US4554303A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Copolyester compositions
Assignee: Eastman Chemical Co
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Filing: 1984-12-14
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Granted: 1985-11-19
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Expires: 2004-12-14
Abstract
Abstract Disclosed are blends of low-melting, slowly crystallizing copolyesters or of substantially amorphous copolyesters having relatively high glass transition temperatures containing very small amounts of low-molecular-weight polyolefins. These blends have sharply increased crystallinity and crystallization rates and provide significant improvements in production because of the enhanced crystallization.
Inventors
- 👤 Frederick D. Petke
- 👤 Charles W. Ramsey
- 👤 Richard L. McConnell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:25
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L91/00; C08L91/06; C09; C09J; C09J167/00; C09J167/02
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
255 words
Composition comprising (a) a copolyester derived from 100 mole % of a dibasic acid component comprising about 40-100 mol % terephthalic acid and 100 mol % of a glycol component comprising about 40-100 mol % ethylene glycol, 1,4-butanediol or 1,6-hexanediol, wherein about 20-120 mol %, based on 200 mol % polymer, is derived from about (1) 0 to about 60 mol % of a second acid selected from the group consisting of isophthalic acid, dimer acid and aliphatic dicarboxylic acids having 3-12 carbon atoms, (2) 0 to about 60 mole % of a second glycol having 2-10 carbon atoms, or (3) about 20-120 mole % of a combination of said second acid and second glycol, said copolyester characterized by having a melting temperature of about 80°-190° C. and a ΔH f of less than about 6 cal/gm, and (b) about 0.02 to about 2 wt % of at least one natural or synthetic wax with said natural wax being animal, vegetable, or mineral waxes with melting points in the range of about 40° to about 90° C. and melt viscosities in the range of about 5 to about 100 cp at 125° C.; said synthetic waxes being based on polyethylene, polypropylene, poly-1-butene, ethylene or propylene copolymers with each other, or with α-olefins containing 3-6 carbon atoms, or Fischer Tropsch waxes, with melting points in the range of about 95° C. to 160° C., densities of about 0.90 to about 0.965 and melt viscosities ranging from about 5 cp. to about 30,000 cp. at 190° C.
Claim 2
Dependent Claim
255 words
Composition comprising (a) a copolyester derived from 100 mole % of a dibasic acid component comprising about 40-100 mol % terephthalic acid and 100 mol % of a glycol component comprising about 40-100 mol % ethylene glycol, 1,4-butanediol or 1,6-hexanediol, wherein about 20-120 mol %, based on 200 mol % polymer, is derived from about (1) 0 to about 60 mol % of a second acid selected from the group consisting of isophthalic acid, dimer acid and aliphatic dicarboxylic acids having 3-12 carbon atoms, (2) 0 to about 60 mole % of a second glycol having 2-10 carbon atoms, or (3) about 20-120 mole % of a combination of said second acid and second glycol, said copolyester characterized by having a melting temperature of about 80°-190° C. and a ΔH f of less than about 6 cal/gm, and (b) about 0.02 to about 2 wt % of at least one natural or synthetic wax with said natural wax being animal, vegetable, or mineral waxes with melting points in the range of about 40° to about 90° C. and melt viscosities in the range of about 5 to about 100 cp at 125° C.; said synthetic waxes being based on polyethylene, polypropylene, poly-1-butene, ethylene or propylene copolymers with each other, or with α-olefins containing 3-6 carbon atoms, or Fischer Tropsch waxes, with melting points in the range of about 95° C. to 160° C., densities of about 0.90 to about 0.965 and melt viscosities ranging from about 5 cp. to about 30,000 cp. at 190° C.
Claim 3
Dependent Claim
18 words
A composition according to claim 1 wherein said copolyester is derived from essentially 100 mol % terephthalic acid.
Claim 4
Dependent Claim
17 words
A composition according to claim 1 wherein said copolyester is derived from terephthalic acid and isophthalic acid.
Claim 5
Dependent Claim
25 words
A composition according to claim 1 wherein said copolyester is derived from terephthalic acid and at least one aliphatic dicarboxylic acid having 3-12 carbon atoms.
Claim 6
Dependent Claim
13 words
A composition according to claim 1 wherein said wax is a natural wax.
Claim 7
Dependent Claim
13 words
A composition according to claim 1 wherein said wax is a synthetic wax.
Claim 8
Dependent Claim
8 words
An adhesive comprising the composition of claim 1.
Claim 9
Dependent Claim
11 words
A film or sheet material comprising the composition of claim 1.
Claim 10
Dependent Claim
9 words
A particulate material comprising the composition of claim 1.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-18 | 1989-05-20 | 1989-11-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-18 | 1993-05-20 | 1993-11-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-18 | 1997-05-20 | 1997-11-19 | $7700.00 | Window Closed / Lapsed |