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US4540049A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of improving steam flood conformance with steam flooding agents without a non-condensable gas

Assignee: Texaco Development Corp
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Filing: 1984-08-08
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Granted: 1985-09-10
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Expires: 2004-08-08
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Abstract

Abstract The disclosed invention is a group of novel steam foaming agents for injection with steam to decrease permeability in steam sept zones. They are effective without the coinjection on a non-condensable gas. The foaming agents have the general formula: RO(R'O)nR''SO3M where R is an alkyl radical, branched or linear, having from about 15 to about 21 carbon atoms in the alkyl chain, R' is ethyl or propyl, n has an average value of about 2 to about 5, R'' is ethyl, propyl, hydroxypropyl or butyl and M is an alkali metal or ammonium ion.

Inventors

  • 👤 Jeffrey T. Hawkins
  • 👤 Zean Z. Gassmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 08:35
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/92; C09K8/94; C09K8/58; C09K8/592; E; E21; E21B; E21B43/00; E21B43/16; E21B43/24; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 144 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting steam into an injection well; injecting into the injection well a mixture of steam and about 0.01% to about 5% by weight of a foaming agent based upon the weight of the steam in the injected mixture, said foaming agent represented by the formula, RO(R'O).sub.n R"SO.sub.3.sup.- M.sup.+, where R is an alkyl radical, branched or linear, having from about 15 to about 21 carbon atoms in the alkyl chain, R' is ethyl or propyl, n has an average value of about 2 to about 5, R" is ethyl, propyl, hydroxypropyl or butyl, and M + is an alkali metal or ammonium ion; injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.
Claim 2
Dependent Claim 144 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting steam into an injection well; injecting into the injection well a mixture of steam and about 0.01% to about 5% by weight of a foaming agent based upon the weight of the steam in the injected mixture, said foaming agent represented by the formula, RO(R'O).sub.n R"SO.sub.3.sup.- M.sup.+, where R is an alkyl radical, branched or linear, having from about 15 to about 21 carbon atoms in the alkyl chain, R' is ethyl or propyl, n has an average value of about 2 to about 5, R" is ethyl, propyl, hydroxypropyl or butyl, and M + is an alkali metal or ammonium ion; injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.
Claim 3
Dependent Claim 18 words
The process of claim 1 for recovering hydrocarbons, wherein said mixture is injected into a steam override zone.
Claim 4
Dependent Claim 44 words
The process of claim 1 for recovering hydrocarbons wherein R is an alkyl radical having about 16 to about 18 carbon atoms, R' is ethyl, n has an average value of about 3 to about 4, R" is propyl and M + is sodium.
Claim 5
Dependent Claim 41 words
The process of claim 1 for recovering hydrocarbons, wherein R is an alkyl radical having about 16 to about 20 carbon atoms, R' is ethyl, n has an average value of about 3, R" is propyl and M + is sodium.
Claim 6
Dependent Claim 26 words
The process of claim 1 for recovering hydrocarbons, wherein the concentration of said foaming agent in steam is increased as the steam injection rate is increased.
Claim 7
Dependent Claim 23 words
The process of claim 1 for recovering hydrocarbons, wherein said mixture is injected into an injection well near the beginning of steam injection.
Claim 8
Dependent Claim 26 words
The process of claim 1 for recovering hydrocarbons, wherein said mixture is injected into an injection well immediately prior to steam breakthrough at a production well.
Claim 9
Dependent Claim 24 words
The process of claim 1 for recovering hydrocarbons, wherein said mixture is injected into an injection well after steam breakthrough at a production well.
Claim 10
Dependent Claim 138 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting into an injection well a mixture of steam and about 0.01% to about 5% by weight of a foaming agent based upon the weight of the steam in the injected mixture, said foaming agent represented by the formula, RO(R'O).sub.n R"SO.sub.3.sup.- M.sup.+, where R is an alkyl radical, branched or linear, having from about 15 to about 21 carbon atoms in the alkyl chain, R' is ethyl or propyl, n has an average value of about 2 to about 5, R" is ethyl, propyl, hydroxypropyl or butyl, and M + is an alkali metal or ammonium ion; injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.
Claim 11
Dependent Claim 138 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting into an injection well a mixture of steam and about 0.01% to about 5% by weight of a foaming agent based upon the weight of the steam in the injected mixture, said foaming agent represented by the formula, RO(R'O).sub.n R"SO.sub.3.sup.- M.sup.+, where R is an alkyl radical, branched or linear, having from about 15 to about 21 carbon atoms in the alkyl chain, R' is ethyl or propyl, n has an average value of about 2 to about 5, R" is ethyl, propyl, hydroxypropyl or butyl, and M + is an alkali metal or ammonium ion; injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.
Claim 12
Dependent Claim 80 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting into an injection well a mixture of steam and about 0.02% to about 1.5% by weight of a foaming agent based upon the weight of steam in the injected mixture, said foaming agent represented by the formula, ##STR3## injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.
Claim 13
Dependent Claim 80 words
A process for recovering hydrocarbons from an underground hydrocarbon formation penetrated by at least one injection well and at least one production well, which comprises: injecting into an injection well a mixture of steam and about 0.02% to about 1.5% by weight of a foaming agent based upon the weight of steam in the injected mixture, said foaming agent represented by the formula, ##STR3## injecting steam into said injection well; and recovering hydrocarbons and other fluids at a production well.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-09-09 1989-03-11 1989-09-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-09-09 1993-03-11 1993-09-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-09-09 1997-03-11 1997-09-10 $7700.00 Window Closed / Lapsed

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