Patent EP0250078A2 successfully refreshed from Google Patents.
US4522706A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hydrocarbon treating processes using perovskite-containing catalytic compositions
Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1983-12-23
•
Granted: 1985-06-11
•
Expires: 2003-12-23
Abstract
Abstract Hydrocarbon treating processes such as catalytic cracking and fluid coking are provided in which a perovskite-containing catalytic composition is used as catalyst. The perovskite-containing catalytic composition is produced by interrupting the reaction of perovskite precursors after formation of at least 60 wt. % perovskite and before formation of more than 99 wt. % perovskite from the precursors.
Inventors
- 👤 Kenneth S. Wheelock
- 👤 Robert C. Schucker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 13:03
CPC Classifications
C; C10; C10B; C10B55/00; C10B55/02; B; B01; B01J; B01J23/00; B01J23/005; C10G; C10G11/00; C10G11/02; C10G11/04; Y; Y10; Y10S; Y10S502/00; Y10S502/525
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
221 words
A fluid coking process which comprises contacting a hydrocarbonaceous feed having a Conradson carbon ranging from about 5 to about 50 weight percent at fluid coking conditions with a catalyst comprising a composition comprising at least about 60 weight percent perovskite and less than about 99 weight percent of a perovskite ABO 3 , and a non-perovskite reaction residue, wherein A is a cation of at least one metal, wherein B is a cation different from said cation A of at least one metal, said perovskite comprising at least one transition metal cation selected from the group consisting of elements having atomic numbers ranging from 21 through 30, through 39 through 48, from 57 through 80, and from 89 through 90, said composition having been prepared by reacting a component A comprising said cation A and a component B comprising said cation B at a temperature ranging from about 600° to about 2000° C. and for a time sufficient to form said perovskite ABO 3 and interrupting said reaction after formation of at least about 60 weight percent perovskite and before the formation of more than about 99 weight percent of said perovskite ABO 3 , based on the weight of said component A plus component B whereby the remainder of said composition is a non-perovskite residue resulting from said reaction.
Claim 2
Dependent Claim
221 words
A fluid coking process which comprises contacting a hydrocarbonaceous feed having a Conradson carbon ranging from about 5 to about 50 weight percent at fluid coking conditions with a catalyst comprising a composition comprising at least about 60 weight percent perovskite and less than about 99 weight percent of a perovskite ABO 3 , and a non-perovskite reaction residue, wherein A is a cation of at least one metal, wherein B is a cation different from said cation A of at least one metal, said perovskite comprising at least one transition metal cation selected from the group consisting of elements having atomic numbers ranging from 21 through 30, through 39 through 48, from 57 through 80, and from 89 through 90, said composition having been prepared by reacting a component A comprising said cation A and a component B comprising said cation B at a temperature ranging from about 600° to about 2000° C. and for a time sufficient to form said perovskite ABO 3 and interrupting said reaction after formation of at least about 60 weight percent perovskite and before the formation of more than about 99 weight percent of said perovskite ABO 3 , based on the weight of said component A plus component B whereby the remainder of said composition is a non-perovskite residue resulting from said reaction.
Claim 3
Dependent Claim
26 words
The process of claim 1 wherein said reaction is interrupted after the formation of at least about 65 weight percent of said perovskite ABO 3 .
Claim 4
Dependent Claim
73 words
The process of claim 1 wherein component A is a metal oxide or compound convertible to a metal oxide and wherein said component B is a metal oxide or compound convertible to a metal oxide, and wherein component A and component B are reacted by heating said component A and component B for a time sufficient to convert at least a portion of said component A and said component B to said perovskite.
Claim 5
Dependent Claim
25 words
The fluid coking process of claim 3 wherein said component A and said component B are heated for a time up to about 32 hours.
Claim 6
Dependent Claim
37 words
The process of claim 3 wherein said component A and said component B are heated at a temperature ranging from about 800° to about 1500° C. with alternating particle size reduction of the resulting heated solid product.
Claim 7
Dependent Claim
27 words
The process of claim 1 wherein at least one of said cations is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium and mixtures thereof.
Claim 8
Dependent Claim
22 words
The process of claim 1 wherein said perovskite is selected from the group consisting of barium zirconate, barium hafnate and mixtures thereof.
Claim 9
Dependent Claim
23 words
The fluid coking process of claim 1 wherein said fluid coking conditions include a temperature ranging from about 850° to about 1400° F.
Claim 10
Dependent Claim
25 words
The fluid coking process of claim 1 wherein said heating is conducted at a temperature of about 1250° C. for about 60 to 90 minutes.
Claim 11
Dependent Claim
16 words
The process of claim 1 wherein said catalyst consists essentially of said perovskite and said residue.
References Cited (Backward Citations)
US3595809A
Cited
US4152299A
Cited
US4151123A
Cited
US4055513A
Cited
US4102777A
Cited
US4134852A
Cited
US4179409A
Cited
US4208269A
Cited
US4269696A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-10 | 1988-12-10 | 1989-06-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-10 | 1992-12-10 | 1993-06-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-10 | 1996-12-10 | 1997-06-11 | $7700.00 | Window Closed / Lapsed |