US4529681A
Expired / Lapsed
US
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Light- and heat-sensitive recording material
Assignee: Fujifilm Holdings Corp
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Filing: 1983-11-17
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Granted: 1985-07-16
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Expires: 2003-11-17
Abstract
Abstract A light- and heat-sensitive recording material is disclosed. The material include microcapsule in which are encapsulated a particular combination comprised of a vinyl compound, a photopolymerization initiator, and a color forming component being capable of undergoing a color reaction with another color forming component to cause color formation. These coloring components are provided on the same side of a support.
Inventors
- 👤 Toshimasa Usami
- 👤 Toshiharu Tanaka
- 👤 Masato Satomura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 14:00
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/002; B; B41; B41M; B41M5/00; B41M5/26; B41M5/28; B41M5/287; H; H10; H10P; H10P76/00; H10P76/20; H10P76/204; H10P76/2041; H10P76/2043; B41M5/30; B41M5/323; B41M5/333; B41M5/337; B41M5/3372; B41M5/3375
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
101 words
A light- and heat-sensitive recording material, comprising: a support base having on one surface thereof; a plurality of microcapsules containing a vinyl compound, a photopolymerization initiator, a first color forming component capable of undergoing a color reaction with a second component to form a color, and a solvent; and said second color forming component, wherein said solvent and said first color forming component are present in the core of said microcapsulates and said second color forming component-is present outside of said microcapsules said recording material coloring by heat, and said vinyl compound being caused to polymerize by light, thereby preventing coloration.
Claim 2
Dependent Claim
101 words
A light- and heat-sensitive recording material, comprising: a support base having on one surface thereof; a plurality of microcapsules containing a vinyl compound, a photopolymerization initiator, a first color forming component capable of undergoing a color reaction with a second component to form a color, and a solvent; and said second color forming component, wherein said solvent and said first color forming component are present in the core of said microcapsulates and said second color forming component-is present outside of said microcapsules said recording material coloring by heat, and said vinyl compound being caused to polymerize by light, thereby preventing coloration.
Claim 3
Dependent Claim
44 words
A light- and heat-sensitive recording material as claimed in claim 1, wherein the vinyl compound contains a group selected from the groups consisting of an acryloyl group, a methacryloyl group, an allyl group, an unsaturated polyester group, a vinyloxy group, and an acrylamido group.
Claim 4
Dependent Claim
40 words
A light- and heat-sensitive recording material as claimed in claim 1, wherein the vinyl compound is a reaction product of polyols, polyamines or aminoalcohols with unsaturated carboxylic acids, or a reaction products of hydroxy group-containing acrylates or methacrylates with polyisocyanates.
Claim 5
Dependent Claim
30 words
A light- and heat-sensitive recording material as claimed in claim 3, wherein the vinyl compound is present in the capsule in an amount of about 10 to 90 wt %.
Claim 6
Dependent Claim
31 words
A light- and heat-sensitive recording material as claimed in claim 1, wherein the photopolymerization initiator is selected from the group consisting of aromatic ketones, quinone compounds, ether compounds and nitro compounds.
Claim 7
Dependent Claim
38 words
A light- and heat-sensitive recording material as claimed in claim 5, wherein the photopolymerization initiator is present in an amount of 0.1 wt % to 30 wt % based on 100 percent by weight of the vinyl compound.
Claim 8
Dependent Claim
60 words
A light- and heat-sensitive recording material as claimed in claim 1, said coloring forming components are selected from the groups wherein the first color forming component is a color former and the second color forming component is a color developer, or the first color forming component is a diazo compound and the second color forming component is a coupling component.
Claim 9
Dependent Claim
36 words
A light- and heat-sensitive recording material as claimed in claim 1 or 7, wherein the first color forming component is present in the microcapsule in a concentration in the range of 0.1 to 50 wt %.
