Activated sludge wastewater treating process

Claim 2

An activated sludge process for treating wastewater containing ammonia as a contaminant and further other wastewater contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials, to achieve substantially complete nitrificiation of said ammonia into nitrite and/or nitrate and substantially complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising microbially treating the wastewater in an activated sludge process in the presence of a microorganism population acclimated to the wastewater contaminants and their levels in the wastewater and including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, under the following conditions: (1) controlling the sludge wastage rate to the extent that, for the wastewater fed during the treatment and at the conditions at which the treatment is operated, the sludge wastage rate (i) is low enough to provide and maintain a steady state population of microorganisms capable of converting ammonia to nitrite and/or nitrate and yet (ii) is high enough to prevent buildup of inert solids in the sludge; (2) controlling the hydraulic residence time of the wastewater in treatment such that the hydraulic residence time is (i) long enough to produce a sludge concentration that can be water/solid separated at the sludge wastage rate of (1) above, and (ii) long enough to achieve substantially full sludge performance; (3) maintaining a dissolved oxygen level on a continuous or weighted average basis, (i) sufficiently high that microbial conversion of ammonia to nitrite and/or nitrate occurs but (ii) lower than the dissolved oxygen level at which microbial conversion of nitrite and/or nitrate to free nitrogen ceases to occur; (4) mixing the sludge (i) to the extent that the sludge mixing rate achieves utilization of sludge present during treatment so as to avoid causing a sludge growth rate which would result in exceeding the maximum allowable sludge wastage rate of (1) above, and (ii) to the extent that the sludge mixing rate is large enough to reduce gradients in levels of bulk dissolved oxygen to a level consistent with the denitrification desired for the wastewater treatment, yet (iii) to the extent that the sludge mixing rate is below the rate at which microbial cell rupture occurs, irreversible breakup of agglomerates of sludge occurs, and/or sludge/water settleability characteristics are not deteriorated; (5) controlling the biological oxygen demand during treatment such that at least the stoichiometric amount of biological oxygen demand required to achieve denitrification by microbial conversion of nitrite and/or nitrate to free nitrogen during treatment at a particular concentration of ammonia in the wastewater fed for treatment is present; (6) controlling the pH of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during treatment is avoided, yet (iii) in a hospitable range for microorganism growth and effective waste treatment of waste in the wastewater; and (7) controlling the temperature of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during the treatment is avoided, yet (iii) in a hospitable range for microorganism action on and effective treatment of the waste in the wastewater.

Claim 3

The activated sludge process of claim 1, wherein said nitrifying microorganisms capable of converting ammonia to nitrite are Nitrosomonas microorganisms, said nitrifying microorganisms capable of converting nitrite to nitrate are Nitrobacter microorganisms and said facultative microorganisms are microorganisms of the genera Pseudomonas, Achromobacter, Bacillus, Micrococcus or mixtures thereof.

Claim 4

The activated sludge process of claim 1, wherein said microorganism population additionally includes sulfur acting microorganisms and cyanide acting microorganisms.

Claim 5

The activated sludge process of claim 1, wherein said controlling of the sludge wastage rate comprises controlling the sludge wastage rate within the range of (a) a Minimum Sludge Wastage Rate and (b) a Maximum Sludge Wastage Rate, said Minimum Sludge Wastage Rate and said Maximum Sludge Wastage Rate being defined in accordance with equations (A) to (D) below: ##EQU3## where the Maximum Sludge Wastage Rate is the smallest of the Sludge Wastage Rates for all of the types of microorganisms present, ##EQU4##

Claim 6

The activated sludge process of claim 4, wherein said controlling of the sludge wastage rate is within about 20% above said Minimum Sludge Wastage Rate (a) to about 20% below said Maximum Sludge Wastage Rate (b).

Claim 7

The activated sludge process of claim 5, wherein said controlling of the sludge wastage rate is within about 40% above said Minimum Sludge Wastage Rate (a) to about 40% below said Maximum Sludge Wastage Rate.

Claim 8

The activated sludge process of claim 6, wherein said controlling of the sludge wastage rate is to substantially a zero sludge wastage rate.

Claim 9

The activated sludge process of claim 1, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 35 days.

Claim 10

The activated sludge process of claim 8, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 20 days.

Claim 11

The activated sludge process of claim 9, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 10 days.

Claim 12

The activated sludge process of claim 10, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of 5 days or less.

Claim 13

The activated sludge process of claim 1, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 2 mg/l, achieved on a continuous or weighted average basis.

