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US4534838A Expired / Lapsed US ⏱️ 0.0 years remaining

Siloxane polyphotoinitiators of the substituted acetophenone type

Assignee: LOCTRITE Corp A CORP OF CT
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Filing: 1984-09-27
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Granted: 1985-08-13
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Expires: 2004-09-27
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Abstract

Abstract An organopolysiloxane photoinitiator having an average of at least two siloxane units, of which at least an average of one siloxane unit per organopolysiloxane molecule has the formula: X.sub.a R.sub.b SiO(.sub.4-a-b)/2 (I) wherein a is an integer of 1-3, b is an integer of 0-2 and a plus b equals 1-3; R is C 1 -C 10 hydrocarbyl or halogen substituted C 1 -C 10 hydrocarbyl; and X is a substituted acetophenone photomoiety selected from: ##STR1## where R 1 is any substituent which will not interfere with hydrosilation, n is an integer between 0 and 5 in formulas (II), (IIa), (III), (IIIa), (IV) and (IVa) and between 0 and 4 in formula (III) and (IIIa); m is 0 or 1; R 2 is alkyl or substituted alkyl; R 3 is H, alkyl or aryl; R 4 is a divalent hydrocarbon group having between 2 and 10 carbon atoms or an alkylene oxy alkylene group; R 5 is a group selected from H, alkyl, aryl, organosilyl, or the reaction product of an isocyanate esterification reagent or an etherification reagent with the hydroxyl product formed when R 5 is H and R 6 is a trivalent hydrocarbon or hydrocarbon oxyhydrocarbon group. The silicones are prepared by hydrosilation of the corresponding olefinically or acetylenically unsaturated acetophenones.

Inventors

  • 👤 Samuel Q. S. Lin
  • 👤 Anthony F. Jacobine

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:59
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; C08G; C08G77/00; C08G77/04; C08G77/38; C08K; C08K5/00; C08K5/54; C08K5/541; C08K5/5415; C08K5/5419; Y; Y10; Y10S; Y10S522/00; Y10S522/904

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 199 words
An organopolysiloxane photoinitiator having an average of at least two siloxane units, of which at least an average of one siloxane unit per organopolysiloxane molecule has the formula: X.sub.a R.sub.b SiO.sub.(4-a-b)/2 (I) wherein a is an integer of 1-3, b is an integer of 0-2 and a plus b equals 1-3; R is C 1 -C 10 hydrocarbyl or halogen substituted C 1 -C 10 hydrocarbyl; and X is a substituted acetophenone photomoiety selected from: ##STR7## where R 1 is any substituent which will not interfere with hydrosilation, n is an integer between 0 and 5 in formulas (II), (IIa), (III), (IIIa), (IV) and (IVa) and between 0 and 4 in formula (III) and (IIIa); m is 0 or 1; R 2 is alkyl or substituted alkyl; R 3 is H, alkyl or aryl; R 4 is a divalent hydrocarbon group having between 2 and 10 carbon atoms or an alkylene oxy alkylene group; R 5 is a group selected from H, alkyl, aryl, organosilyl, or the reaction product of an isocyanate esterification reagent or an etherification reagent with the hydroxyl product formed when R 5 is H and R 6 is a trivalent hydrocarbon or hydrocarbon oxyhydrocarbon group.
Claim 2
Dependent Claim 199 words
An organopolysiloxane photoinitiator having an average of at least two siloxane units, of which at least an average of one siloxane unit per organopolysiloxane molecule has the formula: X.sub.a R.sub.b SiO.sub.(4-a-b)/2 (I) wherein a is an integer of 1-3, b is an integer of 0-2 and a plus b equals 1-3; R is C 1 -C 10 hydrocarbyl or halogen substituted C 1 -C 10 hydrocarbyl; and X is a substituted acetophenone photomoiety selected from: ##STR7## where R 1 is any substituent which will not interfere with hydrosilation, n is an integer between 0 and 5 in formulas (II), (IIa), (III), (IIIa), (IV) and (IVa) and between 0 and 4 in formula (III) and (IIIa); m is 0 or 1; R 2 is alkyl or substituted alkyl; R 3 is H, alkyl or aryl; R 4 is a divalent hydrocarbon group having between 2 and 10 carbon atoms or an alkylene oxy alkylene group; R 5 is a group selected from H, alkyl, aryl, organosilyl, or the reaction product of an isocyanate esterification reagent or an etherification reagent with the hydroxyl product formed when R 5 is H and R 6 is a trivalent hydrocarbon or hydrocarbon oxyhydrocarbon group.
Claim 3
Dependent Claim 14 words
A photoinitiator as in claim 1 where R is alkyl, substituted alkyl or aryl.
Claim 4
Dependent Claim 14 words
A photoinitiator as in claim 1 where R 1 is halo, alkyl or alkoxy.
Claim 5
Dependent Claim 9 words
A photoinitiator of claim 1 where n is 0.
Claim 6
Dependent Claim 19 words
A photoinitiator of claim 1 where X is selected from formulas II and III and R 2 is alkyl.
Claim 7
Dependent Claim 12 words
A photoinitiator of claim 1 where R 4 is propylene or propenylene.
Claim 8
Dependent Claim 13 words
A photoinitiator of claim 1 wherein X has the structure of formula IIa.
Claim 9
Dependent Claim 17 words
A photoinitiator of claim 1 wherein X has the structure of formula III and m is 1.
Claim 10
Dependent Claim 13 words
A photoinitiator of claim 1 wherein X has the structure of formula IVa.
Claim 11
Dependent Claim 18 words
A photoinitiator of claim 1 wherein X has the structure of formula IV and R 5 is organosilyl.
Claim 12
Dependent Claim 31 words
The method of curing a free radical curable compound having acrylic or vinyl functionality comprising subjecting to actinic radiation a composition of said compound and a photoinitiator as in claim 1.
Claim 13
Dependent Claim 17 words
The method of claim 11 wherein said curable compound is a silicone with acrylic or vinyl functionality.
Claim 14
Dependent Claim 20 words
A composition comprising a photoinitiator as in claim 1 and a free radical curable compound having acrylic or vinyl functionality.
Claim 15
Dependent Claim 17 words
The composition of claim 13 wherein said curable compound is a silicone with acrylic or vinyl functionality.

References Cited (Backward Citations)

US4273907A Cited
US4391963A Cited
US4467082A Cited
US4477326A Cited
US4503208A Cited
US4507187A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-08-12 1989-02-11 1989-08-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-08-12 1993-02-11 1993-08-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-08-12 1997-02-11 1997-08-13 $7700.00 Window Closed / Lapsed

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