Liquid electrographic developers containing quaternary ammonium charge-control polymers having acidic monomers

Claim 2

A liquid electrographic developer comprosition comprising an electrically insulating liquid carrier containing (a) dispersed toner particles, (b) a charge-control agent comprising an addition copolymer of a quaternary ammonium salt monomer, a solubilizing monomer and an acidic insolubilizing monomer having an acidic function selected from the group consisting of --COOH, --SO 3 H and --PO 3 HR wherein R is hydrogen or alkyl, and the amount of solubilizing monomer is sufficient to render said charge-control agent soluble in said liquid carrier, and (c) a charging addition copolymer comprising a polar monomer and a solubilizing monomer which may be the same as or different from the solubilizing monomer in said charge-control agent, and is present in an amount sufficient to render said charging addition copolymer soluble in said carrier liquid.

Claim 3

A developer as in claim 1 wherein said acidic insolubilizing monomer is selected from the group consisting of acrylic acid, methacrylic acid, vinyl benzoic acid, styrene acetic acid, sulfoethyl methacrylamide, sulfoethyl methacrylate, styrene sulfonic acid, vinylbenzylethylphosphate, vinylbenzylphosphosphonic acid, vinylphosphonic acid and vinylethylphosphonate.

Claim 4

A developer as in claim 2 wherein said solubilizing monomer in (b) and (c) are independently selected from the group consisting of t-butylstyrene, 4-pentylstyrene, 4-hexylstyrene, 4-octylstyrene, p-amyloxystyrene, lauryl acrylate, lauryl methacrylate, hexadecyl methacrylate, octadecyl methacrylate, eicosyl acrylate, docosyl methacrylate, vinyl caprate, vinyl laurate, vinyl palmitate, vinyl stearate, vinyl eicosate and vinyl docosate, said quaternary ammonium salt monomer is selected from the group consisting of methacryloyloxyethyltrimethylammonium p-toluene sulfonate, dimethyloctadecylvinylbenzylammonium chloride, 2-vinyl-N-methylpyridinium methyl sulfate, N-methyl-N-methacryloyloxyethylpiperidinium bromide, and N-methacryloyloxyethylpyridinium nitrate, and said polar monomer is selected from the group consisting of sulfoethyl methacrylate, sulfoethyl acrylate; sulfopropyl methacrylate; sulfobutyl methacrylate; sulfoethyl methacrylate, sodium salt; sulfoethyl methacrylate, partial sodium salt; sulfopropyl methacrylate, sodium salt; sulfobutyl methacrylate, potassium salt; sulfoethyl methacrylate, lithium salt; sulfoethyl methacrylate, copper salt; sulfopropyl methacrylate, dimethylammonium salt; sulfoethyl methacrylate diethylammonium salt; sulfomethyl acrylate; dimethylammonium salt; sodium methacrylate; sodium acrylate; lithium methacrylate; potassium acrylate; barium methacrylate; zinc methacrylate; cobalt methacrylate; ferrous acrylate; magnesium methacrylate; and zinc acrylate.

Claim 5

A developer as in claim 1 wherein the concentrations of said toner of said charge-control agent, and of said charging agent, are each about 0.01 to about 5 percent, by weight of total developer.

Claim 6

A developer as in claim 4 wherein said concentrations are about 0.02 to about 0.5 percent.

Claim 7

A developer as in claim 1 wherein said toner comprises a neutral pH or basic pH colorant.

Claim 8

A developer as in claim 6 wherein said toner further comprises a polyesterionomer as a binder for said colorant.

Claim 9

A developer as in claim 6 wherein said charge-control agent is poly(t-butyl styrene-co-methacrylic acid-co-methacryloyloxyethyltrimethylammonium-p-toluene sulfonate) and said charging agent is poly(t-butyl styrene-co-lithium methacrylate) or poly(t-butyl styrene-co-lauryl methacrylate-co-lithium methacrylate-co-methacrylic acid).

Claim 10

A developer as in claim 1, 2, 3, 4, 5, 6, 7 or 8 comprising, in addition, a second electrically insulating carrier liquid.

Claim 11

A developer as in claim 9 wherein said charging agent is poly(t-butyl styrene-co-lithium methacrylate) and said electrically insulating carriers are an isoparaffinic hydrocarbon liquid and an alkylated aromatic liquid.