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US4551269A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-linear resistor and method of manufacturing the same

Assignee: US Philips Corp
•
Filing: 1982-05-28
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Granted: 1985-11-05
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Expires: 2002-05-28
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Abstract

Abstract A non-linear resistor having an operational field strength which optionally is formed as a VDR- or as an NTC-resistor having a ceramic sintered body on the basis of a polycrystalline alkaline earth metal titanate doped with a small quantity of a metal oxide so as to produce an N-type conductivity, in which the sintered body comprises at its grain boundaries insulating layers formed by re-oxidation of the sintered body and consists of an alkaline earth metal titanate having a Perowskite structure of the general formula (A.sub.1-x Ln.sub.x)TiO.sub.3.yTiO.sub.2 or A(Ti.sub.1-x Me x )O 3 .yTiO 2 , wherein: A=alkaline earth metal; Ln=rare earth metal; Me=metal having a valency of 5 or more; 0.0005<×<solubility limit in the Perowskite phase; y×0.001 to 0.02. The sintered body becomes adjustable in its non-linear resistance variation by selection of the re-oxidation temperature and of the re-oxidation duration in such manner that an initially present NTC-characteristic gradually is observable only at ever increasing temperatures and changes into a VDR-characteristic in the range of the operating temperature of the resistor.

Inventors

  • 👤 Detlev Hennings
  • 👤 Axel Schnell
  • 👤 Herbert Schreinemacher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:21
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/47; C01; C01G; C01G23/00; C01G23/003; C01G23/006; C04B35/622; C04B35/626; C04B35/62605; C04B35/6261; C04B35/6262; C04B35/62645; C04B35/62675; C04B35/63; C04B35/632; C04B35/634; C04B35/63404; C04B35/63416; H; H01; H01C; H01C7/00; H01C7/10; H01C7/105; H01C7/108; H01C7/115; C01P; C01P2002/00; C01P2002/50; C01P2002/52; C01P2002/54; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/32; C04B2235/3224; C04B2235/3227; C04B2235/3231; C04B2235/3232; C04B2235/3251; C04B2235/3258; C04B2235/65; C04B2235/656; C04B2235/6567; C04B2235/658; C04B2235/6582; C04B2235/6588; C04B2235/66; C04B2235/661; C04B2235/662; C04B2235/663; C04B2235/70; C04B2235/74; C04B2235/76; C04B2235/768; C04B2235/78; C04B2235/786; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49082; Y10T29/49085

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 131 words
A non-linear resistor having a ceramic sintered body consisting of a polycrystalline alkaline metal titanate doped to N-type conductance with a metal oxide and which sintered body is provided with electrodes on opposite located surfaces thereof characterized in that said body has a Perowskite structure, consists of an alkaline earth metal titanate containing excess TiO 2 , has a formula selected from the group consisting of (Sr 1-x Ln x ) TiO 3 .yTiO 2 and Sr(Ti 1-x Me x )O 3 .yTiO 2 wherein Ln is a rare earth metal, Me is a metal having a valence of at least 5, 0.0005<x<solubility limit of the Ln in the Perowskite phase and y=0.001 to 0.02 and which sintered body is provided on its grain boundaries with insulating layers produced by re-oxidation.
Claim 2
Dependent Claim 131 words
A non-linear resistor having a ceramic sintered body consisting of a polycrystalline alkaline metal titanate doped to N-type conductance with a metal oxide and which sintered body is provided with electrodes on opposite located surfaces thereof characterized in that said body has a Perowskite structure, consists of an alkaline earth metal titanate containing excess TiO 2 , has a formula selected from the group consisting of (Sr 1-x Ln x ) TiO 3 .yTiO 2 and Sr(Ti 1-x Me x )O 3 .yTiO 2 wherein Ln is a rare earth metal, Me is a metal having a valence of at least 5, 0.0005<x<solubility limit of the Ln in the Perowskite phase and y=0.001 to 0.02 and which sintered body is provided on its grain boundaries with insulating layers produced by re-oxidation.
Claim 3
Dependent Claim 17 words
A non-linear resistor as claimed in claim 1, characterized in that lanthanum is the rare earth metal.
Claim 4
Dependent Claim 22 words
A non-linear resistor as claimed in claim 1, characterized in that niobium is the metal of a valance of at least 5.
Claim 5
Dependent Claim 22 words
A non-linear resistor as claimed in claim 1, characterized in that tungsten is the metal of a valance of at least 5.

References Cited (Backward Citations)

EP0044981A2 Cited
US4347167A Cited
US4438214A Cited
US4405477A Cited
US4436650A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-04 1989-05-06 1989-11-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-04 1993-05-06 1993-11-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-04 1997-05-06 1997-11-05 $7700.00 Window Closed / Lapsed

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