US4555474A
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Photopolymerizable composition
Assignee: Fujifilm Holdings Corp
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Filing: 1985-02-04
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Granted: 1985-11-26
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Expires: 2005-02-04
Abstract
Abstract A photopolymerizable composition is described, comprising a polymerizable compound having an ethylenically unsaturated bond and a photopolymerization initiator represented by formula (I) <IMAGE> (I) wherein Z represents a non-metallic atomic group forming a nitrogen-containing heterocyclic ring; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring. The photopolymerization initiator (I) greatly improves the sensitivity of the composition.
Inventors
- 👤 Kouichi Kawamura
- 👤 Yoshimasa Aotani
- 👤 Akira Umehara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 12:50
CPC Classifications
C; C07; C07D; C07D271/00; C07D271/02; C07D271/10; C07D277/00; C07D277/60; C07D277/62; C07D277/64; C07D277/84; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/12; Y10S430/121; Y10S430/124
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
52 words
A photopolymerizable composition comprising a polymerizable compound having an ethylenically unsaturated bond and a photopolymerization initiator represented by formula (I) ##STR12## wherein Z represents a non-metallic atomic group forming a substituted or unsubstituted nitrogen-containing heterocyclic ring; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring.
Claim 2
Dependent Claim
52 words
A photopolymerizable composition comprising a polymerizable compound having an ethylenically unsaturated bond and a photopolymerization initiator represented by formula (I) ##STR12## wherein Z represents a non-metallic atomic group forming a substituted or unsubstituted nitrogen-containing heterocyclic ring; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring.
Claim 3
Dependent Claim
14 words
A photopolymerizable composition as in claim 1, wherein the composition further comprises a binder.
Claim 4
Dependent Claim
14 words
A photopolymerizable composition as in claim 1, wherein the composition further comprises a sensitizer.
Claim 5
Dependent Claim
87 words
A photopolymerizable composition as in claim 1, wherein the photopolymerization initiator is represented by formula (II) ##STR13## wherein Z' represents a non-metallic atomic group forming a nitrogen-containing substituted or unsubstituted heterocyclic ring together with X; X represents O, S, or N--R', wherein R' represents a substituted or unsubstituted alkyl group having from 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having from 6 to 10 carbon atoms; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring.
Claim 6
Dependent Claim
33 words
A photopolymerizable composition as in claim 1, wherein the photopolymerization initiator is present in an amount of from 0.01 to 50 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 7
Dependent Claim
33 words
A photopolymerizable composition as in claim 1, wherein the photopolymerization initiator is present in an amount of from 0.1 to 10 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 8
Dependent Claim
31 words
A photopolymerizable composition as in claim 2, wherein the binder is present in an amount of up to 1,000 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 9
Dependent Claim
31 words
A photopolymerizable composition as in claim 7, wherein the binder is present in an amount of up to 500 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 10
Dependent Claim
31 words
A photopolymerizable composition as in claim 3, wherein the sensitizer is present in an amount of up to 100 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 11
Dependent Claim
31 words
A photopolymerizable composition as in claim 9, wherein the sensitizer is present in an amount of up to 20 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 12
Dependent Claim
87 words
A photopolymerizable composition as in claim 2, wherein the photopolymerization initiator is represented by formula (II) ##STR14## wherein Z' represents a non-metallic atomic group forming a nitrogen-containing substituted or unsubstituted heterocyclic ring together with X; X represents O, S, or N--R', wherein R' represents a substituted or unsubstituted alkyl group having from 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having from 6 to 10 carbon atoms; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring.
Claim 13
Dependent Claim
33 words
A photopolymerizable composition as in claim 2, wherein the photopolymerization initiator is present in an amount of from 0.01 to 50 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 14
Dependent Claim
33 words
A photopolymerizable composition as in claim 2, wherein the photopolymerization initiator is present in an amount of from 0.1 to 10 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 15
Dependent Claim
87 words
A photopolymerizable composition as in claim 3, wherein the photopolymerization initiator is represented by formula (II) ##STR15## wherein Z' represents a non-metallic atomic group forming a nitrogen-containing substituted or unsubstituted heterocyclic ring together with X; X represents O, S, or N--R', wherein R' represents a substituted or unsubstituted alkyl group having from 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having from 6 to 10 carbon atoms; and R represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring.
Claim 16
Dependent Claim
33 words
A photopolymerizable composition as in claim 3, wherein the photopolymerization initiator is present in an amount of from 0.01 to 50 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 17
Dependent Claim
33 words
A photopolymerizable composition as in claim 3, wherein the photopolymerization initiator is present in an amount of from 0.1 to 10 parts by weight per 100 parts by weight of the polymerizable compound.
Claim 18
Dependent Claim
47 words
A photopolymerizable composition as in claim 1, wherein the composition further comprises a binder present in an amount of up to 1,000 parts by weight, and a sensitizer in an amount of up to 100 parts by weight, per 100 parts by weight of the polymerizable compound.
Claim 19
Dependent Claim
47 words
A photopolymerizable composition as in claim 4, wherein the composition further comprises a binder present in an amount of up to 1,000 parts by weight, and a sensitizer in an amount of up to 100 parts by weight, per 100 parts by weight of the polymerizable compound.
Claim 20
Dependent Claim
21 words
A photopolymerizable composition as in claim 3, wherein said sensitizer is a carbonyl compound, a halogen compound or an amino compound.
Claim 21
Dependent Claim
24 words
A photopolymerizable composition as in claim 19, wherein said sensitizer is 2-morpholino-2-methyl-p-methylthiopropiophenone, Michler's ketone, 2,6-di(trichloromethyl)-4-(p-methoxyphenyl)-1,3,5-triazine, 2-trichloromethyl-5-(p-methoxystyryl)-1,3,4-oxadiazole, anthraquinone-1-sulfonyl chloride, trimethylamine, triethanolamine, ethyl p-dimethylaminobenzoate or N-phenylglycine.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-25 | 1989-05-27 | 1989-11-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-25 | 1993-05-27 | 1993-11-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-25 | 1997-05-27 | 1997-11-26 | $7700.00 | Window Closed / Lapsed |