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US4530950A Expired / Lapsed US ⏱️ 0.0 years remaining

Piperidine derivatives and use thereof as stabilizers for polymers

Assignee: 3V PARTECIPAZIONI INDUSTRIALI SpA
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Filing: 1983-01-24
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Granted: 1985-07-23
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Expires: 2003-01-24
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Abstract

Abstract The invention relates to novel polyalkyl piperidine derivatives and use thereof as stabilizers for polymers. More particularly the invention relates to compounds having the general formula I <IMAGE> where R denotes hydrogen, alkyl, cycloalkyl, alkenyl, aralkyl or aryl; R1 and R'1 denote hydrogen, alkyl, alkenyl or aralkyl; R2 and R'2 denote hydrogen or methyl; X and X' denote oxygen or NR3; R3 denotes hydrogen, alkyl, cycloalkyl or aralkyl; A and A' denote (CH2)mX''; m equals 2 or 3; X'' has the same meaning as X and X', and n can be 0 or 1.

Inventors

  • 👤 Guiseppe Raspanti
  • 👤 Norberto Fossati
  • 👤 Attilio Ferrari

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:10
CPC Classifications
C; C07; C07D; C07D401/00; C07D401/14

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 237 words
Compounds having the general formula I ##STR14## in which R denotes hydrogen, a straight-chain or branched-chain alkyl radical having 1 to 18 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms, an alkenyl radical having 3 to 18 carbon atoms, an aralkyl radical having 7 to 19 carbon atoms or an aryl radical having 6 to 12 carbon atoms; R 1 and R' 1 can be the same or different and denote hydrogen, a straight-chain or branched alkyl radical having 1 to 12 carbon atoms, an alkenyl radical having 3 to 8 carbon atoms, or an aralkyl radical having 7 to 19 carbon atoms; R 2 and R' 2 can be the same or different and denote hydrogen or methyl; X and X' can be the same or different and denote oxygen or the group N-R 3 in which R 3 denotes hydrogen, a straight-chain or branched alkyl or hydroxyalkyl radical having 1 to 12 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms, or an aralkyl radical having 7 to 12 carbon atoms, A and A' can be the same or different and denote the radical (CH 2 )m-X" in which X" has the meaning previously defined for X and X', and is a direct bond to the triazine ring, m can be 2 or 3 and n is equal to zero or 1, and salts thereof with organic or inorganic acids.
Claim 2
Dependent Claim 237 words
Compounds having the general formula I ##STR14## in which R denotes hydrogen, a straight-chain or branched-chain alkyl radical having 1 to 18 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms, an alkenyl radical having 3 to 18 carbon atoms, an aralkyl radical having 7 to 19 carbon atoms or an aryl radical having 6 to 12 carbon atoms; R 1 and R' 1 can be the same or different and denote hydrogen, a straight-chain or branched alkyl radical having 1 to 12 carbon atoms, an alkenyl radical having 3 to 8 carbon atoms, or an aralkyl radical having 7 to 19 carbon atoms; R 2 and R' 2 can be the same or different and denote hydrogen or methyl; X and X' can be the same or different and denote oxygen or the group N-R 3 in which R 3 denotes hydrogen, a straight-chain or branched alkyl or hydroxyalkyl radical having 1 to 12 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms, or an aralkyl radical having 7 to 12 carbon atoms, A and A' can be the same or different and denote the radical (CH 2 )m-X" in which X" has the meaning previously defined for X and X', and is a direct bond to the triazine ring, m can be 2 or 3 and n is equal to zero or 1, and salts thereof with organic or inorganic acids.
Claim 3
Dependent Claim 33 words
Compounds according to claim 1 having the formula: ##STR15## where R, R 1 , R' 1 , R 2 , R' 2 , X and X' have the meanings defined in claim 1.
Claim 4
Dependent Claim 27 words
Compounds according to claim 1 having the formula: ##STR16## where R, R 1 , R' 1 , X and X' have the meanings defined in claim 1.
Claim 5
Dependent Claim 21 words
Compounds according to claim 1 having the formula: ##STR17## wherein R, X and X' have the meanings defined in claim 1.
Claim 6
Dependent Claim 21 words
Compounds according to claim 1 having the formula: ##STR18## where R and R 3 have the meanings defined in claim 1.
Claim 7
Dependent Claim 9 words
Compounds according to claim 1 having the formula: ##STR19##
Claim 8
Dependent Claim 18 words
Compounds according to claim 1 having the formula: ##STR20## where R has the meaning defined in claim 1.
Claim 9
Dependent Claim 21 words
Compounds according to claim 1 having the formula: ##STR21## where R and R 3 have the meanings defined in claim 1.
Claim 10
Dependent Claim 74 words
A method of preparing compounds having the formula I according to claim 1, characterized in that one mol of a substituted triazine having the formula II ##STR22## where R has the meaning defined in claim 1 and Y denotes chlorine or bromine, is reacted with 2 or more mols of a compound having the formula III ##STR23## where R, R 1 , R 2 , X, (A) and n have the meanings previously defined.
Claim 11
Dependent Claim 32 words
A method of stabilizing a polymer against the deteriorating effects of ultra-violet radiation which comprises incorporating in the polymer 0.1-5.0% by weight of the polymer of a compound according to claim 1.
Claim 12
Dependent Claim 28 words
A polymer composition stabilized against the deteriorating effects of ultra-violet radiation comprising a polymer and 0.0-5.0% by weight of the polymer of a compound according to claim 1.

References Cited (Backward Citations)

US3925376A Cited
US4191683A Cited
US4140673A Cited
US4161592A Cited
US4321374A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-22 1989-01-21 1989-07-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-22 1993-01-21 1993-07-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-22 1997-01-21 1997-07-23 $7700.00 Window Closed / Lapsed

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