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US4524038A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making a vibration-resistant electrical component and connection lead combination, particularly exhaust gas composition sensor

Assignee: Robert Bosch GmbH
•
Filing: 1982-09-27
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Granted: 1985-06-18
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Expires: 2002-09-27
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Abstract

Abstract To manufacture a vibration-resistant, shock-resistant electrical connection on a ceramic substrate (11) having an electrically conductive layer (12) applied to a surface (13, 19) thereof, a groove or channel-like depression (16, 20) is formed in the surface, preferably also including a through-bore (18), into which a conductor (17) is placed. The space between the conductor and the groove, the through-bore, if provided, and an extending groove at the other surface (19) of the substrate is filled with a sinterable mass (21), preferably a cermet, containing a metal which is compatible with the metal of the conductor wire (17), both for example containing platinum. As a starting material, the plate with the grooves therein is extrusion-pressed, pre-sintered at a low temperature to give it form stability, then the electrode (12) is applied, then the electrical conductor (17) and the cermet is applied and then the entire sub-assembly is fired to sintering temperature, e.g. about 1500° C.; if desired, a further protective coating (22) of magnesium spinel may be plasma-sprayed on. Due to shrinkage of the ceramic components, the wire (17) will be securely held in position in the groove, and the cermet additionally forming an electrical connection between the wire and the substrate (11). For additional strain relief, the groove can be undulating (FIG. 3).

Inventors

  • 👤 Wolfgang Heinemann
  • 👤 Rainer Noack
  • 👤 Helmut Weyl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 09:49
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/407; G01N27/4075; H; H05; H05K; H05K3/00; H05K3/30; H05K3/32; H05K3/321; H05K3/40; H05K3/4092; H05K1/00; H05K1/02; H05K1/03; H05K1/0306; H05K1/09; H05K1/092; H05K2201/00; H05K2201/10; H05K2201/10227; H05K2201/10295; H05K2201/10303; H05K2201/1034; H05K2201/10613; H05K2201/10742; H05K2201/10886; H05K2201/10946; H05K2203/00; H05K2203/14; H05K2203/1453; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49117; Y10T29/49169; Y10T29/49171; Y10T29/49172

