US4536564A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyamide from bis-carboxy containing 3,5,3',5'-tetraoxo-1,2-dipiperazine compound and diamine
Assignee: Dow Chemical Co
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Filing: 1983-12-09
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Granted: 1985-08-20
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Expires: 2003-12-09
Abstract
Abstract The invention includes novel dicarboxylic acids derived from alkylene or arylene diaminetetraacetec acid corresponding to the formula ##STR1## These dicarboxylic acids derived from alkylene or arylene diaminetetraacetic acid are useful in the preparation of polyamides. Another aspect of the invention is a polymer prepared from between about 1 and 100 mole percent of the diamine salt of the compound represented by formula (I) ##STR2## These polymers are useful in preparing molded articles.
Inventors
- 👤 Edmund P. Woo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 23:40
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
70 words
A compound corresponding to the formula ##STR9## wherein R is a C 1-20 alkylene group, phenylene group, arylalkylene group, cycloalkylene group, diphenylene group, or --R 2 --X--R 2 --; X is O, S or SO 2 ; R 2 is a C 1-10 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; and R 1 is a C 1-20 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group.
Claim 2
Dependent Claim
70 words
A compound corresponding to the formula ##STR9## wherein R is a C 1-20 alkylene group, phenylene group, arylalkylene group, cycloalkylene group, diphenylene group, or --R 2 --X--R 2 --; X is O, S or SO 2 ; R 2 is a C 1-10 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; and R 1 is a C 1-20 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group.
Claim 3
Dependent Claim
36 words
The compound of claim 1 wherein R is a C 1-5 alkylene group, phenylene group, diphenylene group or --R 2 --X--R 2 -- wherein R 2 is a phenylene group or a C 1-5 alkylene group.
Claim 4
Dependent Claim
26 words
The compound of claim 1 wherein R is an ethylene group, phenyl group or --R 2 --X--R 2 -- wherein R 2 is ethylene or phenylene.
Claim 5
Dependent Claim
18 words
The compound of claim 1 wherein R 1 is a C 1-5 alkylene group or a phenylene group.
Claim 6
Dependent Claim
19 words
The compound of claim 1 wherein R 1 is a methylene group, a pentamethylene group or a phenylene group.
Claim 7
Dependent Claim
149 words
A process for the preparation of a dicarboxylic acid represented by the formula ##STR10## comprising contacting an alkylene or arylene diaminetetraacetic anhydride represented by the formula ##STR11## with an amine-substituted carboxylic acid represented by the formula H.sub.2 N--R.sub.1 --COOH (III) in a solvent comprising a high boiling phenolic compound and an aromatic hydrocarbon capable of forming an azeotrope with water, refluxing the mixture, and removing the water formed in the process as an azeotrope with the aromatic hydrocarbon, until such time as the azeotrope is water-free; wherein R is a C 1-20 alkylene group, phenylene group, arylalkylene group, cycloalkylene group, diphenylene group, or --R 2 --X--R 2 --; X is O, S or SO 2 ; R 2 is a C 1-10 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; and R 1 is a C 1-20 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group.
Claim 8
Dependent Claim
149 words
A process for the preparation of a dicarboxylic acid represented by the formula ##STR10## comprising contacting an alkylene or arylene diaminetetraacetic anhydride represented by the formula ##STR11## with an amine-substituted carboxylic acid represented by the formula H.sub.2 N--R.sub.1 --COOH (III) in a solvent comprising a high boiling phenolic compound and an aromatic hydrocarbon capable of forming an azeotrope with water, refluxing the mixture, and removing the water formed in the process as an azeotrope with the aromatic hydrocarbon, until such time as the azeotrope is water-free; wherein R is a C 1-20 alkylene group, phenylene group, arylalkylene group, cycloalkylene group, diphenylene group, or --R 2 --X--R 2 --; X is O, S or SO 2 ; R 2 is a C 1-10 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; and R 1 is a C 1-20 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group.
Claim 9
Dependent Claim
26 words
The process of claim 6 wherein about 2 moles of the amine-substituted carboxylic acid is contacted with about 1 mole of alkylene or arylene diaminetetraacetic anhydride.
Claim 10
Dependent Claim
149 words
A moldable polymer prepared from between about 1 and 100 mole percent of the diamine salt of a compound of claim 1 represented by formula (I) ##STR12## and between about 0 and 99 mole percent of the diamine salt of the compound represented by the formula HOOC--R 4 --COOH wherein the diamine is represented by the formula H 2 N--R 3 --NH 2 wherein R is a C 1-20 alkylene group, phenylene group, arylalkylene group, cycloalkylene group, diphenylene group, or --R 2 --X--R 2 --; X is O, S or SO 2 ; R 2 is a C 1-10 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; R 1 is a C 1-20 alkylene group, phenylene group, arylalkylene group or a cycloalkylene group; and R 3 is a C 1-12 alkylene group, cyclohexylene, ##STR13## and R 4 is a C 1-10 alkylene group or a phenylene group.
References Cited (Backward Citations)
US3719640A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-19 | 1989-02-18 | 1989-08-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-19 | 1993-02-18 | 1993-08-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-19 | 1997-02-18 | 1997-08-20 | $7700.00 | Window Closed / Lapsed |