Claim 14

The activated sludge process of claim 12, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 1.5 mg/l, achieved on a continuous or weighted average basis.

Claim 15

The activated sludge process of claim 13, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 1 mg/l, achieved on a continuous or weighted average basis.

Claim 16

The activated sludge process of claim 1, wherein the pH and temperature are maintained such that the free ammonia concentration and the nitrous acid concentration at the temperature of the treatment is no greater than the equivalent free ammonia concentration and nitrous acid concentration as defined by the limits of Zone 3 in FIG. 7 at 20° C.

Claim 17

The activated sludge process of claim 15, wherein the nitrous acid concentration is about 0.2 mg/l or less.

Claim 18

The activated sludge process of claim 4, wherein said mixing of the sludge is to a mixing rate allowing about 80% of said Maximum Sludge Wastage Rate to said Maximum Sludge Wastage Rate.

Claim 19

The activated sludge process of claim 17, wherein said mixing of the sludge is to a mixing rate allowing about 60% to less than about 80% of the Maximum Sludge Wastage Rate.

Claim 20

The activated sludge process of claim 18, wherein said mixing of the sludge is to a mixing rate allowing about 40% to less than about 60% of the Maximum Sludge Wastage Rate.

Claim 21

The activated sludge process of claim 19, wherein said mixing of the sludge is to a mixing rate allowing substantially a zero sludge wastage rate.

Claim 22

The activated sludge process of claim 1, wherein said controlling of the biological oxygen demand is to an extent that the BOD to N ratio is at least about 1.7:1 to about 2.8:1 or more.

Claim 23

The activated sludge process of claim 21, wherein said controlling of the biological oxygen demand is to an extent that the BOD to N ratio is at least about 2.8:1 or more.

Claim 24

The activated sludge process of claim 1, wherein said controlling of the pH is to a pH range of about 6 to about 8.

Claim 25

The activated sludge process of claim 23, wherein said controlling of the pH is to a pH range of about 6.5 to about 7.5.

Claim 26

The activated sludge process of claim 24, wherein said controlling of the pH is to a pH range of about 6.8 to about 7.3.

Claim 27

The activated sludge process of claim 1, wherein said controlling of the temperature is to a temperature of about 35° C. or below.

Claim 28

The activated sludge process of claim 26, wherein said controlling of the temperature is to a range of about 5° C. to about 35° C.

Claim 29

The activated sludge process of claim 27, wherein said controlling of the temperature is to a range of about 10° C. to about 25° C.

Claim 30

The activated sludge process of claim 28, wherein said controlling of the temperature is to a range of about 15° C. to about 25° C.

Claim 31

The activated sludge process of claim 1, wherein said wastewater microbially treated has an ammonia concentration of about 300 mg/l or higher.

Claim 32

The activated sludge process of claim 30, wherein said wastewater microbially treated has an ammonia concentration of about 500 mg/l or higher.

Claim 33

The activated sludge process of claim 30, wherein said wastewater microbially treated has an ammonia concentration of about 1000 mg/l or higher.

Claim 34

The activated sludge process of claim 30, wherein said wastewater microbially treated has an ammonia concentration of about 3000 mg/l or higher.

Claim 35

An activated sludge process for treating wastewater containing ammonia as a contaminant and further other wastewater contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials to achieve complete nitrification of said ammonia into nitrite and/or nitrate and less than complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising microbially treating the wastewater in an activated sludge process in the presence of a microorganism population acclimated to the wastewater contaminants and their levels in the wastewater and including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, under the following conditions: (1) controlling the sludge wastage rate to the extent that, for the wastewater fed during the treatment and at the conditions at which the treatment is operated, the sludge wastage rate (i) is low enough to provide and maintain a steady state population of microorganisms capable of converting ammonia to nitrite and/or nitrate, yet (ii) is high enough to prevent buildup of inert solids in the sludge; (2) controlling the hydraulic residence time of the wastewater in treatment such that the hydraulic residence time is (i) long enough to produce a sludge concentration that can be water/solid separated at the sludge wastage rate of (1) above, (ii) long enough to achieve substantially full sludge performance; (3) maintaining a dissolved oxygen level, on a continuous or weighted average basis, sufficiently high that microbial conversion of ammonia to nitrite and/or nitrate and of biological oxygen demand if present, to carbon dioxide and water occurs; (4) mixing the sludge (i) to the extent that the sludge mixing rate achieves utilization of sludge present during treatment so as to avoid causing a sludge growth rate which would result in exceeding the maximum allowable sludge wastage rate of (1) above, (ii) to the extent that the sludge mixing rate is large enough to reduce gradients in levels of bulk dissolved oxygen to a level consistent with the level of denitrification desired for the wastewater treatment, yet (iii) to the extent that the sludge mixing rate is below the rate at which microbial cell rupture occurs, irreversible breakup of agglomerates of sludge occurs and/or sludge/water settleability characteristics are not deteriorated; (5) controlling the biological oxygen demand during treatment such that (i) at least the stoichiometric amount of biological oxygen demand required to achieve a specified level of denitrification by microbial conversion of nitrite and/or nitrate to free nitrogen during treatment at a particular concentration of ammonia in the wastewater fed for treatment is present; and (ii) in the case of substantially no denitrification, controlling the treatment so as to simply provide a source of assimilable carbon for the microorganism population present; (6) controlling the pH of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, yet (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity, during treatment is avoided, yet (iii) in a hospitable range for microorganism growth and effective treatment of waste in the wastewater; and (7) controlling the temperature of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during the treatment is avoided, yet (iii) in a hospitable range for microorganism action on and effective treatment of the waste in the wastewater.

