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US4525524A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester composition

Assignee: Shell USA Inc
•
Filing: 1984-04-16
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Granted: 1985-06-25
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Expires: 2004-04-16
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Abstract

Abstract Polyester compositions which are dispersible or soluble in water based systems can be very valuable as adhesives, coatings, paints, and the like. The use of water based solvent systems eliminates recovery and toxicity problems normally related with many organic solvents. The polyester compositions of this invention have an increased affinity for water based systems by the incorporation therein salts of organic sulfonic acid monomers and by carboxyl terminating these polyesters to a very substantial degree. The water based systems in which these modified polyesters are useful contain an alcohol in addition to water.

Inventors

  • 👤 William C. T. Tung
  • 👤 George A. Deisz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 04:33
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/85; A61Q; A61Q5/00; A61Q5/06; C09; C09D; C09D167/00; C09D167/02; C09J; C09J167/00; C09J167/02

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 259 words
A liquid system comprised of: (A) a water/alcohol solvent comprised of from 50 to 80 weight percent water and from 20 to 50 weight percent of at least one alcohol having from 3 to 5 carbon atoms; and (B) a polyester comprised of repeat units which are derived from (a) a diacid component which is comprised of (1) from 20 to 90 mole percent of at least one member selected from the group consisting of dimethylterephthalate and terephthalic acid, (2) from 1 to 6 mole percent of at least one salt of an organic sulfonic acid monomer, and (3) from 4 to 74 mole percent of at least one member selected from the group consisting of alkyl dicarboxylic acids having from 4 to 36 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 36 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 22 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 22 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 20 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acids; and (b) a diol component which is comprised of (1) from 20 to 100 mole percent ethylene glycol, and (2) from 0 to 80 mole percent of one or more member selected from the group consisting of glycols having from 3 to 12 carbon atoms; wherein said polyester is terminated with carboxyl end groups and wherein said liquid system has a pH of at least 7.
Claim 2
Dependent Claim 259 words
A liquid system comprised of: (A) a water/alcohol solvent comprised of from 50 to 80 weight percent water and from 20 to 50 weight percent of at least one alcohol having from 3 to 5 carbon atoms; and (B) a polyester comprised of repeat units which are derived from (a) a diacid component which is comprised of (1) from 20 to 90 mole percent of at least one member selected from the group consisting of dimethylterephthalate and terephthalic acid, (2) from 1 to 6 mole percent of at least one salt of an organic sulfonic acid monomer, and (3) from 4 to 74 mole percent of at least one member selected from the group consisting of alkyl dicarboxylic acids having from 4 to 36 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 36 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 22 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 22 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 20 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acids; and (b) a diol component which is comprised of (1) from 20 to 100 mole percent ethylene glycol, and (2) from 0 to 80 mole percent of one or more member selected from the group consisting of glycols having from 3 to 12 carbon atoms; wherein said polyester is terminated with carboxyl end groups and wherein said liquid system has a pH of at least 7.
Claim 3
Dependent Claim 29 words
A liquid system as specified in claim 1 wherein said alcohol is selectd from the group consisting of isopropyl alcohol, n-butanol, n-propyl alcohol, tert-butyl alcohol, s-butyl alcohol, and isobutanol.
Claim 4
Dependent Claim 22 words
A liquid system as specified in claim 2 wherein said liquid system contains from 1 to 60 weight percent of said polyester.
Claim 5
Dependent Claim 22 words
A liquid system as specified in claim 3 wherein said liquid system contains from 5 to 40 weight percent of said polyester.
Claim 6
Dependent Claim 21 words
A liquid system as specified in claim 4 wherein said polyester has a molecular weight of about 1000 to about 7000.
Claim 7
Dependent Claim 22 words
A liquid system as specified in claim 5 wherein said liquid system contains from 10 to 30 weight percent of said polyester.
Claim 8
Dependent Claim 36 words
A liquid system as specified in claim 6 wherein said salt of an organic sulfonic acid monomer is an alkali salt of a sulfo dialkyl isophthalate and wherein said polyester is carboxyl terminated with trimellitic anhydride.
Claim 9
Dependent Claim 15 words
A liquid system as specified in claim 1 wherein said liquid system is a hair-spray.
Claim 10
Dependent Claim 22 words
A liquid system as specified in claim 7 wherein said liquid system has a pH in the range of 7 to 8.
Claim 11
Dependent Claim 23 words
A liquid system as specified in claim 9 wherein the pH of said liquid system is adjusted by the addition of ammonium hydroxide.
Claim 12
Dependent Claim 19 words
A liquid system as specified in claim 7 wherein said polyester has a molecular weight of 2,000 to 5,000.
Claim 13
Dependent Claim 22 words
A liquid system as specified in claim 11 wherein said liquid system has a pH in the range of 7 to 9.
Claim 14
Dependent Claim 25 words
A liquid system as specified in claim 12 wherein said akali salt of a sulfo dialkyl isophthalate is a sodium salt of sulfo dimethyl isophthalate.
Claim 15
Dependent Claim 60 words
A polyester as specified in claim 13 wherein said diol component is comprised of (1) from 50 to 100 mole percent ethylene glycol and (2) from 0 to 50 mole percent of one or more members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms.
Claim 16
Dependent Claim 53 words
A polyester as specified in claim 14 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are glycols having from 3 to 8 carbon atoms and glycol ethers having from 4 to 8 carbon atoms.
Claim 17
Dependent Claim 58 words
A polyester as specified in claim 14 wherein said members selected from the group consisting of glycols having from 3 to 12 carbon atoms and glycol ethers having from 4 to 12 carbon atoms are selected from the group consisting of 1,3-propylene glycol, 1,2-propylene glycol, 2,2-diethyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-2-isobutyl-1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,2,4-trimethyl-1,6-hexanediol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
Claim 18
Dependent Claim 14 words
A polyester as specified in claim 13 wherein said diol component is ethylene glycol.
Claim 19
Dependent Claim 129 words
A polyester as specified in claim 14 wherein said members selected from the group consisting of alkyl dicarboxylic acids having from 4 to 20 carbon atoms, diesters of alkyl dicarboxylic acids having from 6 to 20 carbon atoms, aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of aryl dicarboxylic acids having from 11 to 20 carbon atoms, alkyl substituted aryl dicarboxylic acids having from 9 to 20 carbon atoms, diesters of alkyl substituted aryl dicarboxylic acids having from 11 to 20 carbon atoms, dimethylorthophthalate, dimethylisophthalate, orthophthalic acid, and isophthalic acid are selected from the group consisting of isophthalic acid and azelaic acid wherein said diol component is comprised of from 50 to 100 mole percent ethylene glycol and from 0 to 50 mole percent neopentyl glycol.

References Cited (Backward Citations)

US3563942A Cited
US3853820A Cited
US4156073A Cited
US4299743A Cited
US4427557A Cited
US4401787A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-24 1988-12-24 1989-06-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-24 1992-12-24 1993-06-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-24 1996-12-24 1997-06-25 $7700.00 Window Closed / Lapsed

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