US4547318A
Expired / Lapsed
US
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Preparation of color-stable, light-colored, aqueous salt pastes of wash-active, α-sulfofatty acid esters
Assignee: Henkel AG and Co KGaA
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Filing: 1984-04-26
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Granted: 1985-10-15
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Expires: 2004-04-26
Abstract
Abstract This invention is directed to a process for the preparation of color-stable, light-colored aqueous salt pastes of wash-active esters of α-sulfofatty acids with monohydric C 1 -C 8 -alcohols by a combined bleaching treatment of dark-colored α-sulfofatty acid ester salt paste with hydrogen peroxide and alkali metal hypochlorite. According to the process, dark-colored α-sulfofatty acid ester salt paste is first subjected in a preliminary bleaching step to bleaching with alkali metal hypochlorite in a neutral to mildly alkaline aqueous medium, any excess metal hypochlorite is removed, and the paste is subjected in a final bleaching step to bleaching in a mildly acidic medium with hydrogen peroxide or with one or more compounds which yield hydrogen peroxide.
Inventors
- 👤 Dietrich Kloetzer
- 👤 Karl-Heinz Linde
- 👤 Klaus Ojust
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 13:47
CPC Classifications
C; C07; C07C; C07C303/00; C07C303/42; C11; C11D; C11D1/00; C11D1/02; C11D1/12; C11D1/28
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
216 words
A process for the preparation of color-stable, light-colored aqueous salt pastes of wash-active esters of α-sulfofatty acids with C 1 -C 8 -alkanols consisting essentially of the steps of (1) subjecting a dark-colored, wash-active α-sulfofatty acid ester with C 1 -C 8 -alkanols in the form of an alkali-metal salt paste containing from 20% to 60% by weight of said ester at a pH-value in the range of 7 to 11 and a temperature of from 50° to 75° C. to the action of from 0.1 to 4% by weight of an alkali metal hypochlorite based on wash-active substance (WAS) for a time sufficient to effect substantial bleaching, (2) removing the hypochlorite excess by lowering the pH-value to the range of from about 4.0 to 6.5 or by the addition of a reducing agent, of both, (3) subjecting the partially bleached paste to the action of from about 1 to 2.5% by weight of hydrogen peroxide, expressed as 100% H 2 O 2 and based on WAS, at a pH-value in the range of about 4.0 to 6.5 and a temperature of from 50° to 75° C. for a time sufficient to effect further bleaching, and (4) recovering a color-stable, light-colored aqueous salt paste of wash-active esters of α-sulfofatty acids with C 1 -C 8 -alkanols.
Claim 2
Dependent Claim
216 words
A process for the preparation of color-stable, light-colored aqueous salt pastes of wash-active esters of α-sulfofatty acids with C 1 -C 8 -alkanols consisting essentially of the steps of (1) subjecting a dark-colored, wash-active α-sulfofatty acid ester with C 1 -C 8 -alkanols in the form of an alkali-metal salt paste containing from 20% to 60% by weight of said ester at a pH-value in the range of 7 to 11 and a temperature of from 50° to 75° C. to the action of from 0.1 to 4% by weight of an alkali metal hypochlorite based on wash-active substance (WAS) for a time sufficient to effect substantial bleaching, (2) removing the hypochlorite excess by lowering the pH-value to the range of from about 4.0 to 6.5 or by the addition of a reducing agent, of both, (3) subjecting the partially bleached paste to the action of from about 1 to 2.5% by weight of hydrogen peroxide, expressed as 100% H 2 O 2 and based on WAS, at a pH-value in the range of about 4.0 to 6.5 and a temperature of from 50° to 75° C. for a time sufficient to effect further bleaching, and (4) recovering a color-stable, light-colored aqueous salt paste of wash-active esters of α-sulfofatty acids with C 1 -C 8 -alkanols.
Claim 3
Dependent Claim
21 words
The process of claim 1, wherein the α-sulfofatty acid esters are based upon fats and oils of vegetable and/or animal origin.
Claim 4
Dependent Claim
16 words
The process of claim 1, wherein the salt pastes comprise mixtures with wash-active alkyl benzene sulfonates.
Claim 5
Dependent Claim
22 words
The process of claim 1, wherein the preliminary bleaching treatment is terminated at about the time the optimum bleaching effect is reached.
Claim 6
Dependent Claim
24 words
The process of claim 1, wherein the pH-value of said step (1) bleaching treatment is in the range of from about 7.5 to 10.
Claim 7
Dependent Claim
24 words
The process of claim 1, wherein the alkali metal hypochlorite used comprises from about 0.1 to 3% by weight of NaOCl, based upon WAS.
Claim 8
Dependent Claim
29 words
The process of claim 1, wherein a reducing agent is added and is selected from the group consisting of formaldehyde, alkali metal sulfites, alkali metal thio-sulfates, and mixtures thereof.
Claim 9
Dependent Claim
21 words
The process of claim 1, wherein the pH-value of said step (3) bleaching treatment is adjusted by addition of sulfuric acid.
Claim 10
Dependent Claim
32 words
The process of claim 1, wherein the hydrogen peroxide is used in quantities of from about 1 to 2% by weight, expressed as 100% H 2 O 2 and based upon WAS.
Claim 11
Dependent Claim
30 words
The process of claim 1, wherein from approximately 10 to 15% by weight NaOCl solutions and from approximately 20 to 70% by weight H 2 O 2 solutions are used.
Claim 12
Dependent Claim
35 words
The process of claim 1, wherein the hypochlorite bleaching treatment is carried out at temperatures in the range of from about 50° to 75° C. over a period of from about 1 to 10 hours.
Claim 13
Dependent Claim
19 words
The process of claim 11, wherein the temperatures are in the range of from about 55° to 70° C.
Claim 14
Dependent Claim
21 words
The process of claim 11, wherein the treatment is carried out over a period of from about 1 to 3 hours.
Claim 15
Dependent Claim
25 words
The process of claim 1, wherein the alkali metal hypochlorite removal step and the final bleaching treatment are carried out at temperatures above 50° C.
Claim 16
Dependent Claim
32 words
The process of claim 14, wherein the alkali metal hypochlorite removal step and the final bleaching treatment are carried out at temperatures in the range of from about 55° to 70° C.
Claim 17
Dependent Claim
14 words
The process of claim 1, wherein the process is carried out at atmospheric pressure.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-10-14 | 1989-04-15 | 1989-10-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-10-14 | 1993-04-15 | 1993-10-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-10-14 | 1997-04-15 | 1997-10-15 | $7700.00 | Window Closed / Lapsed |