Claim 36

An activated sludge process for treating wastewater containing ammonia as a contaminant and further other wastewater contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials to achieve complete nitrification of said ammonia into nitrite and/or nitrate and less than complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising microbially treating the wastewater in an activated sludge process in the presence of a microorganism population acclimated to the wastewater contaminants and their levels in the wastewater and including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, under the following conditions: (1) controlling the sludge wastage rate to the extent that, for the wastewater fed during the treatment and at the conditions at which the treatment is operated, the sludge wastage rate (i) is low enough to provide and maintain a steady state population of microorganisms capable of converting ammonia to nitrite and/or nitrate, yet (ii) is high enough to prevent buildup of inert solids in the sludge; (2) controlling the hydraulic residence time of the wastewater in treatment such that the hydraulic residence time is (i) long enough to produce a sludge concentration that can be water/solid separated at the sludge wastage rate of (1) above, (ii) long enough to achieve substantially full sludge performance; (3) maintaining a dissolved oxygen level, on a continuous or weighted average basis, sufficiently high that microbial conversion of ammonia to nitrite and/or nitrate and of biological oxygen demand if present, to carbon dioxide and water occurs; (4) mixing the sludge (i) to the extent that the sludge mixing rate achieves utilization of sludge present during treatment so as to avoid causing a sludge growth rate which would result in exceeding the maximum allowable sludge wastage rate of (1) above, (ii) to the extent that the sludge mixing rate is large enough to reduce gradients in levels of bulk dissolved oxygen to a level consistent with the level of denitrification desired for the wastewater treatment, yet (iii) to the extent that the sludge mixing rate is below the rate at which microbial cell rupture occurs, irreversible breakup of agglomerates of sludge occurs and/or sludge/water settleability characteristics are not deteriorated; (5) controlling the biological oxygen demand during treatment such that (i) at least the stoichiometric amount of biological oxygen demand required to achieve a specified level of denitrification by microbial conversion of nitrite and/or nitrate to free nitrogen during treatment at a particular concentration of ammonia in the wastewater fed for treatment is present; and (ii) in the case of substantially no denitrification, controlling the treatment so as to simply provide a source of assimilable carbon for the microorganism population present; (6) controlling the pH of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, yet (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity, during treatment is avoided, yet (iii) in a hospitable range for microorganism growth and effective treatment of waste in the wastewater; and (7) controlling the temperature of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during the treatment is avoided, yet (iii) in a hospitable range for microorganism action on and effective treatment of the waste in the wastewater.

Claim 37

The activated sludge process of claim 34, wherein said nitrifying microorganisms capable of converting ammonia to nitrite are Nitrosomonas microorganisms, said nitrifying microorganisms capable of converting nitrite to nitrate are Nitrobacter microorganisms and said facultative microorganisms are microorganisms of the genera Pseudomonas, Achromobacter, Bacillus, Micrococcus or mixtures thereof.

Claim 38

The activated sludge process of claim 34, wherein said microorganism population additionally includes sulfur acting microorganisms and cyanide acting microorganisms.

