Application of ambient temperature cured polymers or prepolymers to a cured elastomer

Claim 2

A process for applying an amine curable polymer or prepolymer to a cured rubber substrate having unsaturated groups therein, comprising the steps of: applying a treating agent to said rubber substrate, said treating agent selected from the group consisting of N-halohydantoins, N-haloamides, N-haloimides, and combinations thereof, applying a polyisocyanate to said treating agent, said polyisocyanate having the formula R(N═C═X) n where R is an alkyl having from 2 to 20 carbon atoms, a cycloalkyl having from 4 to 20 carbon atoms, an aromatic or an alkyl substituted aromatic having from 6 to 20 carbon atoms, where n is 2 or 3, and where X is oxygen or sulfur, applying an ambient temperature amine curable polymer or prepolymer system to said rubber substrate, and curing said amine curable polymer or prepolymer at an ambient temperature.

Claim 3

A process according to claim 1, wherein said rubber substrate is made from monomers selected from the group consisting of (a) conjugated dienes having from 4 to 12 carbon atoms, copolymers thereof, and interpolymers thereof, (b) natural rubber, (c) copolymers made from vinyl substituted aromatic compounds having from 8 to 15 carbon atoms and conjugated diene compounds having from 4 to 12 carbon atoms, (d) elastomers made from monomers of isobutylene and isoprene, (e) elastomers made from monomers of butadiene and acrylonitrile, (f) elastomers made from monomers of chloroprene, and (g) combinations thereof, and wherein said amine curable polymer or prepolymer system comprises an amine curable polymer or prepolymer, an amine curing agent, and a polar solvent, wherein said polar solvent is selected from (a) compounds having dipole moments in excess of 0.4 debye in which there are no more than a total of 8 CH 3 --, CH 2 , or tertiary carbon radicals per polar group contained in said compounds, and (b) benzene and biphenyl; and said amine curable polymer or prepolymer is selected from the group consisting of (a) epoxy resins; (b) halogen-containing hydrocarbon polymers; (c) chlorosulfonated polymers; (d) polymers containing acid halide groups such as ##STR3## or haloformate groups such as ##STR4## (e) polymers containing anhydride groups which, on reaction with diamines, yield amide-acid linkages; (f) organopolysiloxanes; (g) urethane polymers or prepolymers; and combinations thereof.

Claim 4

A process according to claim 2, including applying said amine curable polymer or prepolymer in liquid form.

Claim 5

A process according to claim 3, wherein said amine curable polymer or prepolymer is said urethane polymer or prepolymer, and wherein in said polyisocyanate formula, n is 2 and X is oxygen.

Claim 6

A process according to claim 4, wherein said treating agent is selected from the group consisting of 1,3-dichloro-5,5-dimethyl hydantoin; 1,3-dibromo-5,5-dimethyl hydantoin; 1,3-dichloro-5-methyl-5-isobutyl hydantoin; 1,3-dichloro-5-methyl-5-hexyl hydantoin; N-bromoacetamide; tetrachloroglycoluril; and N-bromosuccinimide; and wherein said polar solvent ranges from about 2 to about 40 parts per 100 parts of said prepolymer or polymer and is selected from the group consisting of esters, ketones, ethers, halogenated hydrocarbons, tertiary amines, nitrile paraffins, fully substituted amides, sulfones, sulfoxides, and sulfides.

Claim 7

A process according to claim 5, wherein said treating agent is selected from the group consisting of monochloroisocyanuric acid, dichloroisocyanuric acid, trichloroisocyanuric acid, and combinations thereof, and including covering said amine curable polymer or prepolymer during cure.

Claim 8

A process according to claim 6, wherein said polyisocyanate is toluene diisocyanate.

Claim 9

A process according to claim 7, wherein said rubber substrate is selected from the group consisting of polybutadiene, natural and synthetic cis-1,4-polyisoprene, and styrene-butadiene rubber, wherein said polar solvent is selected from the group consisting of dimethylformamide, tetrahydrofuran, cyclohexanone, ethyl acetate, methyl ethyl ketone, and acetone, wherein said amine curing agent is selected from the group consisting of (a) 4,4'-methylene bis(2-chloraniline), (b) a complex of 4,4'-methylene dianiline and a salt, said salt being selected from the group consisting of sodium chloride, sodium bromide, sodium iodide, sodium nitrite, lithium chloride, lithium bromide, lithium iodide, lithium nitrite, and sodium cyanide, (c) a complex of racemic 2,3-di-4(aminophenyl)butane with a salt, said salt selected from the group consisting of sodium chloride, sodium bromide, sodium iodide, potassium chloride, potassium bromide, potassium iodide, cesium chloride, cesium bromide, and cesium iodide, the ratio of said dianiline or said butane to said salt in said complex being 3 moles to 1 mole, the equivalent amount of said curing agent based upon said prepolymer or polymer ranging from about 0.85 to about 1.05 equivalents.

Claim 10

A process according to claim 7, wherein said rubber substrate is a tire having a gouge or opening therein and including repairing said tire.

Claim 11

A process according to claim 7, wherein said rubber substrate is a hose or belt having a gouge or opening therein and including repairing said belt or hose.