US4552811A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Capsule manufacture
Assignee: WTA Inc
•
Filing: 1984-06-12
•
Granted: 1985-11-12
•
Expires: 2004-06-12
Abstract
Abstract A process is disclosed for performing encapsulation, en masse, by an in situ polymerization reaction to yield capsule wall material. The reaction comprises the polymerization of urea and formaldehyde, or monomeric or low molecular weight polymers of dimethylol urea or methylated dimethylol urea, melamine and formaldehyde, monomeric or low molecular weight polymers of methylol melamine or methylated methylol melamine, in an aqueous vehicle and the reaction is conducted in the presence of certain acrylic acid copolymers. The disclosed encapsulation process provides improved resistance of the emulsion of intended capsule core material to destabilization and permits the manufacture of microcapsules with improved drop size distribution, improved resistance to frictional smudge damage and enhanced impermeability.
Inventors
- 👤 Robert W. Brown
- 👤 Richard P. Bowman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 21:51
CPC Classifications
B; B01; B01J; B01J13/00; B01J13/02; B01J13/06; B01J13/14; B01J13/18; B41; B41M; B41M5/00; B41M5/124; B41M5/165; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
143 words
A process for preparing microcapsules in an aqueous manufacturing vehicle which comprises enwrapping particles of intended capsule core material, substantially insoluble in said vehicle, with polymeric shells produced by in situ polymerization of melamine and formaldehyde, methylol melamine, methylated methylol melamine, urea and formaldehyde, dimethylol urea or methylated dimethylol urea in the presence of an acrylic acid-alkyl acrylate copolymer, wherein the weight percent and type of alkyl acrylate in said copolymer are selected from the group consisting of about 12 to about 30 ethyl acrylate, about 6 to about 14 propyl acrylate, about 4 to about 20 butyl acrylate, about 2 to about 14 amyl acrylate, about 2 to about 10 hexyl acrylate, about 4 to about 12 cyclohexyl acrylate and about 2 2-ethylhexyl acrylate and said copolymer is present as about 0.4 to about 15 percent by weight of said manufacturing vehicle.
Claim 2
Dependent Claim
143 words
A process for preparing microcapsules in an aqueous manufacturing vehicle which comprises enwrapping particles of intended capsule core material, substantially insoluble in said vehicle, with polymeric shells produced by in situ polymerization of melamine and formaldehyde, methylol melamine, methylated methylol melamine, urea and formaldehyde, dimethylol urea or methylated dimethylol urea in the presence of an acrylic acid-alkyl acrylate copolymer, wherein the weight percent and type of alkyl acrylate in said copolymer are selected from the group consisting of about 12 to about 30 ethyl acrylate, about 6 to about 14 propyl acrylate, about 4 to about 20 butyl acrylate, about 2 to about 14 amyl acrylate, about 2 to about 10 hexyl acrylate, about 4 to about 12 cyclohexyl acrylate and about 2 2-ethylhexyl acrylate and said copolymer is present as about 0.4 to about 15 percent by weight of said manufacturing vehicle.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the polymeric shell is produced by in situ polymerization of methylated methylol melamine or urea and formaldehyde.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein the polymeric shell is produced by in situ polymerization of methylated methylol melamine.
Claim 5
Dependent Claim
24 words
The process of claims 1, 2 or 3, wherein the polymerization is conducted at a temperature of about 40° C. to about 95° C.
Claim 6
Dependent Claim
21 words
The process of claim 4 wherein the polymerization is conducted at a temperature of about 50° C. to about 70° C.
Claim 7
Dependent Claim
19 words
The process of claim 5 wherein said copolymer consists of about 6 to about 10 weight percent butyl acrylate.
Claim 8
Dependent Claim
16 words
The process of claim 6 wherein said copolymer consists of about 8 weight percent butyl acrylate.
Claim 9
Dependent Claim
19 words
The process of claim 5 wherein said copolymer consists of about 18 to about 24 weight percent ethyl acrylate.
Claim 10
Dependent Claim
16 words
The process of claim 8 wherein said copolymer consists of about 22 weight percent ethyl acrylate.
Claim 11
Dependent Claim
19 words
The process of claim 5 wherein said copolymer consists of about 2 to about 6 weight percent hexyl acrylate.
Claim 12
Dependent Claim
16 words
The process of claim 10 wherein said copolymer consists of about 4 weight percent hexyl acrylate.
Claim 13
Dependent Claim
19 words
The process of claim 5 wherein said copolymer consists of about 4 to about 6 weight percent cyclohexyl acrylate.
Claim 14
Dependent Claim
16 words
The process of claim 12 wherein said copolymer consists of about 4 weight percent cyclohexyl acrylate.
Claim 15
Dependent Claim
10 words
Microcapsules produced by a process as claimed in claim 1.
References Cited (Backward Citations)
GB1246031A
Cited
US3704264A
Cited
US4105823A
Cited
DE2832637A1
Cited
US4251386A
Cited
US4356109A
Cited
FR2416727A1
Cited
US4221710A
Cited
DE3008658A1
Cited
US4353809A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-11 | 1989-05-13 | 1989-11-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-11 | 1993-05-13 | 1993-11-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-11 | 1997-05-13 | 1997-11-12 | $7700.00 | Window Closed / Lapsed |