US4531141A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Heat-sensitive composition and imaging sheet incorporating same
Assignee: 3M Co
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Filing: 1983-01-17
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Granted: 1985-07-23
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Expires: 2003-01-17
Abstract
Abstract Heat-sensitive composition containing (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical change which results in change of color, and (2) a non-complexing phenolic compound which enhances the color forming reaction. This composition can be applied to a substrate, such as, for example, paper of film, in order to form a heat-sensitive imaging sheet.
Inventors
- 👤 Burt K. Sagawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 23:49
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/32
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
204 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants being selected from the group of reactants consisting of (a) a ferric salt of an organic acid and a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy and (b) a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 2
Dependent Claim
204 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants being selected from the group of reactants consisting of (a) a ferric salt of an organic acid and a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy and (b) a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 3
Dependent Claim
108 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said reactants comprising a ferric salt of an organic acid and a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy, and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 4
Dependent Claim
108 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said reactants comprising a ferric salt of an organic acid and a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy, and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 5
Dependent Claim
44 words
The sheet material of claim 2 wherein said phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy has hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 6
Dependent Claim
14 words
The sheet material of claim 2 wherein the non-complexing phenolic compound is a bisphenol.
Claim 7
Dependent Claim
13 words
The sheet material of claim 4 wherein the non-complexing phenolic compound is 4,4'-isopropylidenediphenol.
Claim 8
Dependent Claim
162 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said reactants comprising a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 9
Dependent Claim
162 words
A heat-sensitive sheet material comprising (a) a substrate, (b) a heat-sensitive layer bonded to said substrate, said layer comprising (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said reactants comprising a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change and (2) a non-complexing phenolic compound, said non-complexing phenolic compound having no hydroxyl groups in adjacent positions on any aromatic ring thereof.
Claim 10
Dependent Claim
14 words
The sheet material of claim 6 wherein the non-complexing phenolic compound is a bisphenol.
Claim 11
Dependent Claim
13 words
The sheet material of claim 7 wherein the non-complexing phenolic compound is 4,4'-isopropylidenediphenol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-22 | 1989-01-21 | 1989-07-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-22 | 1993-01-21 | 1993-07-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-22 | 1997-01-21 | 1997-07-23 | $7700.00 | Window Closed / Lapsed |