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US4521301A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of production of organic dithio-acids and their application

Assignee: Societe Nationale Elf Aquitaine Production SA
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Filing: 1984-03-05
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Granted: 1985-06-04
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Expires: 2004-03-05
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Abstract

Abstract Process for the preparation of an organic dithio-acid by reaction of the corresponding dithio-ester and an alkali metal or alkaline earth metal hydrosulphide in a solvent in the presence of an excess of H2S and treatment with a mineral acid. The dithioic acids so obtained can be utilized as collectors for the flotation of minerals.

Inventors

  • 👤 Jean-Louis Detienne
  • 👤 Guy Levesque
  • 👤 Pierre Tozzolino

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:44
CPC Classifications
C; C07; C07C; C07C327/00; B; B03; B03D; B03D1/00; B03D1/001; B03D1/004; B03D1/012; B03D2201/00; B03D2201/02; B03D2203/00; B03D2203/02

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 72 words
In a process of using a sulphur-containing material as a collector in the flotation of a mineral selected from the group consisting of galena, chalcopyrite and blende, the improvement which comprises employing as the collector a dithioic acid of the formula RCS.sub.2 H in which R is alkyl or alkenyl, linear or branched, of 4 to 20 carbon atoms which does not contain sulphur, or the sodium, potassium or ammonium salts thereof.
Claim 2
Dependent Claim 72 words
In a process of using a sulphur-containing material as a collector in the flotation of a mineral selected from the group consisting of galena, chalcopyrite and blende, the improvement which comprises employing as the collector a dithioic acid of the formula RCS.sub.2 H in which R is alkyl or alkenyl, linear or branched, of 4 to 20 carbon atoms which does not contain sulphur, or the sodium, potassium or ammonium salts thereof.
Claim 3
Dependent Claim 14 words
The process of claim 1 in which R contains 6 to 18 carbon atoms.
Claim 4
Dependent Claim 29 words
The process of claim 1 in which the dithioic acid is selected from the group consisting of dithiomyristic, dithiopalmitic, dithiooleic acid and the sodium, potassium or ammonium salts thereof.
Claim 5
Dependent Claim 19 words
The process of claim 1 wherein the dithioacid is dithiopentanoic acid or the sodium, potassium or ammonium salt thereof.
Claim 6
Dependent Claim 21 words
The process of claim 1 in which the dithioic acid is dithiocapoic acid or the sodium, potassium or ammonium salt thereof.
Claim 7
Dependent Claim 19 words
The process of claim 1 wherein the dithioacid is dithiolauric acid or the sodium, potassium or ammonium salt thereof.

References Cited (Backward Citations)

SU275915A1 Cited
US1788331A Cited
US2844584A Cited
FR2337199A1 Cited
US4235709A Cited
US4274950A Cited
US4324654A Cited
FR2458319A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-03 1988-12-03 1989-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-03 1992-12-03 1993-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-03 1996-12-03 1997-06-04 $7700.00 Window Closed / Lapsed

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