Claim 39

The activated sludge process of claim 34, wherein said controlling of the sludge wastage rate comprises controlling the sludge wastage rate within the range of (a) a Minimum Sludge Wastage Rate and (b) a Maximum Sludge Wastage Rate, said Minimum Sludge Wastate Rate and said Maximum Sludge Wastage Rate being defined in accordance with equations (A) to (D) below: ##EQU5## where the Maximum Sludge Wastage Rate is the smallest of the Sludge Wastage Rates for all of the types of microorganisms present, ##EQU6##

Claim 40

The activated sludge process of claim 37, wherein said controlling of the sludge wastage rate is within about 20% below said Minimum Sludge Wastage Rate (a) to about 20% below said Maximum Sludge Wastage Rate (b).

Claim 41

The activated sludge process of claim 38, wherein said controlling of the sludge wastage rate is within about 40% above said Minimum Sludge Wastage Rate (a) to about 40% below said Maximum Sludge Wastage Rate.

Claim 42

The activated sludge process of claim 39, wherein said controlling of the sludge wastage rate is to substantially a zero sludge wastage rate.

Claim 43

The activated sludge process of claim 34, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 35 days.

Claim 44

The activated sludge process of claim 41, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 20 days.

Claim 45

The activated sludge process of claim 42, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 10 days.

Claim 46

The activated sludge process of claim 43, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of 5 days or less.

Claim 47

The activated sludge process of claim 34, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of at least about 0.1 mg/l, on a continuous or weighted average basis.

Claim 48

The activated sludge process of claim 34, wherein the pH and temperature are maintained such that the free ammonia concentration and the nitrous acid concentration at the temperature of the treatment is no greater than the equivalent free ammonia concentration and nitrous acid concentration as defined by the limits of Zone 3 in FIG. 7 at 20° C.

Claim 49

The activated sludge process of claim 46, wherein nitrous acid concentration is about 0.2 mg/l or less.

Claim 50

The activated sludge process of claim 37, wherein said mixing of the sludge is to a mixing rate allowing about 80% of the Maximum Sludge Wastage Rate to said Maximum Sludge Wastage Rate.

Claim 51

The activated sludge process of claim 48, wherein said mixing of the sludge is to a mixing rate allowing about 60% to less than about 80% of the Maximum Sludge Wastage Rate.

Claim 52

The activated sludge process of claim 49, wherein said mixing of the sludge is to a mixing rate allowing about 40% to less than about 80% of the Maximum Sludge Wastage Rate.

Claim 53

The activated sludge process of claim 50, wherein said mixing of the sludge is to a mixing rate allowing substantially a zero sludge wastage rate.

Claim 54

The activated sludge process of claim 34, wherein said source of assimilable carbon is an inorganic carbon source or an organic carbon source.

Claim 55

The activated sludge process of claim 52, wherein said source of assimilable carbon is carbon dioxide.

Claim 56

The activated sludge process of claim 34, wherein said controlling of the pH is to a pH range of about 6 to about 8.

Claim 57

The activated sludge process of claim 54, wherein said controlling of the pH is to a pH range of about 6.5 to about 7.5.

Claim 58

The activated sludge process of claim 55, wherein said controlling of the pH is to a pH range of about 6.8 to about 7.3.

Claim 59

The activated sludge process of claim 34, wherein said controlling of the temperature is to a temperature of about 35° C. or below.

Claim 60

The activated sludge process of claim 57, wherein said controlling of the temperature is to a range of about 5° C. to about 35° C.

Claim 61

The activated sludge process of claim 58, wherein said controlling of the temperature is to a range of about 10° C. to about 25° C.

Claim 62

The activated sludge process of claim 59, wherein said controlling of the temperature is to a range of about 15° C. to about 25° C.

Claim 63

The activated sludge process of claim 34, wherein said process achieves substantially complete nitrification of said ammonia and about 75% to less than substantially complete denitrification of said nitrite and/or nitrate.

Claim 64

The activated sludge process of claim 34, wherein said process achieves substantially complete nitrification of said ammonia and about 50% to less than about 75% denitrification of said nitrite and/or nitrate.

Claim 65

The activated sludge process of claim 34, wherein said process achieves substantially complete nitrification of said ammonia and about 25% to less than 50% denitrification of said nitrite and/or nitrate.

Claim 66

The activated sludge process of claim 34, wherein said process achieves substantially complete nitrification of said ammonia and substantially no denitrification of said nitrite and/or nitrate.

Claim 67

The activated sludge process of claim 34, wherein said wastewater microbially treated has an ammonia concentration of about 300 mg/l or higher.

Claim 68

The activated sludge process of claim 34, wherein said wastewater microbially treated has an ammonia concentration of about 500 mg/l or higher.

Claim 69

The activated sludge process of claim 34, wherein said wastewater microbially treated has an ammonia concentration of about 1000 mg/l or higher.

