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US4535142A Expired / Lapsed US ⏱️ 0.0 years remaining

High solids coatings based on diricinoleate derivatives

Assignee: Caschem Inc
•
Filing: 1984-07-10
•
Granted: 1985-08-13
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Expires: 2004-07-10
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Abstract

Abstract Low viscosity, high solids polyurethane coatings compositions are prepared from a diricinoleate derivate and an isocyanate or from a diricinoleate derivative, a high viscosity polyol, and an isocyanate. Also, a method for reducing the viscosity and increasing the solids content of a polyurethane coating by adding from about 1 to 99 percent by weight of a diricinoleate derivative to a hydroxyl bearing component before reacting with an isocyanate, and a method for preparing a polyurethane coating having a low viscosity suitable for spray coating applications by reacting a diricinoleate derivative with an isocyanate.

Inventors

  • 👤 Melvin Brauer
  • 👤 Dominic Simone

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 09:22
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/36

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 30 words
A low viscosity sprayable polyurethane coating composition comprising at least one diricinoleate diol and a polyisocyanate compound; said diricinoleate diol and said polyisocyanate compound being present in substantially stoichiometric amounts.
Claim 2
Dependent Claim 30 words
A low viscosity sprayable polyurethane coating composition comprising at least one diricinoleate diol and a polyisocyanate compound; said diricinoleate diol and said polyisocyanate compound being present in substantially stoichiometric amounts.
Claim 3
Dependent Claim 34 words
The composition according to claim 1 wherein said diricinoleate diol is a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof.
Claim 4
Dependent Claim 40 words
The composition according to claim 2 wherein said diricinoleate diol is a diricinoleate of 1,4 cyclo hexane dimethanol, ethylene glycol, diethylene glycol, ethoxylated bisphenol A, 1, 4 butanediol, 1, 3 propanediol, 1, 6 hexane diol, or 1, 3 neopentyl glycol.
Claim 5
Dependent Claim 20 words
The composition according to claim 3 wherein said diricinoleate diol further comprises up to about 50% of a monoricinoleate derivative.
Claim 6
Dependent Claim 41 words
A low viscosity sprayable polyurethane coating composition comprising a hydroxyl bearing component comprising at least one diricinoleate diol and at least one polyol; and a polyisocyanate component; said hydroxyl bearing component and said polyisocyanate component being present in substantially stoichiometric amounts.
Claim 7
Dependent Claim 41 words
A low viscosity sprayable polyurethane coating composition comprising a hydroxyl bearing component comprising at least one diricinoleate diol and at least one polyol; and a polyisocyanate component; said hydroxyl bearing component and said polyisocyanate component being present in substantially stoichiometric amounts.
Claim 8
Dependent Claim 46 words
The composition according to claim 5 wherein said diricinoleate diol comprises between 1 and 99 weight percent of the hydroxyl bearing component of the composition and said at least one polyol comprises between 99 and 1 weight percent of the hydroxyl bearing component of the composition.
Claim 9
Dependent Claim 34 words
The composition according to claim 6 wherein said diricinoleate diol is a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol or mixtures thereof.
Claim 10
Dependent Claim 36 words
The composition according to claim 7 wherein said diricinoleate diol is a diricinoleate of 1,4 cyclo hexane dimethanol, ethylene glycol, diethylene glycol, ethoxylated bisphenol A, 1,4 butanediol, 1,3 propanediol, 1,6 hexane diol, or 1,3 neopentyl glycol.
Claim 11
Dependent Claim 20 words
The composition according to claim 8 wherein said diricinoleate diol further comprises up to about 50% of a monoricinoleate derivative.
Claim 12
Dependent Claim 13 words
The composition according to claim 9 further comprising a small amount of solvent.
Claim 13
Independent Claim 54 words
A method for reducing the viscosity and increasing the solids content of a polyurethane coating composition which comprises adding to the hydroxyl bearing component of a polyurethane composition from about 1 to 99 percent by weight of a diricinoleate diol before said components are reacted with a substantially stoichiometric amount of a polyisocyanate compound.
Claim 14
Independent Claim 54 words
A method for reducing the viscosity and increasing the solids content of a polyurethane coating composition which comprises adding to the hydroxyl bearing component of a polyurethane composition from about 1 to 99 percent by weight of a diricinoleate diol before said components are reacted with a substantially stoichiometric amount of a polyisocyanate compound.
Claim 15
Dependent Claim 34 words
The method according to claim 11 wherein said diricinoleate diol is a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof.
Claim 16
Dependent Claim 36 words
The method according to claim 12 wherein said diricinoleate diol is a diricinoleate of 1,4 cyclo hexane dimethanol, ethylene glycol, diethylene glycol, ethoxylated bisphenol A, 1,4 butanediol, 1,3 propanediol, 1,6 hexane diol, or 1,3 neopentyl glycol.
Claim 17
Dependent Claim 20 words
The method according to claim 13 wherein said diricinoleate diol further comprises up to about 50% of a monoricinoleate derivative.
Claim 18
Dependent Claim 17 words
