US4544607A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Engine parts
Assignee: NGK Insulators Ltd
•
Filing: 1984-04-04
•
Granted: 1985-10-01
•
Expires: 2004-04-04
Abstract
Abstract This invention relates to engine parts having high durability, which can be used at high operating temperatures. The engine parts comprise component members consisting mainly of the partially stabilized zirconia having high strength which is excellent in thermal insulation and mechanical strength. As the partially stabilized zirconia having high strength, use is made of ones in which thermal expansion hysteresis (difference of thermal expansion at an optional temperature in the thermal expansion during heating up and the thermal shrinkage during cooling down) is less than 0.4% and thermal expansion coefficient is more than 10×10 -6 /°C. The preferable engine parts having higher durability and reliability comprise component members consisting of a ceramic-metal composite body wherein the partially stabilized zirconia having a difference of thermal expansion coefficient being less than 3×10 -6 /°C. and a metal are bonded.
Inventors
- 👤 Masayuki Kaneno
- 👤 Isao Oda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 11:46
CPC Classifications
F; F02; F02F; F02F7/00; F02F7/0085; F02F7/0087; C; C04; C04B; C04B35/00; C04B35/01; C04B35/48; C04B35/486; C04B35/488; F02F1/00; F02F1/004; F02F1/24; F02F3/00; F02F3/0015; F02F3/0084; F02F3/02; F02F3/04; F02F3/045; F02F3/10; F02F3/12; F02F3/14; F02B; F02B1/00; F02B1/02; F02B1/04; F02B3/00; F02B3/06; F02F2001/008; F05; F05C; F05C2201/00; F05C2201/04; F05C2201/0433; F05C2201/0448; F05C2203/00; F05C2203/08; F05C2203/0865; F05C2203/0895; F05C2251/00; F05C2251/04; F05C2251/042
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
113 words
A ceramic engine part which consists essentially of partially stabilized zirconia and a metal part bonded thereto, said partially stabilized zirconia consisting of a monoclinic crystal phase of zirconia in an amount less than 10% and either a tetragonal crystal phase of zirconia or a mixture of a tetragonal crystal phase of zirconia and a cubic phase of zirconia, and having a four point bending strength of at least 50 kg/mm 2 , and a thermal expansion hysteresis which provides for a maximum difference in expansion percents of 0.4% existing between the thermal expansion heating curve and the thermal expansion cooling curve at any temperature occurring between room temperature and approximately 1000° C.
Claim 2
Dependent Claim
113 words
A ceramic engine part which consists essentially of partially stabilized zirconia and a metal part bonded thereto, said partially stabilized zirconia consisting of a monoclinic crystal phase of zirconia in an amount less than 10% and either a tetragonal crystal phase of zirconia or a mixture of a tetragonal crystal phase of zirconia and a cubic phase of zirconia, and having a four point bending strength of at least 50 kg/mm 2 , and a thermal expansion hysteresis which provides for a maximum difference in expansion percents of 0.4% existing between the thermal expansion heating curve and the thermal expansion cooling curve at any temperature occurring between room temperature and approximately 1000° C.
Claim 3
Dependent Claim
24 words
The ceramic engine part of claim 1, wherein the partially stabilized zirconia is press-fitted into the metal part to form a ceramic-metal composite body.
Claim 4
Dependent Claim
28 words
The ceramic engine part of claim 1, wherein the partially stabilized zirconia is bonded by a bonding layer to the metal part to form a ceramic-metal composite body.
Claim 5
Dependent Claim
28 words
The ceramic engine part of claim 1, wherein the partially stabilized zirconia is press-fitted by a bonding layer of the metal part to form a ceramic-metal composite body.
Claim 6
Dependent Claim
21 words
The ceramic engine part of claim 1, wherein the partially stabilized zirconia has a polished surface of less than 10 μm.
Claim 7
Dependent Claim
21 words
The ceramic engine part of claim 1, wherein the partially stabilized zirconia has a polished surface of less than 1 μm.
Claim 8
Dependent Claim
151 words
A ceramic engine part which consists essentially of partially stabilized zirconia and a metal part bonded thereto, said partially stabilized zirconia consisting of a monoclinic crystal phase of zirconia in an amount of less than 10% and either a tetragonal crystal phase of zirconia or a mixture of a tetragonal crystal phase of zirconia and a cubic crystal phase of zirconia, and having a four point bend test strength of at least 50 kg/mm 2 , a thermal expansion hysteresis which provides for a maximum difference in expansion percents of 0.4% existing between the thermal expansion heating curve and the thermal expansion cooling curve at any temperature occurring between room temperature and approximately 1,000° C., and a thermal expansion coefficient of greater than 10×10 -6 /°C., wherein said thermal expansion coefficient of said partially stablized zirconia differs from a thermal expansion coefficient of said metal by less than 3×10 -6 /°C.
Claim 9
Dependent Claim
151 words
A ceramic engine part which consists essentially of partially stabilized zirconia and a metal part bonded thereto, said partially stabilized zirconia consisting of a monoclinic crystal phase of zirconia in an amount of less than 10% and either a tetragonal crystal phase of zirconia or a mixture of a tetragonal crystal phase of zirconia and a cubic crystal phase of zirconia, and having a four point bend test strength of at least 50 kg/mm 2 , a thermal expansion hysteresis which provides for a maximum difference in expansion percents of 0.4% existing between the thermal expansion heating curve and the thermal expansion cooling curve at any temperature occurring between room temperature and approximately 1,000° C., and a thermal expansion coefficient of greater than 10×10 -6 /°C., wherein said thermal expansion coefficient of said partially stablized zirconia differs from a thermal expansion coefficient of said metal by less than 3×10 -6 /°C.
References Cited (Backward Citations)
US4360598A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-30 | 1989-04-01 | 1989-10-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-30 | 1993-04-01 | 1993-10-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-30 | 1997-04-01 | 1997-10-01 | $7700.00 | Window Closed / Lapsed |