US4531982A
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US
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Superconductor manufacturing process
Assignee: Alstom SA
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Filing: 1984-03-09
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Granted: 1985-07-30
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Expires: 2004-03-09
Abstract
Abstract A superconductor manufacturing process provides electrical insulation and enhanced transverse electrical resistivity of multifilament superconductor strands based on Nb 3 Sn. The process includes forming, during the early manufacturing steps in which the product is relatively short and of large cross section, resistive barriers around bundles of filaments in an oxide powder doped with conductive materials. In subsequent steps, an electrically insulative powder is used to insulate between a copper tube surrounding the bundles of filaments and an outer resistive ring or to insulate around multifilament strands.
Inventors
- 👤 Patrick Dubots
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 16:23
CPC Classifications
H; H10; H10N; H10N60/00; H10N60/01; H10N60/0184; H10N60/0212; Y; Y10; Y10S; Y10S505/00; Y10S505/80; Y10S505/815; Y10S505/825; Y10S505/917; Y10S505/918; Y10S505/919; Y10S505/92; Y10S505/921; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49014
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
178 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) arranging the multifilament strand into a desired configuration; (f) heating the strand in the desired configuration to a temperature at which the first metal combines with the second metal material to form a superconductor, wherein the improvement comprises: between steps (c) and (d) surrounding said bronze tube with a resistive tube and disposing between the bronze tube and the resistive tube an electrically insulating refractory powder that is not soluble in the material of either tube.
Claim 2
Dependent Claim
178 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) arranging the multifilament strand into a desired configuration; (f) heating the strand in the desired configuration to a temperature at which the first metal combines with the second metal material to form a superconductor, wherein the improvement comprises: between steps (c) and (d) surrounding said bronze tube with a resistive tube and disposing between the bronze tube and the resistive tube an electrically insulating refractory powder that is not soluble in the material of either tube.
Claim 3
Dependent Claim
16 words
A process according to claim 1 further comprising the step of precompacting the insulating refractory powder.
Claim 4
Dependent Claim
19 words
A process according to claim 1, wherein the insulating refractory powder is aluminum oxide (Al 2 O 3 ).
Claim 5
Dependent Claim
15 words
A process according to claim 1, wherein the insulating refractory powder is magnesium oxide (MgO).
Claim 6
Dependent Claim
19 words
A process according to claim 1, wherein the insulating refractory powder is a glass stable at 800 degrees C.
Claim 7
Dependent Claim
19 words
A process according to claim 1, wherein the insulating refractory powder is a quartz stable at 800 degrees C.
Claim 8
Dependent Claim
91 words
A process according to claim 1, further comprising: between steps (c) and (d), working the bronze tube packed with the plurality of said rods to form a multifilament rod having a hexagonal cross section and packing a plurality of said multifilament hexagonal rods into an additional tube, said steps of working the bronze tube packed with rods into a hexagonal multifilament rod and packing a plurality of said multifilament rods into an additional tube being performed at least once, and the final one of said additional tubes being composed of copper.
Claim 9
Dependent Claim
51 words
A process according to claim 7, the process further comprising: prior to step (d), surrounding said final additional tube composed of copper with a resistive tube and disposing between the copper tube and the resistive tube an electrically insulating refractory powder that is not soluble in the material of either tube.
Claim 10
Dependent Claim
19 words
A process according to claim 8, the process further comprising the step of precompacting said electrically insulating refractory powder.
Claim 11
Dependent Claim
38 words
A process according to claim 1, further comprising: forming at least one hexagonal rod composed of copper and substituting at least one of said hexagonal copper rods for a corresponding at least one of said plurality of rods.
Claim 12
Dependent Claim
29 words
A process according to claim 1, further comprising: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor.
Claim 13
Dependent Claim
20 words
A process according to claim 11, wherein the resistive barrier material comprises: an oxide powder doped with a conductive substance.
Claim 14
Dependent Claim
16 words
A process according to claim 12 further comprising the step of precompacting the doped oxide powder.
Claim 15
Dependent Claim
20 words
A process according to claim 12, wherein the resistive barrier material comprises: magnesium oxide (MgO) doped with a copper alloy.
Claim 16
Dependent Claim
33 words
A process according to claim 11, wherein the matrix is an intermetallic compound in the form of niobium-tin (Nb 3 Sn), the first metal is bronze, and the second metal material is niobium.
Claim 17
Dependent Claim
36 words
A process according to claim 11, wherein the matrix is an intermetallic compound selected from the group consisting of niobium-silicon (Nb 3 Si); niobium-aluminum (Nb 3 Al); vanadium-gallium (V 3 Ga); and vanadium-silicon (V 3 Si).
Claim 18
Dependent Claim
21 words
A process according to claim 11, wherein the matrix is an intermetallic compound in the form of a CHEVREL phase-based superconductor.
