Process for flocculating phophatic slimes

Claim 2

A process for flocculating phosphatic slimes which comprises: (a) forming a concentrated aqueous solution from a water-soluble, ter- or higher polymer water-in-oil emulsion, wherein said polymer has the formula containing the repeating units as follows: ##STR8## wherein: R, R 1 and R 3 are independently hydrogen or methyl; R 2 + is an alkali metal ion; R 4 is OR 5 wherein R 5 is an alkyl group having up to 5 carbon atoms; ##STR9## wherein R 6 is an alkyl group having up to 8 carbon atoms; ##STR10## wherein R 7 is methyl, ethyl or butyl; phenyl; substituted phenyl; CN or ##STR11## a is from about 30 to about 90 mole percent; b is from about 5 to about 60 mole percent; c is from about 1 to about 10 mole percent; d is an integer of from about 1,000 to about 500,000; and wherein said polymer has an intrinsic viscosity from about 15 to about 28 dl/g as measured in a one normal aqueous sodium chloride solution; (b) diluting said concentrated aqueous solution of ter- or higher polymer formed in step (a) with additional water; (c) mixing the diluted solution of step (b) with phosphatic slimes under floc forming conditions; and (d) allowing the suspended solids to settle from said slime to form an essentially clear aqueous supernatant.

Claim 3

The process of claim 1 wherein: R, R 1 and R 3 are hydrogen; R 2 + is Na + or K + ; and ##STR12##

Claim 4

The process of claim 2 wherein R 2 + is Na + , R 6 is ethyl and R 7 is methyl.

Claim 5

The process of claim 1 wherein said polymer has the formula containing the repeating units as follows: ##STR13## wherein: R, R 1 and R 3 are independently hydrogen or methyl; R 2 + is an alkali metal ion; R 4 is OR 5 wherein R 5 is an alkyl group having up to 5 carbon atoms; or ##STR14## wherein R 7 is methyl, ethyl or butyl; a is from about 30 to about 90 mole percent; b is from about 5 to about 60 mole percent; c is from about 1 to about 10 mole percent; and e is from about 1 to about 10 mole percent.

Claim 6

The process of claim 4 wherein: R, R 1 and R 3 are hydrogen; R 2 + is Na + or K + ; and ##STR15##

Claim 7

The process of claim 5 wherein R 2 + is Na + and R 7 is methyl.

Claim 8

The process of claim 1 wherein repeating unit (c) is derived from a monomer that is water insoluble or very slightly water soluble which is selected from the group consisting of vinyl ethers, alkyl acrylates or methacrylates, vinyl esters, styrene, substituted styrene, acrylonitrile and N-vinyl carbazole.

Claim 9

The process of claim 7 wherein said monomer is an alkyl acrylate or vinyl ester.

Claim 10

The process of claim 8 wherein said monomer is vinyl acetate or ethyl acrylate.

Claim 11

A process for flocculating phosphatic slimes which comprises: (a) forming a concentrated aqueous solution from a water-soluble, ter- or higher polymer water-in-oil emulsion, wherein said polymer has the formula containing the repeating units as follows: ##STR16## wherein: R, R 1 and R 3 are independently hydrogen or methyl; R 2 + is an alkali metal ion; R 4 is OR 5 wherein R 5 is an alkyl group having up to 5 carbon atoms; ##STR17## wherein R 6 is an alkyl group having up to 8 carbon atoms; ##STR18## wherein R 7 is methyl, ethyl or butyl; phenyl; substituted phenyl; CN or ##STR19## a is from about 55 to about 85 mole percent; b is from about 10 to about 41.1 mole percent; c is from about 5 to about 12.5 mole percent; d is an integer of from about 1,000 to about 500,000; and wherein said polymer has an intrinsic viscosity of from about 15 to about 28 dl/g as measured in a one normal aqueous sodium chloride solution; (b) diluting said concentrated aqueous solution of ter- or higher polymer formed in step (a) with additional water; (c) mixing the diluted solution of (b) with phosphatic slimes under floc forming conditions; and (d) allowing the suspended solids to settle from said slime to form an essentially clear aqueous supernatant.

Claim 12

A process for flocculating phosphatic slimes which comprises: (a) forming a concentrated aqueous solution from a water-soluble, ter- or higher polymer water-in-oil emulsion, wherein said polymer has the formula containing the repeating units as follows: ##STR16## wherein: R, R 1 and R 3 are independently hydrogen or methyl; R 2 + is an alkali metal ion; R 4 is OR 5 wherein R 5 is an alkyl group having up to 5 carbon atoms; ##STR17## wherein R 6 is an alkyl group having up to 8 carbon atoms; ##STR18## wherein R 7 is methyl, ethyl or butyl; phenyl; substituted phenyl; CN or ##STR19## a is from about 55 to about 85 mole percent; b is from about 10 to about 41.1 mole percent; c is from about 5 to about 12.5 mole percent; d is an integer of from about 1,000 to about 500,000; and wherein said polymer has an intrinsic viscosity of from about 15 to about 28 dl/g as measured in a one normal aqueous sodium chloride solution; (b) diluting said concentrated aqueous solution of ter- or higher polymer formed in step (a) with additional water; (c) mixing the diluted solution of (b) with phosphatic slimes under floc forming conditions; and (d) allowing the suspended solids to settle from said slime to form an essentially clear aqueous supernatant.