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US4526839A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for thermally spraying porous metal coatings on substrates

Assignee: Surface Science Corp
•
Filing: 1984-03-01
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Granted: 1985-07-02
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Expires: 2004-03-01
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Abstract

Abstract A process for forming a substantially planar porous metal coating on a substrate which comprises thermal spraying of the metal on the substrate to form a porous metal coating on the substrate, rolling the sprayed coating to render it substantially planar and in the process close the pores, and then removing part of the surface to improve planarity and to reopen the surface-connected pores of the surface. The metal to be sprayed may be in the form of a wire, powder or molten metal mass and be selected from the group consisting of aluminum, zinc, tin, copper, nickel, or their alloys. Preferably, the substrate is selected from the group consisting of steel, aluminum, aluminized or galvanized steel, tin plate, and plastic. The spraying is preferably conducted in a non-oxidizing or reducing atmosphere. Preferably, the coating on the substrate is subjected to cold rolling. Most preferably, the rolling is conducted so as to reduce the coating thickness to approximately half of its original thickness. The coated substrates are useful for a number of purposes, particularly where the substrate metal would not be useful by itself because it does not have the proper physical or chemical properties. The substantially planar porous metal coated substrates are particularly desirable for subsequent coating with other materials, especially organic coatings, because of the "tooth" for the coating provided by the pores of the metal coating on the substrate. The substantially planar porous metal coated substrates of the invention are particularly suited as the base for either a presensitized or "wipe-on" lithographic printing plate.

Inventors

  • 👤 Herbert Herman
  • 👤 Daniel R. Marantz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 20:33
CPC Classifications
C; C23; C23C; C23C4/00; C23C4/18; B; B41; B41N; B41N1/00; B41N1/04; B41N1/08; Y; Y10; Y10S; Y10S29/00; Y10S29/039; Y10S428/00; Y10S428/922; Y10S428/9335; Y10S428/937; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/12028; Y10T428/12042; Y10T428/12063; Y10T428/12993