Claim 70

The activated sludge process of claim 34, wherein said wastewater microbially treated has an ammonia concentration of about 3000 mg/l or higher.

Claim 71

A process for producing an acclimated population of microorganisms for treating wastewater containing ammonia as a contaminant, and further other contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials, to achieve substantially complete nitrification of said ammonia into nitrite and/or nitrate and substantially complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising introducing the wastewater into an activated sludge process containing a microorganism population including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, and allowing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms, each having a different growth rate, to grow and become acclimated to the level of ammonia, and other contaminants if present, by feeding the wastewater to the activated sludge system and microorganisms population at a rate sufficiently high to a stimulate microbial cell division but at a rate insufficiently high that an inhibitory level of ammonia, and other contaminants if present, in the wastewater is not reached, thereby causing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting ammonia to nitrite to nitrate, if present, and facultative microorganisms to grow relatively such that the microorganism population becomes acclimated to the wastewater contaminants and their levels in the wastewater.

Claim 72

A process for producing an acclimated population of microorganisms for treating wastewater containing ammonia as a contaminant, and further other contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials, to achieve substantially complete nitrification of said ammonia into nitrite and/or nitrate and substantially complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising introducing the wastewater into an activated sludge process containing a microorganism population including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, and allowing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms, each having a different growth rate, to grow and become acclimated to the level of ammonia, and other contaminants if present, by feeding the wastewater to the activated sludge system and microorganisms population at a rate sufficiently high to a stimulate microbial cell division but at a rate insufficiently high that an inhibitory level of ammonia, and other contaminants if present, in the wastewater is not reached, thereby causing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting ammonia to nitrite to nitrate, if present, and facultative microorganisms to grow relatively such that the microorganism population becomes acclimated to the wastewater contaminants and their levels in the wastewater.

Claim 73

The acclimination process of claim 69, wherein said acclimation process is conducted under the following conditions: (1) controlling the sludge wastage rate to the extent that, for the wastewater fed during the treatment and at the conditions at which the treatment is operated, the sludge wastage rate (i) is low enough to provide and maintain a steady state population of microorganisms capable of converting ammonia to nitrite and/or nitrate and yet (ii) is high enough to prevent buildup of inert solids in the sludge; (2) controlling the hydraulic residence time of the wastewater in treatment such that the hydraulic residence time is (i) long enough to produce a sludge concentration that can be water/solid separated at the sludge wastage rate of (1) above, and (ii) long enough to achieve substantially full sludge performance; (3) maintaining a dissolved oxygen level, on a continuous or weighted average basis, (i) sufficiently high that microbial conversion of ammonia to nitrite and/or nitrate occurs but (ii) lower than the dissolved oxygen level at which microbial conversion of nitrite and/or nitrate to free nitrogen ceases to occur; (4) mixing the sludge (i) to the extent that the sludge mixing rate achieves utilization of sludge present during treatment so as to avoid causing a sludge growth which would result in exceeding the maximum allowable sludge wastage rate of (1) above, and (ii) to the extent that the sludge mixing rate is large enough to reduce gradients in levels of bulk dissolved oxygen to a level consistent with the denitrification desired for the wastewater treatment, yet (iii) to the extent that the sludge mixing rate is below the rate at which microbial cell rupture occurs, irreversible breakup of agglomerates of sludge occurs, and/or sludge/water settleability characteristics are not deteriorated; (5) controlling the biological oxygen demand during treatment such that at least the stoichiometric amount of biological oxygen demand required to achieve denitrification by microbial conversion of nitrite and/or nitrate to free nitrogen during treatment at a particular concentration of ammonia in the wastewater fed for treatment is present; (6) controlling the pH of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during treatment is avoided, yet (iii) in a hospitable range for microorganism growth and effective waste treatment of waste in the wastewater; and (7) controlling the temperature of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during the treatment is avoided, yet (iii) in a hospitable range for microorganism action on and effective treatment of the waste in the wastewater.

Claim 74

The acclimation process of claim 70, wherein said nitrifying microorganisms capable of converting ammonia to nitrite are Nitrosomonas microorganisms, said nitrifying microorganisms capable of converting nitrite to nitrate are Nitrobacter microorganisms and said facultative microorganisms are microorganisms of the genera Pseudomonas, Achromobacter, Bacillus, Micrococcus or mixtures thereof.

Claim 75

The acclimation process of claim 70, wherein said microorganism population additionally includes sulfur acting microorganisms and cyanide acting microorganisms.

