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US4528085A Expired / Lapsed US ⏱️ 0.0 years remaining

Ion selective electrode and process of preparing the same

Assignee: Fujifilm Holdings Corp
•
Filing: 1983-03-15
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Granted: 1985-07-09
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Expires: 2003-03-15
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Abstract

Abstract An ion selective electrode comprising a support having provided thereon, in sequence, a conductive layer and an ion selective layer, which is characterized by having at least one groove through the conductive layer and covering the surface of the groove with the ion selective layer is disclosed. Half cells or electrodes useful for the measurement of ionic activity of chlorine, sodium, potassium or, carbonate or hydrogen carbonate ions in blood or other aqueous sample liquids can be prepared in an extremely simple manner. The single ion selective electrode element comprising paired ion selective electrodes in accordance with the present invention are electrochemically equivalent. A process for forming the same is also disclosed.

Inventors

  • 👤 Masao Kitajima
  • 👤 Osamu Seshimoto
  • 👤 Shigemitsu Mizutani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 09:19
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; G01N27/333; G01N27/3335

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 45 words
An ion selective electrode comprising a support having provided thereon, in sequence, a conductive layer and a substantially electrically insulating ion selective layer, said conductive layer having at least one groove therethrough, and, the surface of said groove being covered with said ion selective layer.
Claim 2
Dependent Claim 45 words
An ion selective electrode comprising a support having provided thereon, in sequence, a conductive layer and a substantially electrically insulating ion selective layer, said conductive layer having at least one groove therethrough, and, the surface of said groove being covered with said ion selective layer.
Claim 3
Dependent Claim 25 words
The ion selective electrode as claimed in claim 1 wherein said groove has a depth at least 10 times the thickness of said conductive layer.
Claim 4
Dependent Claim 22 words
The ion selective electrode as claimed in claim 1 wherein said groove has an opening width of 10 μm to 1 mm.
Claim 5
Dependent Claim 34 words
The ion selective electrode as claimed in claim 1 wherein said conductive layer is selected from the group consisting of a layer of a conductive metal and a layer of a conductive metal oxide.
Claim 6
Dependent Claim 42 words
The ion selective electrode as claimed in claim 4 wherein a layer of a water insoluble salt of the conductive metal employed for said conductive layer (a water-insoluble metal salt layer) is provided between said conductive layer and said ion selective layer.
Claim 7
Dependent Claim 26 words
The ion selective electrode as claimed in claim 5 wherein an electrolyte layer is provided between said water-insoluble metal salt layer and said ion selective layer.
Claim 8
Dependent Claim 29 words
The ion selective electrode as claimed in claim 5 wherein said conductive layer is a silver layer and said water insoluble metal salt layer is a silver halide layer.
Claim 9
Dependent Claim 19 words
The ion selective electrode as claimed in claim 7 wherein said silver halide layer is a silver chloride layer.
Claim 10
Dependent Claim 33 words
The ion selective electrode as claimed in claim 1 wherein at least one of the conductive layers separated from each other by said groove have an area sufficient to provide an electro-motive force.
Claim 11
Dependent Claim 35 words
A single electrode element comprising a pair of the ion selective electrodes of claim 1 wherein said support and said substantially electrically insulating ion selective layer are common to the pair of ion selective electrodes.
Claim 12
Dependent Claim 25 words
The single electrode element as claimed in claim 10 wherein said groove has a depth at least 10 times the thickness of said conductive layer.
Claim 13
Dependent Claim 22 words
The single electrode element as claimed in claim 10 wherein said groove has an opening width of 10 μm to 1 mm.
Claim 14
Dependent Claim 33 words
The single electrode element as claimed in claim 10 wherein at least one of the conductive layers separated from each other by said groove have an area sufficient to provide an electro-motive force.
Claim 15
Dependent Claim 34 words
The single electrode element as claimed in claim 10 wherein said conductive layer is selected from the group consisting of a layer of a conductive metal and a layer of a conductive metal oxide.
Claim 16
Dependent Claim 42 words
The single electrode element as claimed in claim 14 wherein a layer of a water insoluble salt of the conductive metal employed for said conductive layer (a water-insoluble metal salt layer) is provided between said conductive layer and said ion selective layer.
Claim 17
Dependent Claim 26 words
The single electrode element as claimed in claim 15 wherein an electrolyte layer is provided between said water-insoluble metal salt layer and said ion selective layer.
Claim 18
Dependent Claim 29 words
The single electrode element as claimed in claim 15 wherein said conductive layer is a silver layer and said water insoluble metal salt layer is a silver halide layer.
Claim 19
Dependent Claim 19 words
The single electrode element as claimed in claim 17 wherein said silver halide layer is a silver chloride layer.

References Cited (Backward Citations)

US4020830A Cited
US4020830B1 Cited
US4053381A Cited
US4269682A Cited
US4214968A Cited
US4184936A Cited
US4273639A Cited
EP0023156A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-08 1989-01-07 1989-07-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-08 1993-01-07 1993-07-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-08 1997-01-07 1997-07-09 $7700.00 Window Closed / Lapsed

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