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 60 words
A process for forming a substantially planar porous metal coating on a substrate which comprises thermal spraying of the metal on the substrate, rolling the sprayed coating to render it substantially planar but thereby closing some of the pores, and then surface finishing part of the surface to improve planarity and to reopen some of the pores of the coating.
Claim 2
Dependent Claim 60 words
A process for forming a substantially planar porous metal coating on a substrate which comprises thermal spraying of the metal on the substrate, rolling the sprayed coating to render it substantially planar but thereby closing some of the pores, and then surface finishing part of the surface to improve planarity and to reopen some of the pores of the coating.
Claim 3
Dependent Claim 21 words
A process as claimed in claim 1 in which the metal to be sprayed is in the form of a wire.
Claim 4
Dependent Claim 21 words
A process as claimed in claim 1 in which the metal to be sprayed is in the form of molten metal.
Claim 5
Dependent Claim 35 words
A process as claimed in claim 1 in which the metal to be sprayed onto the substrate is selected from the group consisting of aluminum, zinc, tin, copper, nickel, and their alloys, and ferrous alloys.
Claim 6
Dependent Claim 28 words
A process as claimed in claim 1 in which the substrate is selected from the group consisting of steel, aluminum, aluminized steel, galvanized steel, tin plate, and plastic.
Claim 7
Dependent Claim 19 words
A process as claimed in claim 1 in which the substrate is introduced into the process from a coil.
Claim 8
Dependent Claim 25 words
A process as claimed in claim 1 in which the surface of the substrate is cleaned prior to or contemporaneously with its being thermally spray-coated.
Claim 9
Dependent Claim 26 words
A process as claimed in claim 1 in which the surface of the substrate is cleaned by heating to temperature of at least about 500° F.
Claim 10
Dependent Claim 27 words
A process as claimed in claim 1 in which the thermal spraying step utilizes the flame, two-wire electric arc, or molten metal electric arc thermal spray method.
Claim 11
Dependent Claim 17 words
A process as claimed in claim 1 in which the spraying is conducted in a non-oxidizing atmosphere.
Claim 12
Dependent Claim 18 words
A process as claimed in claim 1 in which the spraying is conducted in a chemically reducing atmosphere.
Claim 13
Dependent Claim 19 words
A process as claimed in claim 1 in which the coating on the substrate is subjected to cold rolling.
Claim 14
Dependent Claim 28 words
A process as claimed in claim 1 in which the rolling is conducted so as to reduce the metal coating thickness to approximately half of its original thickness.
Claim 15
Dependent Claim 38 words
A process as claimed in claim 1 in which the rolling is conducted so as to reduce the roughness root mean square height of the metal coating to a range of from about 90 to about 150 microinches.
Claim 16
Dependent Claim 22 words
A process as claimed in claim 1 in which the removal of part of the surface utilizes abrasives brushed against the surface.
Claim 17
Dependent Claim 42 words
A process as claimed in claim 1 in which the thermal spraying is accomplished by electric-arc spraying with arc current at from about 25 to about 600 amps. D.C. and with arc voltage of from about 19 to about 30 volts D.C.
Claim 18
Dependent Claim 38 words
A process as claimed in claim 1 in which the atomizing gas is selected from the group consisting of air, nitrogen and NH x and is used at a pressure of from about 40 to about 120 p.s.i.
Claim 19
Dependent Claim 32 words
A process as claimed in claim 1 in which the metal to be sprayed is in the form of a wire with a diameter of from about 0.035 to about 0.062 inches.
Claim 20
Dependent Claim 50 words
A process as claimed in claim 1 in which the origin of the spray is from about 2 to about 12 inches from the surface the substrate to be coated and the angle of the spray to the surface of the substrate is from about 60 to about 120 degrees.
Claim 21
Dependent Claim 30 words
A process as claimed in claim 1 in which the the spray gun traverses the surface of the substrate at a rate of from about 2 to about 50 surface-feet/minute.
Claim 22
Dependent Claim 26 words
A process as claimed in claim 1 in which the temperature of the substrate to be coated is from about room temperature to about 900° F.
Claim 23
Dependent Claim 31 words
A process as claimed in claim 1 in which the process is conducted in such a manner as to form a spray coating of from about 0.001 to about 0.010 inches.
Claim 24
Dependent Claim 51 words
A substantially planar porous metal coated substrate which comprises a substrate, a thermal spray coating of the metal on the substrate, rolled so as to render the sprayed coating substantially planar, and then part of the surface removed to improve planarity and to reopen some of the pores of the coating.
Claim 25
Dependent Claim 51 words
A substantially planar porous metal coated substrate which comprises a substrate, a thermal spray coating of the metal on the substrate, rolled so as to render the sprayed coating substantially planar, and then part of the surface removed to improve planarity and to reopen some of the pores of the coating.
Claim 26
Dependent Claim 32 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the metal coating is selected from the group consisting of aluminum, zinc, tin, copper, nickel, and their alloys.
Claim 27
Dependent Claim 31 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the substrate is selected from the group consisting of steel, aluminum, aluminized steel, galvanized steel, and plastic.
Claim 28
Dependent Claim 25 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the coating on the substrate has been subjected to cold rolling.
Claim 29
Dependent Claim 35 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the coating has been rolled so as to reduce the metal coating thickness down to approximately half of its as-sprayed thickness.
Claim 30
Dependent Claim 31 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the coating has a roughness root mean square height of from about 10 to about 30 microinches.
Claim 31
Dependent Claim 28 words
A substantially planar porous metal coated substrate as claimed in claim 23 in which the coating has a porosity of from about 8 to about 15 volume percent.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-01 1988-12-31 1989-07-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-01 1992-12-31 1993-07-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-01 1996-12-31 1997-07-02 $7700.00 Window Closed / Lapsed

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