Claim 76

The acclimation process of claim 70, wherein said controlling of the sludge wastage rate comprises controlling the sludge wastage rate within the range of (a) a Minimum Sludge Wastage Rate and (b) a Maximum Sludge Wastage Rate, said Minimum Sludge Wastage Rate and said Maximum Sludge Wastage Rate being defined in accordance with equations (A) to (D) below: ##EQU7## where the Maximum Sludge Wastage Rate is the smallest of the Sludge Wastage Rates for all of the types of microorganisms present, ##EQU8##

Claim 77

The acclimation process of claim 73, wherein said controlling of the sludge wastage rate is within about 20% above said Minimum Sludge Wastage Rate (a) to about 20% below said Maximum Sludge Wastage Rate (b).

Claim 78

The acclimation process of claim 74, wherein said controlling of the sludge wastage rate is within about 40% above said Minimum Sludge Wastage Rate (a) to about 40% below said Maximum Sludge Wastage Rate.

Claim 79

The acclimation process of claim 75, wherein said controlling of the sludge wastage rate is to substantially a zero sludge wastage rate.

Claim 80

The acclimation process of claim 70, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 35 days.

Claim 81

The acclimation process of claim 77, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 20 days.

Claim 82

The acclimation process of claim 78, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 10 days.

Claim 83

The acclimation process of claim 79, wherein said controlling of th hydraulic residence time is to a hydraulic residence time of 5 days or less.

Claim 84

The acclimation process of claim 70, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 2 mg/l, achieved on a continuous or weighted average basis.

Claim 85

The acclimation process of claim 81, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 1.5 mg/l, achieved on a continuous or weighted average basis.

Claim 86

The acclimation process of claim 82, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of about 0.1 mg/l to about 1 mg/l, achieved on a continuous or weighted average basis.

Claim 87

The acclimation process of claim 83, wherein the pH and temperature are maintained such that the free ammonia concentration and the nitrous acid concentration at the temperature of the treatment is no greater than the equivalent free ammonia concentration and nitrous acid concentration as defined by the limits of Zone 3 in FIG. 7 at 20° C.

Claim 88

The activated sludge process of claim 84, wherein the nitrous acid concentration is about 0.2 mg/l or less.

Claim 89

The acclimation process of claim 70, wherein said mixing of the sludge is to a mixing rate allowing about 80% of the Maximum Sludge Wastage Rate to said Maximum Sludge Wastage Rate.

Claim 90

The acclimation process of claim 86, wherein said mixing of the sludge is to a mixing rate allowing about 60% to less than about 80% of the Maximum Sludge Wastage Rate.

Claim 91

The acclimation process of claim 87, wherein said mixing of the sludge is to a mixing rate allowing about 40% to less than about 60% of the Maximum Sludge Wastage Rate.

Claim 92

The acclimation process of claim 70, wherein said controlling of the biological oxygen demand is to an extent that the BOD to N ratio is at least about 1.7:1 to about 2.8:1 or more.

Claim 93

The acclimation process of claim 89, wherein said controlling of the biological oxygen demand is to an extent that the BOD to N ratio is at least about 2.8:1 or more.

Claim 94

The acclimation process of claim 70, wherein said controlling of the pH is to a pH range of about 6 to about 8.

Claim 95

The acclimation process of claim 91, wherein said controlling of the pH is to a pH range of about 6.5 to about 7.5.

Claim 96

The acclimation process of claim 92, wherein said controlling of the pH is to a pH range of about 6.8 to about 7.3.

Claim 97

The acclimation process of claim 70, wherein said controlling of the temperature is to a temperature of about 35° C. or below.

Claim 98

The acclimation process of claim 94, wherein said controlling of the temperature is to a range of about 5° C. to about 35° C.

Claim 99

The acclimation process of claim 95, wherein said controlling of the temperature is to a range of about 10° C. to about 25° C.

Claim 100

The acclimation process of claim 96, wherein said controlling of the temperature is to a range of about 15° C. to about 25° C.

Claim 101

A process for producing an acclimated population of microorganisms for treating wastewater containing ammonia as a contaminant, and further other contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials, to achieve substantially complete nitrification of said ammonia into nitrite and/or nitrate and less than complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising introducing the wastewater into an activated sludge process containing a microorganism population including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, and allowing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms, each having a different growth rate, to grow and become acclimated to the level of ammonia, and other contaminants if present, by feeding the wastewater to the activated sluge system and microorganism population at a rate sufficiently high to stimulate microbial cell division but at a rate insufficiently high that an inhibitory level of ammonia, and other contaminants if present, in the wastewater is not reached, thereby causing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms to grow relatively such that the microorganism population becomes acclimated to the wastewater contaminants and their levels in the wastewater.