The method according to claim 14 wherein said polyurethane composition further comprises a small amount of solvent.
Claim 19
Independent Claim 34 words
A method for preparing a polyurethane coating composition having a low viscosity suitable for spray coating applications which comprises reacting at least one diricinoleate diol with a substantially stoichiometric amount of a polyisocyanate compound.
Claim 20
Independent Claim 34 words
A method for preparing a polyurethane coating composition having a low viscosity suitable for spray coating applications which comprises reacting at least one diricinoleate diol with a substantially stoichiometric amount of a polyisocyanate compound.
Claim 21
Dependent Claim 34 words
The method according to claim 16 wherein said diricinoleate diol is a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof.
Claim 22
Dependent Claim 35 words
The method according to claim 17 wherein said diricinoleate diol is a diricinoleate of 1,4 cyclohexane dimethanol, ethylene glycol, diethylene glycol, ethoxylated bisphenol A, 1,4 butanediol, 1,3 propanediol, 1,6 hexane diol, or 1,3 neopentyl glycol.
Claim 23
Dependent Claim 20 words
The method according to claim 18 wherein said diricinoleate diol further comprises up to about 50% of a monoricinoleate derivative.
Claim 24
Dependent Claim 62 words
A low viscosity sprayable polyurethane coating composition comprising at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, and a polyisocyanate compound; said diricinoleate and said polyisocyanate and being present in amounts such that the ratio of the polyisocyanate to the diricinoleate is about 1.05 to 1.
Claim 25
Dependent Claim 62 words
A low viscosity sprayable polyurethane coating composition comprising at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, and a polyisocyanate compound; said diricinoleate and said polyisocyanate and being present in amounts such that the ratio of the polyisocyanate to the diricinoleate is about 1.05 to 1.
Claim 26
Dependent Claim 112 words
A low viscosity sprayable polyurethane coating composition comprising a hydroxyl bearing component comprising at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, and mixtures therefore, and at least one polyol; and a polyisocyanate compound; said diricinoleate diol comprising between 1 and 99 weight percent of the hydroxyl bearing component of the composition, and said at least one polyol comprising between 99 and 1 weight percent of the hydroxyl bearing component of the composition; said hydroxyl bearing component and said polyisocyanate compound being present in amounts such that the ratio of polyisocyanate to the hydroxyl bearing component is about 1.05/1.
Claim 27
Dependent Claim 112 words
A low viscosity sprayable polyurethane coating composition comprising a hydroxyl bearing component comprising at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, and mixtures therefore, and at least one polyol; and a polyisocyanate compound; said diricinoleate diol comprising between 1 and 99 weight percent of the hydroxyl bearing component of the composition, and said at least one polyol comprising between 99 and 1 weight percent of the hydroxyl bearing component of the composition; said hydroxyl bearing component and said polyisocyanate compound being present in amounts such that the ratio of polyisocyanate to the hydroxyl bearing component is about 1.05/1.
Claim 28
Independent Claim 91 words
A method for reducing the viscosity and increasing the solids content of a polyurethane coating composition which comprises adding to the hydroxyl bearing component of a polyurethane composition from about 1 to 99 percent by weight of a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, before said hydroxyl bearing component is reacted with a slight excess of a polyisocyanate compound such that the ratio of polyisocyanate to diricinoleate is about 1.05/l to form the polyurethane composition.
Claim 29
Independent Claim 91 words
A method for reducing the viscosity and increasing the solids content of a polyurethane coating composition which comprises adding to the hydroxyl bearing component of a polyurethane composition from about 1 to 99 percent by weight of a diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, before said hydroxyl bearing component is reacted with a slight excess of a polyisocyanate compound such that the ratio of polyisocyanate to diricinoleate is about 1.05/l to form the polyurethane composition.
Claim 30
Independent Claim 64 words
A method for preparing a polyurethane coating composition having a low viscosity suitable for spray coating applications which comprises reacting at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, with a slight excess of a polyisocyanate compound; such that the ratio of polyisocyanate to diricinoleate is about 1.05/1.
Claim 31
Independent Claim 64 words
A method for preparing a polyurethane coating composition having a low viscosity suitable for spray coating applications which comprises reacting at least one diricinoleate of an aliphatic diol of between about 2 and 12 carbon atoms, a cycloaliphatic diol, an aromatic diol, or mixtures thereof, with a slight excess of a polyisocyanate compound; such that the ratio of polyisocyanate to diricinoleate is about 1.05/1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-08-12 1989-02-11 1989-08-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-08-12 1993-02-11 1993-08-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-08-12 1997-02-11 1997-08-13 $7700.00 Window Closed / Lapsed

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