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US4532282A Expired / Lapsed US ⏱️ 0.0 years remaining

Blends of aromatic polycarbonate resin, olefin polymers or copolymers and acrylate- or methacrylate-copolymer resins

Assignee: General Electric Co
•
Filing: 1983-03-16
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Granted: 1985-07-30
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Expires: 2003-03-16
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Abstract

Abstract Thermoplastic molding compositions are described which comprise an admixture of (a) an aromatic polycarbonate resin, (b) an olefinic polymer or copolymer and (c) a third component which is a copolymer of an olefin and an acrylate, methacrylate, acrylic acid or methacrylic acid. The presence of the third component enhances impact strength in thicker sections and improves weld line strength.

Inventors

  • 👤 Ping Y. Liu
  • 👤 David E. Overton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 07:16
CPC Classifications
C; C08; C08L; C08L69/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 139 words
A thermoplastic composition, comprising an intimate blend of (a) from about 55 to about 93 parts by weight of an aromatic polycarbonate resin; (b) from about 3.5 to about 30 parts b weight of a polyolefin homopolymer an olefin copolymer or terpolymer made solely from olefin monomers or mixtures thereof; and (c) from about 3.5 to about 15 parts by weight of a third polymeric component comprising a copolymer of one or more olefins and a monomeric acrylate, methacrylate, acrylic acid or methacrylic acid, the amount of (c) being at least sufficient to impart to the blend a resistance to impact failure in thick sections greater than that possessed by (a), and a weld line impact strength better than that possessed by (a) and (b) in combination the total weight of (a), (b), and (c) combined is 100 parts.
Claim 2
Dependent Claim 139 words
A thermoplastic composition, comprising an intimate blend of (a) from about 55 to about 93 parts by weight of an aromatic polycarbonate resin; (b) from about 3.5 to about 30 parts b weight of a polyolefin homopolymer an olefin copolymer or terpolymer made solely from olefin monomers or mixtures thereof; and (c) from about 3.5 to about 15 parts by weight of a third polymeric component comprising a copolymer of one or more olefins and a monomeric acrylate, methacrylate, acrylic acid or methacrylic acid, the amount of (c) being at least sufficient to impart to the blend a resistance to impact failure in thick sections greater than that possessed by (a), and a weld line impact strength better than that possessed by (a) and (b) in combination the total weight of (a), (b), and (c) combined is 100 parts.
Claim 3
Dependent Claim 27 words
A composition according to claim 1, in which the aromatic polycarbonate resin has the formula ##STR3## wherein A is a divalent aromatic radical of a dihydric phenol.
Claim 4
Dependent Claim 79 words
A composition according to claim 1, in which the aromatic polycarbonate resin has the formula ##STR4## wherein R 1 and R 2 are, independently, hydrogen, alkyl having from 1 to about 10 carbon atoms, or phenyl; X is, independently, alkyl having from 1 to about 10 carbon atoms, chloro, bromo or hydrogen; p and r are independently, from zero to 4; and n represents the total number of monomer units and is an integer of at least about 30.
Claim 5
Dependent Claim 16 words
A composition according to claim 1, in which the aromatic polycarbonate resin is poly(bisphenol A carbonate).
Claim 6
Dependent Claim 43 words
A composition according to claim 1, in which the olefin resin (b) is selected from the group consisting of polyethylene, polypropylene, polyisobutylene, a copolymer of ethylene and propylene, terpolymers of ethylene, propylene and a diene copolymer of ethylene and butene-1 and mixtures thereof.
Claim 7
Dependent Claim 12 words
A composition according to claim 1, in which component (b) comprises polypropylene.
Claim 8
Dependent Claim 19 words
A composition according to claim 6, in which component (b) comprises a terpolymer of ethylene, propylene and a diene.
Claim 9
Dependent Claim 17 words
A composition according to claim 1, in which component (b) comprises a copolymer of ethylene and propylene.
Claim 10
Dependent Claim 16 words
A composition according to claim 1, in which component (b) comprises a linear low density polyethylene.
Claim 11
Dependent Claim 18 words
A composition according to claim 1, in which component (c) comprises a copolymer of ethylene and ethyl acrylate.
Claim 12
Dependent Claim 19 words
A composition according to claim 1, in which component (c) comprises a terpolymer of ethylene, propylene and acrylic acid.
Claim 13
Dependent Claim 15 words
A composition according to claim 1, wherein a reinforcing amount of a filler is present.
Claim 14
Dependent Claim 12 words
A composition according to claim 12, wherein said filler comprises glass fiber.
Claim 15
Dependent Claim 24 words
A composition according to claim 1, wherein a flame retardant effective amount of a metal salt of an organic sulfonic acid is also present.
Claim 16
Dependent Claim 39 words
An article which has been molded from a composition according to claim 1, said article being characterized by improved resistance to environmental stress cracking and crazing in comparison with a corresponding article consisting of the aromatic polycarbonate resin alone.
Claim 17
Dependent Claim 151 words
A thermoplastic composition comprising an intimate blend of (a) from about 55 to about 93 parts by weight of an aromatic polycarbonate resin; (b) from about 3.5 to about 30 parts by weight of a polymer made solely from olefin monomers selected from the group consisting of polyolefin homopolymer, an olefin copolymer or terpolymer made solely from olefin monomers and mixtures thereof; and (c) from about 3.5 to 15 parts by weight of a third polymeric component comprising a copolymer of one or more aliphatic monoalphaolefins and a monomeric acrylate, methacrylate, acrylic acid or methacrylic acid, the amount of (c) being at least sufficient to impart to the blend a resistance to impact failure in thick sections greater than that possessed by (a), and a weld line impact strength better than that possessed by (a) and (b) in combination, the total weight of (a), (b), and (c) combined is 100 parts.
Claim 18
Dependent Claim 151 words
A thermoplastic composition comprising an intimate blend of (a) from about 55 to about 93 parts by weight of an aromatic polycarbonate resin; (b) from about 3.5 to about 30 parts by weight of a polymer made solely from olefin monomers selected from the group consisting of polyolefin homopolymer, an olefin copolymer or terpolymer made solely from olefin monomers and mixtures thereof; and (c) from about 3.5 to 15 parts by weight of a third polymeric component comprising a copolymer of one or more aliphatic monoalphaolefins and a monomeric acrylate, methacrylate, acrylic acid or methacrylic acid, the amount of (c) being at least sufficient to impart to the blend a resistance to impact failure in thick sections greater than that possessed by (a), and a weld line impact strength better than that possessed by (a) and (b) in combination, the total weight of (a), (b), and (c) combined is 100 parts.

References Cited (Backward Citations)

US3431224A Cited
US4226950A Cited
US4257937A Cited
US4257937B1 Cited
US4363201A Cited
JPS57153041A Cited
JPS57153042A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-29 1989-01-28 1989-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-29 1993-01-28 1993-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-29 1997-01-28 1997-07-30 $7700.00 Window Closed / Lapsed

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