the impregnated paper.
Claim 4
Dependent Claim 51 words
A substrate in accordance with claim 1 in which the mica is selected from the group composed of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite and fluorphlogopite.
Claim 5
Dependent Claim 21 words
A substrate in accordance with claim 1 wherein at least one of the laminated mica papers contains up to 75% resin.
Claim 6
Dependent Claim 15 words
A substrate in accordance with claim 1 wherein conductive circuit patterns are buried between laminae.
Claim 7
Dependent Claim 24 words
A substrate in accordance with claim 1 in which one or more holes are produced through the substrate and the hole walls are metallized.
Claim 8
Dependent Claim 75 words
Synthetic mica papers impregnated with an organic resin and consisting essentially of overlapping ion-exchanged platelets of a synthetic lithium and/or sodium water-swelling mica, wherein lithium and/or sodium ions from the mica have been exchanged for larger cations, said mica platelets having a high aspect ratio and a planar orientation such that said papers can be stacked and consolidated to produce a laminated substrate having a planar isotropic coefficient of thermal expansion in the X-Y plane.
Claim 9
Dependent Claim 75 words
Synthetic mica papers impregnated with an organic resin and consisting essentially of overlapping ion-exchanged platelets of a synthetic lithium and/or sodium water-swelling mica, wherein lithium and/or sodium ions from the mica have been exchanged for larger cations, said mica platelets having a high aspect ratio and a planar orientation such that said papers can be stacked and consolidated to produce a laminated substrate having a planar isotropic coefficient of thermal expansion in the X-Y plane.
Claim 10
Dependent Claim 16 words
Synthetic mica papers according to claim 7 wherein the organic resin constitutes 15-75% of said papers.
Claim 11
Dependent Claim 14 words
Synthetic mica papers according to claim 7 wherein the organic resin is an epoxy.
Claim 12
Dependent Claim 20 words
Synthetic mica papers according to claim 7 also containing a coupling agent for the mica platelets and the organic resin.
Claim 13
Dependent Claim 27 words
Synthetic mica papers according to claim 10 wherein said organic resin is an epoxy and said coupling agent is selected from the group of silanes and titanates.
Claim 14
Dependent Claim 16 words
Synthetic mica papers according to claim 1 also containing a curing agent for the organic resin.
Claim 15
Dependent Claim 29 words
Synthetic mica papers according to claim 12 wherein said organic resin is an epoxy and said curing agent is selected from the group of amines, acid anhydrides, and catalytic.
Claim 16
Dependent Claim 51 words
Synthetic mica papers in accordance with claim 7 wherein the mica is selected from the group composed of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite.
Claim 17
Dependent Claim 25 words
Synthetic mica papers in accordance with claim 7 wherein the larger exchanged ions are selected from the group of complex organic cations and potassium ions.
Claim 18
Dependent Claim 20 words
Synthetic mica papers in accordance with claim 7 wherein the mica platelets have an aspect ratio of at least 100.
Claim 19
Dependent Claim 25 words
Synthetic mica papers in accordance with claim 7 wherein the planar coefficient of thermal expansion in a laminated stack is less than 100×10 -7 /°C.

References Cited (Backward Citations)

US4360570A Cited
US4239519A Cited
US4335367A Cited
US4336302A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-12-16 1989-06-17 1989-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-12-16 1993-06-17 1993-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-12-16 1997-06-17 1997-12-17 $7700.00 Window Closed / Lapsed

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