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US4548737A Expired / Lapsed US ⏱️ 0.0 years remaining

Conducting polymers

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1984-04-06
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Granted: 1985-10-22
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Expires: 2004-04-06
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Abstract

Abstract An electrically conducting composition is described which comprises a polyarylene, e.g. polyphenylene, and a suitable doping agent, e.g. ferric chloride. The polyarylene is prepared from a poly(1,2-disubstitutedcyclohexa-3,5-diene).

Inventors

  • 👤 Denis G. H. Ballard
  • 👤 Kenneth T. Moran
  • 👤 Ian M. Shirley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 01:30
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; C08G61/02; C08G61/10; C08L65/02; H; H01; H01B; H01B1/00; H01B1/06; H01B1/12; H01B1/124; H01B1/128; C08G2261/00; C08G2261/30; C08G2261/31; C08G2261/312

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 226 words
An electrically conducting composition comprising: (a) a polyarylene of structure --(Ar).sub.n (X).sub.m wherein the residues Ar and X, where X is present, may vary from unit to unit in the polymer chain, Ar represents a divalent aromatic or substituted aromatic group, X is a residue of one or more polymerisable comonomers selected from the group consisting of styrene, methacrylates, vinyl halides, vinyl esters, acrylonitrile, tetrafluoroethylene, and sulphur dioxide, n and m are whole numbers and the ratio of n:m lies in the range of 1:0 to 1:100, which polyarylene is prepared from a poly(1,2-disubstituted cyclohexa-3,5-diene) of structure ##STR5## wherein the cyclohexenylene ring and the residue X, where X is present, may vary from unit to unit along the polymer chain, each z, which may be the same or different, is amide, halide, thioester, urethane, xanthate, or OR 1 , where R 1 is hydrogen, lower alkyl having up to five carbon atoms, aroyl, alkanoyl having up to ten carbon atoms or R 2 OCO where R 2 is aryl or alkyl having up to ten carbon atoms, X, n and m have the meanings above-ascribed to them; and (b) a suitable doping agent selected from the group consisting of Group IA metals, Group IA metal arenes, Bronsted acids, non-metal oxides, Group VB sulphides, and halides of Groups VB, VIA, IB, IIB, IVB and the inert gases.
Claim 2
Dependent Claim 226 words
An electrically conducting composition comprising: (a) a polyarylene of structure --(Ar).sub.n (X).sub.m wherein the residues Ar and X, where X is present, may vary from unit to unit in the polymer chain, Ar represents a divalent aromatic or substituted aromatic group, X is a residue of one or more polymerisable comonomers selected from the group consisting of styrene, methacrylates, vinyl halides, vinyl esters, acrylonitrile, tetrafluoroethylene, and sulphur dioxide, n and m are whole numbers and the ratio of n:m lies in the range of 1:0 to 1:100, which polyarylene is prepared from a poly(1,2-disubstituted cyclohexa-3,5-diene) of structure ##STR5## wherein the cyclohexenylene ring and the residue X, where X is present, may vary from unit to unit along the polymer chain, each z, which may be the same or different, is amide, halide, thioester, urethane, xanthate, or OR 1 , where R 1 is hydrogen, lower alkyl having up to five carbon atoms, aroyl, alkanoyl having up to ten carbon atoms or R 2 OCO where R 2 is aryl or alkyl having up to ten carbon atoms, X, n and m have the meanings above-ascribed to them; and (b) a suitable doping agent selected from the group consisting of Group IA metals, Group IA metal arenes, Bronsted acids, non-metal oxides, Group VB sulphides, and halides of Groups VB, VIA, IB, IIB, IVB and the inert gases.
Claim 3
Dependent Claim 11 words
A composition as claimed in claim 1 wherein Ar is phenylene.
Claim 4
Dependent Claim 11 words
A composition as claimed in claim 2 wherein m is O.
Claim 5
Dependent Claim 17 words
A composition as claimed in claim 1 in the form of a substantially continuous two dimensional solid.

References Cited (Backward Citations)

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US4375427A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-10-21 1989-04-22 1989-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-10-21 1993-04-22 1993-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-10-21 1997-04-22 1997-10-22 $7700.00 Window Closed / Lapsed

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