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US4556750A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkylation process

Assignee: Phillips Petroleum Co
•
Filing: 1985-04-12
•
Granted: 1985-12-03
•
Expires: 2005-04-12
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Abstract

Abstract In an alkylation process a portion of the alkylating olefin is added to benzene before heating the benzene up to the alkylation reaction temperature.

Inventors

  • 👤 R. Lynn Cobb

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:06
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/54; C07C2/64; C07C2/66; C07C2/68; C07C2/70; C07C2521/00; C07C2521/16; C07C2527/00; C07C2527/06; C07C2527/08; C07C2527/12; C07C2527/1213; C07C2527/14; C07C2527/16; C07C2527/167; C07C2527/173; C07C2531/00; C07C2531/02

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 76 words
A process for the dialkylation of benzene with isobutylene which comprises: (a) adding to said benzene and an alkylation catalyst about 10 to about 50 volume percent of the total amount of isobutylene to be used in the alkylation process; (b) heating the mixture produced in step (a) up to an alkylation reaction temperature; and (c) adding the remainder of the isobutylene to be used in the alkylation process to said heated mixture to produce ditertiary-butylbenzene.
Claim 2
Dependent Claim 76 words
A process for the dialkylation of benzene with isobutylene which comprises: (a) adding to said benzene and an alkylation catalyst about 10 to about 50 volume percent of the total amount of isobutylene to be used in the alkylation process; (b) heating the mixture produced in step (a) up to an alkylation reaction temperature; and (c) adding the remainder of the isobutylene to be used in the alkylation process to said heated mixture to produce ditertiary-butylbenzene.
Claim 3
Dependent Claim 40 words
A process in accordance with claim 1 wherein about 15 to about 35 volume percent of the total amount of isobutylene to be used in the alkylation process is added to said benzene and said alkylation catalyst in step (a).
Claim 4
Dependent Claim 21 words
A process in accordance with claim 1 wherein said alkylation reaction temperature is in the range of about 50° C.-250° C.
Claim 5
Dependent Claim 21 words
A process in accordance with claim 3 wherein said alkylation reaction temperature is in the range of about 130° C.-190° C.
Claim 6
Dependent Claim 31 words
A process in accordance with claim 3 wherein said alkylation catalyst is selected from the group consisting of: acid-treated montmorillonite, boron trifluoride, boron trifluoride: phosphoric acid complex, and boron trifluoride: etherate.
Claim 7
Dependent Claim 14 words
A process in accordance with claim 4 wherein said alkylation catalyst is acid-treated montmorillonite.
Claim 8
Dependent Claim 11 words
A process in accordance with claim 4 wherein 1,4-ditertiary-butylbenzene is produced.

References Cited (Backward Citations)

US2308786A Cited
US2400437A Cited
US2584103A Cited
US2768985A Cited
US2819323A Cited
US3118956A Cited
US3207800A Cited
US3849507A Cited
US4225737A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-12-02 1989-06-03 1989-12-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-12-02 1993-06-03 1993-12-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-12-02 1997-06-03 1997-12-03 $7700.00 Window Closed / Lapsed

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