Claim 102

A process for producing an acclimated population of microorganisms for treating wastewater containing ammonia as a contaminant, and further other contaminants, if present, including cyanide, thiocyanate, sulfide and/or organic materials, to achieve substantially complete nitrification of said ammonia into nitrite and/or nitrate and less than complete denitrification of said nitrite and/or nitrate into free nitrogen, said process comprising introducing the wastewater into an activated sludge process containing a microorganism population including nitrifying microorganisms capable of converting ammonia to nitrite, optionally, nitrifying microorganisms capable of converting nitrite to nitrate, and facultative microorganisms capable of denitrifying nitrite and/or nitrate by oxidizing organic material and converting nitrite and/or nitrate to free nitrogen, and allowing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms, each having a different growth rate, to grow and become acclimated to the level of ammonia, and other contaminants if present, by feeding the wastewater to the activated sluge system and microorganism population at a rate sufficiently high to stimulate microbial cell division but at a rate insufficiently high that an inhibitory level of ammonia, and other contaminants if present, in the wastewater is not reached, thereby causing the nitrifying microorganisms capable of converting ammonia to nitrite, nitrifying microorganisms capable of converting nitrite to nitrate, if present, and facultative microorganisms to grow relatively such that the microorganism population becomes acclimated to the wastewater contaminants and their levels in the wastewater.

Claim 103

The acclimation process of claim 98, wherein said acclimation process is conducted under the following conditions: (1) controlling the sludge wastage rate to the extent that, for the wastewater fed during the treatment and at the conditions at which the treatment is operated, the sludge wastage rate (i) is low enough to provide and maintain a steady state population of microorganisms capable of converting ammonia to nitrite and/or nitrate, yet (ii) is high enough to prevent buildup of inert solids in the sludge; (2) controlling the hydraulic residence time of the wastewater in treatment such that the hydraulic residence time is (i) long enough to produce a sludge concentration that can be water/solid separated at the sludge wastage rate of (1) above, (ii) long enough to achieve substantially full sludge performance; (3) maintaining a dissolved oxygen level, on a continuous or weighted average basis, sufficiently high that microbial conversion of ammonia to nitrite and/or nitrate and of biological oxygen demand if present, to carbon dioxide and water occurs; (4) mixing the sludge (i) to the extent that the sludge mixing rate achieves utilization of sludge present during treatment so as to avoid causing a sludge growth rate which would result in exceeding the maximum allowable sludge wastage rate of (1) above, (ii) to the extent that the sludge mixing rate is large enough to reduce gradients in levels of bulk dissolved oxygen to a level consistent with the level of denitrification desired for the wastewater treatment, yet (iii) to the extent that the sludge mixing rate is below the rate at which microbial cell rupture occurs, irreversible breakup of agglomerates of sludge occurs and/or sludge/water settleability characteristics are not deteriorated; (5) controlling the biological oxygen demand during treatment such that (i) at least the stoichiometric amount of biological oxygen demand required to achieve a specified level of denitrification by microbial conversion of nitrite and/or nitrate to free nitrogen during treatment at a particular concentration of ammonia in the wastewater fed for treatment is present; and (ii) in the case of substantially no denitrification, controlling the treatment so as to simply provide a source of assimilable carbon for the microorganism population present; (6) controlling the pH of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, yet (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity, during treatment is avoided, yet (iii) in a hospitable range for microorganism growth and effective treatment of waste in the wastewater; and (7) controlling the temperature of the treatment (i) in a range in which the level of free ammonia inhibitory to microorganism activity during the treatment is avoided, and (ii) in a range in which the level of free nitrous acid inhibitory to microorganism activity during the treatment is avoided, yet (iii) in a hospitable range for microorganism action on and effective treatment of the waste in the wastewater.

Claim 104

The acclimation process of claim 98, wherein said nitrifying microorganisms capable of converting ammonia to nitrite are Nitrosomonas microorganisms, said nitrifying microorganisms capable of converting nitrite to nitrate are Nitrobacter microorganisms and said facultative microorganisms are microorganisms of the genera Pseudomonas, Achromobacter, Bacillus, Micrococcus or mixtures thereof.

Claim 105

The acclimation process of claim 98, wherein said microorganism population additionally includes sulfur acting microorganisms and cyanide acting microorganisms.