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 313 words
Method of making an electrical component which comprises a substrate (11, 11') of brittle, sinterable material having the characteristic of shrinking upon sintering and having an exposed surface (13, 19); a layer electrode (12, 12') applied to said exposed surface; an electrical connection wire (17) electrically connected to said layer electrode and mechanically retained on the substrate; wherein a bonding mass is provided, securing the connecting wire to the substrate and retaining said wire thereon, comprising, in accordance with the invention, the steps of forming the substrate (11, 11') in unsintered state; forming the surface (13, 19) of the substrate in the region of the connection of the layer electrode (12, 12') and the connection wire (17) with a channel-like depression or groove (16, 16') extending essentially parallel to said surface, the groove being defined and positioned between groove walls; pre-sintering the so formed substrate to render the substrate form-stable; applying said layer electrode (12, 12') to said surface (13, 19); positioning the connection wire (17) longitudinally within said groove (16, 16') and essentially parallel to said surface, the diameter of said connection wire being just slightly smaller than the width of the groove to leave a small clearance space between the longitudinally positioned and opposed groove walls; introducing an electrically conductive sinterable bonding material (21) into the clearance space between the groove walls and the connection wire, said sinterable bonding material surrounding and embedding the connection wire therein to form a sub-assembly comprising the substrate (11, 11'), the layer electrode (12, 12') thereon, the connection wire (17) within the groove (16, 16') and the sinterable bonding material (21) in said groove; and then finish-sintering said sub-assembly while shrinking the substrate and the sinterable bonding material to securely hold the connection wire in said groove by clamping of the wire between the groove walls upon shrinkage of the substrate and the bonding material.
Claim 2
Dependent Claim 313 words
Method of making an electrical component which comprises a substrate (11, 11') of brittle, sinterable material having the characteristic of shrinking upon sintering and having an exposed surface (13, 19); a layer electrode (12, 12') applied to said exposed surface; an electrical connection wire (17) electrically connected to said layer electrode and mechanically retained on the substrate; wherein a bonding mass is provided, securing the connecting wire to the substrate and retaining said wire thereon, comprising, in accordance with the invention, the steps of forming the substrate (11, 11') in unsintered state; forming the surface (13, 19) of the substrate in the region of the connection of the layer electrode (12, 12') and the connection wire (17) with a channel-like depression or groove (16, 16') extending essentially parallel to said surface, the groove being defined and positioned between groove walls; pre-sintering the so formed substrate to render the substrate form-stable; applying said layer electrode (12, 12') to said surface (13, 19); positioning the connection wire (17) longitudinally within said groove (16, 16') and essentially parallel to said surface, the diameter of said connection wire being just slightly smaller than the width of the groove to leave a small clearance space between the longitudinally positioned and opposed groove walls; introducing an electrically conductive sinterable bonding material (21) into the clearance space between the groove walls and the connection wire, said sinterable bonding material surrounding and embedding the connection wire therein to form a sub-assembly comprising the substrate (11, 11'), the layer electrode (12, 12') thereon, the connection wire (17) within the groove (16, 16') and the sinterable bonding material (21) in said groove; and then finish-sintering said sub-assembly while shrinking the substrate and the sinterable bonding material to securely hold the connection wire in said groove by clamping of the wire between the groove walls upon shrinkage of the substrate and the bonding material.
Claim 3
Dependent Claim 41 words
Method according to claim 1, wherein the groove has a depth slightly deeper than the diameter of the wire, and the sinterable bonding material (21) surrounds said wire at least in the region of connection with the layer electrode (12, 12').
Claim 4
Dependent Claim 35 words
Method according to claim 1, wherein the step of forming the substrate in unsintered state includes extruding and pressing a plate-like quantity of said sinterable substrate material while simultaneously forming the channel-like depression or groove.
Claim 5
Dependent Claim 56 words
Method according to claim 1, wherein the step of forming said channel-like depression or groove (16, 16') comprises forming the channel-like depression in zig-zag or undulating form; and the step of positioning the connection wire comprises pre-forming the connection wire to match the undulation or zig-zag configuration of said groove, and placing said connection wire therein.
Claim 6
Dependent Claim 56 words
Method according to claim 3, wherein the step of forming said channel-like depression or groove (16, 16') comprises forming the channel-like depression in zig-zag or undulating form; and the step of positioning the connection wire comprises pre-forming the connection wire to match the undulation or zig-zag configuration of said groove, and placing said connection wire therein.
Claim 7
Dependent Claim 82 words
Method according to claim 1, including the step of forming a through-opening (18) adjacent the end portion of the channel-like depression or groove (16, 16') extending from said exposed surface of the substrate (11) to an opposite surface thereof; and wherein the step of positioning the connection wire (17) comprises introducing said connection wire through said opening (18); and the further step of introducing the sinterable bonding material comprises introducing the sinterable bonding material around the connection wire and into the through-opening.
Claim 8
Dependent Claim 36 words
Method according to claim 6, including the step of forming an extending channel-like depression or groove (20) at least approximately comparable to said groove (16, 16') in the opposite surface (19) of the substrate (11, 11').
Claim 9
Dependent Claim 29 words
Method according to claim 7, wherein the step of forming said extending groove comprises positioning said extending groove in a plane spaced from the plane of said groove (16).
Claim 10
Dependent Claim 26 words
Method according to claim 8, wherein said extending groove is in at least approximate alignment with, and extending in the same direction as said groove (16).
Claim 11
Dependent Claim 37 words
Method according to claim 7, further including sinterable bonding material (21) positioned in said extending groove, and forming part of said sub-assembly; and wherein the finish-sintering step includes sintering all the sinterable bonding material on said substrate.
Claim 12
Dependent Claim 14 words
Method according to claim 1, wherein said sinterable bonding material comprises a conductive cermet.
Claim 13
Dependent Claim 21 words
Method according to claim 11, wherein the step of introducing the sinterable bonding material comprises dripping said bonding material in suspension.
Claim 14
Dependent Claim 12 words
Method according to claim 11, wherein said cermet includes a noble metal.
Claim 15
Dependent Claim 12 words
Method according to claim 11, wherein said cermet includes a platinum metal.
Claim 16
Dependent Claim 16 words
Method according to claim 11, wherein said cermet includes zirconium dioxide as the ceramic component thereof.
Claim 17
Dependent Claim 43 words
Method according to claim 1, further including the step of coating at least a portion of the region of said substrate, and including at least a portion of the layer electrode (12, 12') and said connection wire (17) with an insulating layer (22).
Claim 18
Dependent Claim 13 words
Method according to claim 16, wherein said insulating layer (22) comprises magnesium spinel.
Claim 19
Dependent Claim 15 words
Method according to claim 16, wherein the step of applying said insulating layer comprises plasma-spraying.
Claim 20
Dependent Claim 32 words
Method according to claim 16, wherein the step of applying said insulating layer is carried out before finish-sintering; and wherein the step of finish-sintering includes sintering said insulating layer on the substrate.
Claim 21
Dependent Claim 15 words
Method according to claim 1, wherein the substrate (11, 11') essentially consists of zirconium dioxide.
Claim 22
Dependent Claim 19 words
Method according to claim 1, wherein said electrically conductive layer comprises at least part of a resistance heating layer.
Claim 23
Dependent Claim 50 words
Method according to claim 2, wherein the electrical component is an oxygen sensor, including an electrical connecting wire therefor; wherein the substrate (11, 11') is a plate-like element consisting, essentially, of zirconium dioxide; and wherein said sinterable bonding material (21) comprises a cermet including zirconium dioxide and a noble metal.
Claim 24
Dependent Claim 41 words
Method according to claim 1, wherein the steps of positioning the connecting wire (17) and introducing the sinterable bonding material (21) is carried out in the sequence: (a) first positioning the connection wire, and (b) then introducing the sinterable bonding material.
Claim 25
Dependent Claim 41 words
Method according to claim 1, wherein the steps of positioning the connecting wire (17) and introducing the sinterable bonding material (21) is carried out in the sequence: (a) first introducing the sinterable bonding material, and (b) then positioning the connection wire.

References Cited (Backward Citations)

US2750657A Cited
US3405382A Cited
US3968193A Cited
DE2526340A1 Cited
US4374457A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-17 1988-12-17 1989-06-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-17 1992-12-17 1993-06-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-17 1996-12-17 1997-06-18 $7700.00 Window Closed / Lapsed

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