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US4559059A Expired / Lapsed US ⏱️ 0.0 years remaining

Tinted contact lenses and a method for their preparation

Assignee: Ciba Vision Corp
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Filing: 1984-08-20
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Granted: 1985-12-17
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Expires: 2004-08-20
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Abstract

Abstract Contact lenses comprising polymeric lens materials in which reactive dyestuffs have been covalently bonded to monomer units of the polymer backbone, said reactive dyestuffs being reactive dyes capable of forming ether linkages with cellulose and reactive with hydroxyl, amino, amido or mercapto groups present in a hydrogel polymer to form the covalent bond therewith. The invention is of particular interest in the area of so-called hydrophilic or "soft" contact lenses, commonly referred to as hydrogel lenses.

Inventors

  • 👤 Kai C. Su

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:48
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; D; D06; D06P; D06P3/00; D06P3/008; G02C; G02C7/00; G02C7/02; G02C7/021

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 59 words
A contact lens colored over at least a portion of its surface, comprising a copolymeric hydrogel material to which at least one reactive fluorotriazine dyestuff is covalently bonded external to the polymer backbone by reaction at temperatures up to 60° C. with hydroxyl, amino, amido or mercapto groups present in said polymer, over the colored portion of the lens.
Claim 2
Dependent Claim 59 words
A contact lens colored over at least a portion of its surface, comprising a copolymeric hydrogel material to which at least one reactive fluorotriazine dyestuff is covalently bonded external to the polymer backbone by reaction at temperatures up to 60° C. with hydroxyl, amino, amido or mercapto groups present in said polymer, over the colored portion of the lens.
Claim 3
Dependent Claim 25 words
A contact lens according to claim 1, wherein said reactive dyestuff is covalently bonded by nucleophilic addition to said hydroxyl, amino, amido or mercapto groups.
Claim 4
Dependent Claim 17 words
A contact lens according to claim 1, wherein said hydrogel material contains hydroxy groups in the polymer.
Claim 5
Dependent Claim 26 words
A contact lens according to claim 1 wherein the reactive fluorotriazine dyestuff is bonded to the polymer backbone by reaction at temperatures up to 50° C.
Claim 6
Dependent Claim 17 words
A contact lens according to claim 1, comprising a colored central portion and a clear annular edge.
Claim 7
Dependent Claim 28 words
A contact lens according to claim 1, wherein the colored portion thereof has a light transmission of 90% or less in a segment of the visible light range.
Claim 8
Dependent Claim 53 words
A process for preparing a contact lens colored over at least a portion of its surface, comprising reacting at temperatures up to 60° C. at least one ractive fluorotriazine dyestuff with hydroxyl, amino, amido or mercapto groups present in the polymeric hydrogel contact lens material, and removing unreacted dyestuff from said lens material.
Claim 9
Dependent Claim 53 words
A process for preparing a contact lens colored over at least a portion of its surface, comprising reacting at temperatures up to 60° C. at least one ractive fluorotriazine dyestuff with hydroxyl, amino, amido or mercapto groups present in the polymeric hydrogel contact lens material, and removing unreacted dyestuff from said lens material.
Claim 10
Dependent Claim 26 words
The process according to claim 7 wherein the reactive fluorotriazine dyestuff and the polymeric hydrogel contact lens material is reacted at temperatures up to 50° C.
Claim 11
Dependent Claim 18 words
A process according to claim 7, wherein said lens material is in the form of a contact lens.
Claim 12
Dependent Claim 31 words
A process according to claim 9, wherein the reaction is conducted in an aqueous medium having a pH of at least 9 and at a temperature of up to 40° C.
Claim 13
Dependent Claim 19 words
A process according to claim 9, wherein the reactive dyestuff is applied to only a portion of said lens.
Claim 14
Dependent Claim 25 words
A process according to claim 7, wherein said dyestuff reacts by nucleophilic addition to said hydroxyl, amino, amido or mercapto groups in the hydrogel material.
Claim 15
Dependent Claim 16 words
A process according to claim 7, wherein said hydrogel material contains hydroxy groups in the polymer.

References Cited (Backward Citations)

GB1004424A Cited
GB1163617A Cited
US4252421A Cited
US4468229A Cited
US4494954A Cited
US4447474A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-12-16 1989-06-17 1989-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-12-16 1993-06-17 1993-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-12-16 1997-06-17 1997-12-17 $7700.00 Window Closed / Lapsed

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