Claim 106

the acclimation process of claim 99, wherein said controlling of the sludge wastage rate comprises controlling the sludge wastage rate within the range of (a) a Minimum Sludge Wastage Rate and (b) a Maximum Sludge Wastage Rate, said Minimum Sludge Wastage Rate and said Maximum Sludge Wastage Rate being defined in accordance with equations (A) to (D) below: ##EQU9## where the Maximum Sludge Wastage Rate is the smallest of the Sludge Wastage Rates for all of the types of microorganisms present, ##EQU10##

Claim 107

The acclimation process of claim 102, wherein said controlling of the sludge wastage rate is within about 20% above said Minimum Sludge Wastage Rate (a) to about 20% below said Maximum Sludge Wastage Rate (b).

Claim 108

The acclimation process of claim 103, wherein said controlling of the sludge wastage rate is within about 40% above said Minimum Sludge Wastage Rate (a) to about 40% below said Maximum Sludge Wastage Rate.

Claim 109

The acclimation process of claim 104, wherein said controlling of the sludge wastage rate is to substantially a zero sludge wastage rate.

Claim 110

The acclimation process of claim 99, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 35 days.

Claim 111

The acclimation process of claim 106, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 20 days.

Claim 112

The acclimation process of claim 107, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of about 5 days to about 10 days.

Claim 113

The acclimation process of claim 108, wherein said controlling of the hydraulic residence time is to a hydraulic residence time of 5 days or less.

Claim 114

The acclimation process of claim 99, wherein said controlling of the dissolved oxygen level is to a dissolved oxygen level of at least about 0.1 mg/l, on a continuous or weighted average basis.

Claim 115

The acclimation process of claim 99, wherein the pH and temperature are maintained such that the free ammonia concentration and the nitrous acid concentration at the temperature of the treatment is no greater than the equivalent free ammonia concentration and nitrous acid concentration as defined by the limits of Zone 3 in FIG. 7 at 20° C.

Claim 116

The activated sludge process of claim 111, wherein the nitrous acid concentration is about 0.2 mg/l or less.

Claim 117

The acclimation process of claim 99, wherein said mixing of the sludge is to a mixing rate allowing about 80% of the Maximum Sludge Wastage Rate to said Maximum Sludge Wastage Rate.

Claim 118

The acclimation process of claim 113, wherein said mixing of the sludge is to a mixing rate allowing about 60% to less than about 80% of the Maximum Sludge Wastage Rate.

Claim 119

The acclimation process of claim 114, wherein said mixing of the sludge is to a mixing rate allowing about 40% to less than about 60% of the Maximum Sludge Wastage Rate.

Claim 120

The acclimation process of claim 99, wherein said source of assimilable carbon is an inorganic carbon source or an organic carbon source.

Claim 121

The acclimation process of claim 116, wherein said source of assimilable carbon is carbon dioxide.

Claim 122

The acclimation process of claim 99, wherein said controlling of the pH is to a pH range of about 6 to about 8.

Claim 123

The acclimation process of claim 118, wherein said controlling of the pH is to a pH range of about 6.5 to about 7.5.

Claim 124

The acclimation process of claim 119, wherein said controlling of the pH is to a pH range of about 6.8 to about 7.3.

Claim 125

The acclimation process of claim 99, wherein said controlling of the temperature is to a temperature of about 35° C. or below.

Claim 126

The acclimation process of claim 121, wherein said controlling of the temperature is to a range of about 5° C. to about 35° C.

Claim 127

The acclimation process of claim 122, wherein said controlling of the temperature is to a range of about 10° C. to about 25° C.

Claim 128

The acclimation process of claim 123, wherein said controlling of the temperature is to a range of about 15° C. to about 25° C.

Claim 129

The acclimation process of claim 98, wherein said acclimation is to achieve substantially complete nitrification of said ammonia and to achieve about 75% to less than substantially complete denitrification of said nitrite and/or nitrate.

Claim 130

The acclimation process of claim 98, wherein said acclimation is to achieve substantially complete nitrification of said ammonia and to achieve about 50% to less than about 75% denitrification of said nitrite and/or nitrate.

Claim 131

The acclimation process of claim 98, wherein said acclimation is to achieve substantially complete nitrification of said ammonia and to achieve about 25% to less than 50% denitrification of said nitrite and/or nitrate.

Claim 132

The acclimation process of claim 98, wherein said acclimation is to achieve substantially complete nitrification of said ammonia and to achieve substantially no dentrification of said nitrite and/or nitrate.