Reverse osmosis membrane quenching

Claim 1

A process for preparing permselective membranes comprising the steps of casting a film or hollow fiber from a solution including: (a) synthetic organic nitrogen-linked aromatic polymer represented by the formula: --(LR).sub.2 -- where (1) each L independently is a divalent linking group of the formula --(D i E j D k E l D m )-- wherein (i) D is ##STR9## and E is ##STR10## or vice versa: each X independently is O or S; each Z independently is H, lower alkyl, or phenyl, provided that at least about 1/4 of the Z's in the polymer are H; and all non-terminal ##STR11## occur in pairs; (ii) i and j each represent the numerals 1 or 2, k, l, and m each represent the numerals 0, 1, or 2; provided that if l=0; then m=0; and if k=0, then l=0; and further that i+j+k+l+m≦8; (2) each R independently is a divalent organic radical, both of whose terminal atoms are carbon atoms, at least about 1/2 of all such terminal atoms bonded to ##STR12## and at least about 2/3 of all such terminal atoms bonded to ##STR13## and the L links being members of aromatic nuclei; and such that (i) (N R )/(s) is less than about 10, (ii) f M is less than about 1/5, and (iii) P.I. is less than about 1/500, where: N R =N R °-10N 1 --N H N R °=(number of atoms in R, exclusive of H-atoms) 50 N 1 =number of ionic groups in R N H =number of H-bonding units contributed by polar groups in R N R =average value of N R for the polymer, s=1/2[(number of ##STR14## groups in L)+1] ##EQU2## (3) n is an integer sufficiently large to provide film-forming molecular weight; and (4) the polymer has a solubility of at least about 10% by weight in a medium consisting of 0-3% by weight of lithium chloride in a solvent selected from the group consisting of dimethylacetamide, dimethyl sulfoxide, N-methyl pyrrolidone, hexamethyl phosphoramide, and mixtures thereof at 25° C.; and (b) organic solvent for the polymer; contacting the cast film or hollow fiber with an aqueous quenching liquid for a period of about from 5 seconds to 15 minutes, the quenching liquid comprising about from 5 to 50 weight percent of at least one polar liquid selected from the group consisting of carbonyl compounds of the general formula ##STR15## wherein A is H, NH 2 , CH 3 , or CH 2 CH 3 and B is OH, NH 2 , or CH 3 ; and then immersing the quenched film or hollow fiber in water for a time necessary to extract substantially all of the polar liquid from the film or hollow fiber.