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US4550171A Expired / Lapsed US ⏱️ 0.0 years remaining

2-(Oxo, or thio)-3-substituted 1,3-benzothiazolyl-4-cyano-7-substituted amino-benzopyrans

Assignee: BASF Corp
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Filing: 1978-10-10
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Granted: 1985-10-29
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Expires: 1998-10-10
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Abstract

Abstract There are described novel dyes of the formulae ##STR1## in which R 1 and R 2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, and R 1 and R 2 together with the nitrogen atom, and optionally with the inclusion of further hetero atoms, can also form a 5- to 7-membered heterocycle, or one of the radicals R 1 or R 2 can be linked with the carbon atom, in the o-position with respect to the amino group, of the ring A to form a fused-on, saturated, unsubstituted or substituted 5- or 6-membered ring, X is ═NR 3 , ═NCOR 4 , ##STR2## ═NH or ═O, wherein R 3 is alkyl or unsubstituted or substituted phenyl, R 4 is unsubstituted or substituted alkyl, aralkyl, aryl, vinyl, alkoxy, phenoxy or amino, and R 5 is cyano, carbalkoxy, or unsubstituted or substituted carbonamide, and R 6 is an electron-attracting radical, processes for producing them, and their use for dyeing and printing synthetic and semi-synthetic fibres, such as polyamide and cellulose triacetate materials, especially however polyester materials.

Inventors

  • 👤 Peter Mockli

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 05:17
CPC Classifications
C; C09; C09B; C09B57/00; C09B57/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 122 words
A compound of the formula ##STR45## in which R 1 and R 2 independently of one another are each hydrogen; alkyl of 1 to 7 carbon atoms unsubstituted or by hydroxyl, low-molecular alkoxy or carbalkoxy, phenoxy, cyano, carbonamido, halogen or acetoxy; cyclohexyl or methylcyclohexyl; benzyl, phenethyl, or β-phenyl-β-hydroxyethyl; unsubstituted phenyl or naphthyl or phenyl or naphthyl substituted by halogen, hydroxyl, cyano, rhodan, amino, phenylamino, phenyl, phenoxy, nitro, acetyl, acetoxy, acetylamino, benzoylamino or by alkyl, alkoxy, mono- and dialkyl amino or n-phenyl-n-alkylamino, wherein said alkyl residue is of 1-4 carbon atoms; X is ═NH or ═O; and R 6 is the radical ##STR46## in which Y is sulfur; T 12 is hydrogen, alkyl, halogen or alkoxy, and T 13 is hydrogen or alkyl.
Claim 2
Dependent Claim 122 words
A compound of the formula ##STR45## in which R 1 and R 2 independently of one another are each hydrogen; alkyl of 1 to 7 carbon atoms unsubstituted or by hydroxyl, low-molecular alkoxy or carbalkoxy, phenoxy, cyano, carbonamido, halogen or acetoxy; cyclohexyl or methylcyclohexyl; benzyl, phenethyl, or β-phenyl-β-hydroxyethyl; unsubstituted phenyl or naphthyl or phenyl or naphthyl substituted by halogen, hydroxyl, cyano, rhodan, amino, phenylamino, phenyl, phenoxy, nitro, acetyl, acetoxy, acetylamino, benzoylamino or by alkyl, alkoxy, mono- and dialkyl amino or n-phenyl-n-alkylamino, wherein said alkyl residue is of 1-4 carbon atoms; X is ═NH or ═O; and R 6 is the radical ##STR46## in which Y is sulfur; T 12 is hydrogen, alkyl, halogen or alkoxy, and T 13 is hydrogen or alkyl.
Claim 3
Dependent Claim 33 words
A compound according to claim 1, wherein R 6 is benzothiazole or benzothiazole substituted by chlorine or methyl, which is bound in a position adjacent to a ring-nitrogen atom with the coumarin ring.
Claim 4
Dependent Claim 52 words
A compound according to claim 1, wherein R 1 and R 2 independently of one another are each methyl, ethyl or phenyl, X is oxygen, and R 6 is benzothiazole or benzothiazole substituted by methyl or chlorine, which is bound in a position adjacent to a ring-nitrogen atom to the coumarin ring.
Claim 5
Dependent Claim 10 words
A compound according to claim 1, wherein X is ═O.
Claim 6
Dependent Claim 30 words
A compound according to claim 1; wherein R 1 and R 2 independently of one another are each an alkyl of 1 to 4 carbon atoms or naphthalene or phenyl.
Claim 7
Dependent Claim 26 words
A compound according to claim 1, wherein R 1 and R 2 independently of one another are each methyl, ethyl or phenyl, and X is oxygen.
Claim 8
Dependent Claim 30 words
A compound according to claim 3, wherein R 1 and R 2 independently of one another are each methyl, ethyl or phenyl, X is oxygen, and R 6 is benzothiazole.
Claim 9
Dependent Claim 12 words
The compound according to claim 1, which is of the formula ##STR47##

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-10-28 1989-04-29 1989-10-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-10-28 1993-04-29 1993-10-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-10-28 1997-04-29 1997-10-29 $7700.00 Window Closed / Lapsed

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