Method of degassing a liquid

Claim 1

A method of degassing a liquid, the method being applicable to a liquid containing an unwanted gas in solution and serving to reduce the concentration of the gas to final concentration below its initial concentration, said method comprising the steps of: effecting mass exchange at reduced pressure during which the liquid is to be degassed by placing said liquid in a free separation enclosure, and aspirating the gaseous medium above the liquid to reduce the pressure of the unwanted gas to a degassing value below its saturation pressure which corresponds to the desired final concentration, and maintaining said degassing pressure for the time required to obtain the desired final pressure by mass exchange through the interface between the liquid and the gas phases, injecting bubbles of said unwanted gas itself into the un-degassed liquid to thereby increase the area of the interface between the liquid and gas phases during the reduced pressure exchange operation, thereby accelerating mass exchange, the improvement wherein said step of injecting microbubbles comprising injecting microbubbles of a diameter substantially in the range of about 50 micrometers to about 100 micrometers under a condition of a small rate of gas injection whereby said bubbles initially rise slowly through the liquid and create a large interface area, wherein said method is applicable to a liquid circulating in a closed circuit and further comprises the following steps: taking a fraction of said liquid flow, said fraction being a fraction for injection; pressurizing said fraction to an injection pressure greater than twice the degassing pressure; taking a fraction of said liquid flow, said fraction being a fraction for engassing; engassing the fraction for engassing in an engassing enclosure which is supplied with said unwanted gas and which is subjected to an engassing pressure greater than the injection pressure, thereby dissolving the gas in a liquid to a concentration which is greater than twice the initial concentration; and transforming said fraction into a superengassed fraction; and progressively and adjustably relaxing the superengassed fraction to mix it in adjustable proportions with the injection fraction and thus to supply an injection mixture having a substantially constant injection concentration of said unwanted gas; with said step of injecting bubbles into said liquid taking place through injection holes supplied with the injection mixture and leading to said liquid substantially at the degassing pressure.

Claim 2

A method of degassing a liquid, the method being applicable to a liquid containing an unwanted gas in solution and serving to reduce the concentration of the gas to final concentration below its initial concentration, said method comprising the steps of: effecting mass exchange at reduced pressure during which the liquid is to be degassed by placing said liquid in a free separation enclosure, and aspirating the gaseous medium above the liquid to reduce the pressure of the unwanted gas to a degassing value below its saturation pressure which corresponds to the desired final concentration, and maintaining said degassing pressure for the time required to obtain the desired final pressure by mass exchange through the interface between the liquid and the gas phases, injecting bubbles of said unwanted gas itself into the un-degassed liquid to thereby increase the area of the interface between the liquid and gas phases during the reduced pressure exchange operation, thereby accelerating mass exchange, the improvement wherein said step of injecting microbubbles comprising injecting microbubbles of a diameter substantially in the range of about 50 micrometers to about 100 micrometers under a condition of a small rate of gas injection whereby said bubbles initially rise slowly through the liquid and create a large interface area, wherein said method is applicable to a liquid circulating in a closed circuit and further comprises the following steps: taking a fraction of said liquid flow, said fraction being a fraction for injection; pressurizing said fraction to an injection pressure greater than twice the degassing pressure; taking a fraction of said liquid flow, said fraction being a fraction for engassing; engassing the fraction for engassing in an engassing enclosure which is supplied with said unwanted gas and which is subjected to an engassing pressure greater than the injection pressure, thereby dissolving the gas in a liquid to a concentration which is greater than twice the initial concentration; and transforming said fraction into a superengassed fraction; and progressively and adjustably relaxing the superengassed fraction to mix it in adjustable proportions with the injection fraction and thus to supply an injection mixture having a substantially constant injection concentration of said unwanted gas; with said step of injecting bubbles into said liquid taking place through injection holes supplied with the injection mixture and leading to said liquid substantially at the degassing pressure.