US4538348A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Molten carbonate fuel cell matrix tape and assembly method
Assignee: RTX Corp
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Filing: 1983-11-07
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Granted: 1985-09-03
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Expires: 2003-11-07
Abstract
Abstract A matrix material for a molten carbonate fuel cell is described which is flexible, pliable and has rubber-like compliance at room temperature. The matrix has three components comprising fine inert particulate material, larger crack attenuating ceramic particulate material, and an organic polymeric binder. A process of assembling a molten carbonate fuel cell utilizing the compliant matrix material is also described. The compliant matrix material is inserted into a molten carbonate fuel cell stack utilizing fuel cell anodes with sufficient porosity to contain excess electrolyte. The fuel cell is heated up to a temperature sufficient to remove the polymer binder and cause a portion of the electrolyte material present in the anode to wick into the matrix to substantially fill it completely.
Inventors
- 👤 Raymond W. Vine
- 👤 Craig R. Schroll
- 👤 Carl A. Reiser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 10:56
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/02; H01M8/0289; H01M8/0295; H01M8/14; H01M8/141; H01M8/142; H01M2008/147; H01M2300/00; H01M2300/0017; H01M2300/0048; H01M2300/0051; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02E60/30; Y02E60/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
133 words
In the process of assembling a molten carbonate fuel cell including forming a fuel cell stack by stacking a plurality of electrodes separated by layers of matrix material, wherein the improvement comprises: inserting as the matrix material a matrix comprising particles inert to molten carbonate electrolyte having a particle size less than about one micron, ceramic particles having a particle size greater than about 25 microns, and an organic polymer binder material, the binder material being present in an amount of at least about 35% by volume, the matrix material being flexible, pliable, and compliant at room temperature, into the fuel cell stack, and utilizing as the fuel cell anode, an anode with sufficient porosity to contain sufficient electrolyte for continuous operation of the molten carbonate fuel cell for at least 40,000 hours.
Claim 2
Dependent Claim
133 words
In the process of assembling a molten carbonate fuel cell including forming a fuel cell stack by stacking a plurality of electrodes separated by layers of matrix material, wherein the improvement comprises: inserting as the matrix material a matrix comprising particles inert to molten carbonate electrolyte having a particle size less than about one micron, ceramic particles having a particle size greater than about 25 microns, and an organic polymer binder material, the binder material being present in an amount of at least about 35% by volume, the matrix material being flexible, pliable, and compliant at room temperature, into the fuel cell stack, and utilizing as the fuel cell anode, an anode with sufficient porosity to contain sufficient electrolyte for continuous operation of the molten carbonate fuel cell for at least 40,000 hours.
Claim 3
Dependent Claim
50 words
The process of claim 1 including heating the fuel cell stack containing the matrix and anode to a temperature for a time sufficient to remove the polymer binder and cause at least a portion of the electrolyte material in the anode to wick into and substantially completely fill the matrix.
Claim 4
Dependent Claim
92 words
The process of claim 2 wherein the stack is heated from room temperature up to 205° C. at a rate of 40° C. per hour, held at 205° C. for 6 hours, then heated to 315° C. at a rate of 40° C. per hour and held at 315° C. for 6 hours, and then heated to 470° C. at a rate of 40° C. per hour and held at 470° C. for 2 hours, before being raised above the electrolyte melt temperature to a stack operating temperature of approximately 650° C.
Claim 5
Dependent Claim
35 words
The process of claim 1 wherein the inert particles are present in about 40% to about 45% by volume and the ceramic particles are present in an amount of at least about 15% by volume.
Claim 6
Dependent Claim
11 words
The process of claim 1 wherein the polymer is polyvinyl butyral.
Claim 7
Dependent Claim
12 words
The process of claim 1 wherein the inert material is lithium aluminate.
Claim 8
Dependent Claim
11 words
The process of claim 1 wherein the ceramic particles are alumina.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-02 | 1989-03-04 | 1989-09-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-02 | 1993-03-04 | 1993-09-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-02 | 1997-03-04 | 1997-09-03 | $7700.00 | Window Closed / Lapsed |