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US4521508A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic light-sensitive materials

Assignee: Fujifilm Holdings Corp
•
Filing: 1983-11-07
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Granted: 1985-06-04
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Expires: 2003-11-07
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Abstract

Abstract A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I): A--S--S--B (I) wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.

Inventors

  • 👤 Tadao Sugimoto
  • 👤 Hideo Ikeda
  • 👤 Hiroyuki Mifune
  • 👤 Koki Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 16:34
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/09; Y; Y10; Y10S; Y10S430/00; Y10S430/141; Y10S430/15

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 126 words
A silver halide photographic light-sensitive material, comprising: a support base having thereon: a silver halide emulsion layer; and a protective layer; wherein the light-sensitive material contains a photosensitive halide emulsion, an inside fogged silver halide emulsion, and a disulfide compound represented by the general formula (I): A--S--S--B (I) wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR7## wherein R represents a alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group; wherein at least one of A or B represents a heterocyclic group or ##STR8## and wherein the disulfide compound represented by general formula (I) is present is an amount effective to improve maximum density and gamma of an image.
Claim 2
Dependent Claim 126 words
A silver halide photographic light-sensitive material, comprising: a support base having thereon: a silver halide emulsion layer; and a protective layer; wherein the light-sensitive material contains a photosensitive halide emulsion, an inside fogged silver halide emulsion, and a disulfide compound represented by the general formula (I): A--S--S--B (I) wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR7## wherein R represents a alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group; wherein at least one of A or B represents a heterocyclic group or ##STR8## and wherein the disulfide compound represented by general formula (I) is present is an amount effective to improve maximum density and gamma of an image.
Claim 3
Dependent Claim 17 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein B is a heterocyclic group.
Claim 4
Dependent Claim 17 words
A silver halide photographic light-sensitive material as claimed in claim 2, wherein A is a heterocyclic group.
Claim 5
Dependent Claim 31 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the photosensitive silver halide emulsion has a sensitivity higher than the sensitivity of the inside fogged silver halide emulsion.
Claim 6
Dependent Claim 35 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the photosensitive silver halide emulsion has a sensitivity 10 times or more greater than the sensitivity of the inside fogged silver halide emulsion.
Claim 7
Dependent Claim 35 words
A silver halide photographic light-sensitive material as claimed in claim 5, wherein the photosensitive silver halide emulsion has a sensitivity 100 times or more greater than the sensitivity of the inside fogged silver halide emulsion.
Claim 8
Dependent Claim 26 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the photosensitive silver halide emulsion is a surface latent image type silver halide emulsion.
Claim 9
Dependent Claim 35 words
A silver halide photographic light-sensitive material as claimed in claim 7, wherein the surface latent image type silver halide emulsion includes silver iodide in an amount in the range of 0.1 to 30% by mol.
Claim 10
Dependent Claim 35 words
A silver halide photographic light-sensitive material as claimed in claim 7, wherein the surface latent image type silver halide emulsion includes silver halide particles having an average particle size of 0.2 μm to 10 μm.
Claim 11
Dependent Claim 34 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the inside fogged silver halide emulsion includes silver halide particles having an average particle size of b 0.05 μm to 1.0 μm.
Claim 12
Dependent Claim 35 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ratio of the photosensitive silver halide emulsion to the inside fogged silver halide emulsion is in the range of 100:1 to 1:100.
Claim 13
Dependent Claim 38 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein the compound of general formula (I) is present in an amount in the range of 1×10 -5 to 1×10 -1 mol per mol of silver halide.
Claim 14
Dependent Claim 38 words
A silver halide photographic light-sensitive material as claimed in claim 12, wherein the compound of general formula (I) is present in an amount in the range of 1×10 -4 to 1×10 -2 mol per mol of silver halide.
Claim 15
Dependent Claim 37 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein said disulfide compound is in at least one layer from the group comprising a silver halide emulsion layer, a protective layer and any other layer.
Claim 16
Dependent Claim 23 words
A silver halide photographic light-sensitive material as claimed in claim 1, wherein said disulfide compound is in at least one hydrophilic colloid layer.

References Cited (Backward Citations)

US2438716A Cited
US2440110A Cited
US2756145A Cited
BE569317A Cited
US2996382A Cited
US3178282A Cited
GB963987A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-03 1988-12-03 1989-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-03 1992-12-03 1993-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-03 1996-12-03 1997-06-04 $7700.00 Window Closed / Lapsed

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