Claim 19
Dependent Claim
23 words
A process according to claim 10, wherein the matrix is an intermetallic compound in the form of lead-molybdenum-sulfur (PbMo 6 S 8 ).
Claim 20
Dependent Claim
200 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) coating the multifilament strand with an insulative sheath; (f) placing a plurality of said sheathed strands together to form a multistrand conductor; (g) arranging the multifilament conductor into a desired configuration; (h) heating the conductor in the desired configuration to a temperature at which the first metal combines with the one element to form a superconductor, wherein the improvement comprises: between steps (c) and (d) surrounding said bronze tube with a resistive tube and disposing between the bronze tube and the resistive tube an electrically insulating refractory powder that is not soluble in the material of either tube.
Claim 21
Dependent Claim
200 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) coating the multifilament strand with an insulative sheath; (f) placing a plurality of said sheathed strands together to form a multistrand conductor; (g) arranging the multifilament conductor into a desired configuration; (h) heating the conductor in the desired configuration to a temperature at which the first metal combines with the one element to form a superconductor, wherein the improvement comprises: between steps (c) and (d) surrounding said bronze tube with a resistive tube and disposing between the bronze tube and the resistive tube an electrically insulating refractory powder that is not soluble in the material of either tube.
Claim 22
Dependent Claim
91 words
A process according to claim 19, further comprising: between steps (c) and (d), working the bronze tube packed with the plurality of said rods to form a multifilament rod having a hexagonal cross section, and packing a plurality of said multifilament hexagonal rods into an additional tube, said steps of working the bronze tube packed with rods into a hexagonal multifilament rod and packing a plurality of said multifilament rods into an additional tube being performed at least once, and the final one of said additional tubes being composed of copper.
Claim 23
Dependent Claim
41 words
A process according to claim 19, further comprising: forming at least one hexagonal rod composed of copper and substituting at least one of said hexagonal copper rods for a corresponding at least one of said plurality of rods in step (c).
Claim 24
Dependent Claim
29 words
A process according to claim 19, further comprising: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor.
Claim 25
Dependent Claim
174 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal marterial being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) arranging the multifilament strand into a desired configuration; (f) heating the strand in the desired configuration to a temperature at which the first metal combines with the second metal material to form a superconductor, wherein the improvement comprises: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor, the resistive barrier material comprising an oxide powder doped with a conductive substance.
Claim 26
Dependent Claim
174 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal marterial being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) arranging the multifilament strand into a desired configuration; (f) heating the strand in the desired configuration to a temperature at which the first metal combines with the second metal material to form a superconductor, wherein the improvement comprises: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor, the resistive barrier material comprising an oxide powder doped with a conductive substance.
Claim 27
Dependent Claim
16 words
A process according to claim 23 further comprising the step of precompacting the doped oxide powder.
Claim 28
Dependent Claim
20 words
A process according to claim 23, wherein the resistive barrier material comprises: magnesium oxide (MgO) doped with a copper alloy.
Claim 29
Dependent Claim
196 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) coating the multifilament strand with an insulative sheath; (f) placing a plurality of said sheathed strands together to form a multistrand conductor; (g) arranging the multifilament conductor into a desired configuration; (h) heating the conductor in the desired configuration to a temperature at which the first metal combines with the one element to form a superconductor, wherein the improvement comprises: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor, the resistive barrier material comprising an oxide powder doped with a conductive substance.
Claim 30
Dependent Claim
196 words
A process for manufacturing a superconductor, the process having the following sequential steps: (a) placing a bar of a first metal in a matrix of at least a second and a third metal material, said second metal material being capable of combining, when heated, with the first metal to form a superconductor; (b) working the bar and matrix together to form a rod having a hexagonal cross section; (c) packing a plurality of said rods into a bronze tube; (d) repeatedly drawing the assembly of the preceding step to form a multifilament strand having a reduced cross section and increased length; (e) coating the multifilament strand with an insulative sheath; (f) placing a plurality of said sheathed strands together to form a multistrand conductor; (g) arranging the multifilament conductor into a desired configuration; (h) heating the conductor in the desired configuration to a temperature at which the first metal combines with the one element to form a superconductor, wherein the improvement comprises: step (c) includes disposing a resistive barrier material between the packed rods to reduce spurious induced currents in the finished superconductor, the resistive barrier material comprising an oxide powder doped with a conductive substance.
Claim 31
Dependent Claim
16 words
A process according to claim 26 further comprising the step of precompacting the doped oxide powder.
Claim 32
Dependent Claim
20 words
A process according to claim 26, wherein the resistive barrier material comprises: magnesium oxide (MgO) doped with a copper alloy.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-29 | 1989-01-28 | 1989-07-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-29 | 1993-01-28 | 1993-07-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-29 | 1997-01-28 | 1997-07-30 | $7700.00 | Window Closed / Lapsed |