Claim 10
Dependent Claim
45 words
A light- and heat-sensitive recording material as claimed in claim 7, wherein the color former is present in an amount of 0.05 to 1.5 g/m 2 and the color developer is present in an amount in the range of 0.5 to 4.0 g/m 2 .
Claim 11
Dependent Claim
48 words
A light- and heat-sensitive recording material as claimed in claim 9, wherein the color former is present in an amount in the range of 0.05 to 0.4 g/m 2 and the color developer is present in an amount in the range of 0.5 to 2.0 g/m 2 .
Claim 12
Dependent Claim
140 words
A process for forming color images in a light- and heat-sensitive recording material which comprises imagewise exposing the recording material to light and uniformly heating to form a color image on the unexposed area, or imagewise heating the recording material to form a color image and uniformly exposing to light to prevent undesired coloration; said light- and heat-sensitive recording material being a recording material comprising a support base having on one surface thereof a plurality of microcapsules containing a vinyl compound, a photopolymerization initiator, a first color forming component capable of undergoing a color reaction with a second component to form a color, and a solvent, and second color forming component wherein said solvent and said first color forming component are present in the core of said microcapsules and said second color forming component is present outside of said microcapsules.
Claim 13
Dependent Claim
140 words
A process for forming color images in a light- and heat-sensitive recording material which comprises imagewise exposing the recording material to light and uniformly heating to form a color image on the unexposed area, or imagewise heating the recording material to form a color image and uniformly exposing to light to prevent undesired coloration; said light- and heat-sensitive recording material being a recording material comprising a support base having on one surface thereof a plurality of microcapsules containing a vinyl compound, a photopolymerization initiator, a first color forming component capable of undergoing a color reaction with a second component to form a color, and a solvent, and second color forming component wherein said solvent and said first color forming component are present in the core of said microcapsules and said second color forming component is present outside of said microcapsules.
Claim 14
Dependent Claim
51 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 11, wherein the vinyl compound contains a group selected from the groups consisting of an acryloyl group, a methacryloyl group, an allyl group, an unsaturated polyester group, a vinyloxy group, and an acrylamido group.
Claim 15
Dependent Claim
37 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 12, wherein the vinyl compound is present in the capsule in an amount of about 10 to 90 wt %.
Claim 16
Dependent Claim
38 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 11, wherein the photopolymerization initiator is selected from the group consisting of aromatic ketones, quinone compounds, ether compounds and nitro compounds.
Claim 17
Dependent Claim
45 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 14, wherein the photopolymerization initiator is present in an amount of 0.1 wt % to 30 wt % based on 100 percent by weight of the vinyl compound.
Claim 18
Dependent Claim
38 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 11, wherein the first color forming component is a color former and the second color forming component is a color developer.
Claim 19
Dependent Claim
41 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 11, wherein the first color forming component is present in the microcapsule in a concentration in the range of 0.1 to 50 wt %.
Claim 20
Dependent Claim
41 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 15, wherein the first color forming component is present in the microcapsule in a concentration in the range of 0.1 to 50 wt %.
Claim 21
Dependent Claim
52 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 16, wherein the color former is present in an amount of 0.05 to 1.5 g/m 2 and the color developer is present in an amount in the range of 0.5 to 4.0 g/m 2 .
Claim 22
Dependent Claim
55 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 18, wherein the color former is present in an amount in the range of 0.05 to 0.4 g/m 2 and the color developer is present in an amount in the range of 0.5 to 2.0 g/m 2 .
Claim 23
Dependent Claim
18 words
A light- and heat-sensitive recording material as claimed in claim 1, said solvent comprising at least one oil.
Claim 24
Dependent Claim
25 words
A process for forming color images in a light- and heat-sensitive recording material as claimed in claim 11, said solvent comprising at least one oil.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-07-15 | 1989-01-14 | 1989-07-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-07-15 | 1993-01-14 | 1993-07-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-07-15 | 1997-01-14 | 1997-07-16 | $7700.00 | Window Closed / Lapsed |