Patent US2799862A successfully refreshed from Google Patents.
US4520105A
Expired / Lapsed
US
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Process for production of sugars and optionally cellulose and lignin from lignocellulosic raw materials
Assignee: Bau und Forschungsgesellschaft Thermoform AG
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Filing: 1983-08-10
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Granted: 1985-05-28
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Expires: 2003-08-10
Abstract
Abstract A process for the production of sugars, and optionally cellulose and lignin, from lignocellulosic vegetable materials which comprises subjecting the vegetable materials to a chemical pretreatment with a mixture of water and lower aliphatic alcohols and/or ketones at a temperature from 100° to 190° C. for a period of from 4 hours to 2 minutes with control of the breakdown of the hemicellulose components followed by separation of residue and a subsequent main chemical treatment with a similar solvent mixture at elevated temperatures for a further period of from 6 hours to 2 minutes.
Inventors
- 👤 Michael Sinner
- 👤 Hans-Hermann Dietrichs
- 👤 Jurgen Puls
- 👤 Werner Schweers
- 👤 Karl-Heinz Brachthauser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:45
CPC Classifications
C; C13; C13K; C13K1/00; C13K1/02; C13K13/00; C13K13/002; D; D21; D21C; D21C3/00; D21C3/20
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
194 words
A process for treating vegetable material essentially comprised of cellulose, lignin and hemicelluloses, comprising the steps of: (a) treating said vegetable material under elevated pressure with a first solution comprising (i) water and acetone in a volume ratio between about 70:30 and 30:70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and about 220° C., such that substantially all of said lignin and said hemicelluloses are dissolved in said first solution and a residue comprising microcrystalline cellulose is formed; (b) separating said residue from said first solution; and (c) after step (b), treating said residue with a second solution comprising (i) water and acetone in a volume ratio between about 70:30 and 30:70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and about 220° C., such that said microcrystalline cellulose is substantially completely hydrolyzed to glucose, said glucose being dissolved in said second solution.
Claim 2
Dependent Claim
194 words
A process for treating vegetable material essentially comprised of cellulose, lignin and hemicelluloses, comprising the steps of: (a) treating said vegetable material under elevated pressure with a first solution comprising (i) water and acetone in a volume ratio between about 70:30 and 30:70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and about 220° C., such that substantially all of said lignin and said hemicelluloses are dissolved in said first solution and a residue comprising microcrystalline cellulose is formed; (b) separating said residue from said first solution; and (c) after step (b), treating said residue with a second solution comprising (i) water and acetone in a volume ratio between about 70:30 and 30:70, and (ii) at least one acid, said acid having a concentration, relative to the total volume of said first solution, of between about 0.001 and about 1N, at a temperature between about 170° and about 220° C., such that said microcrystalline cellulose is substantially completely hydrolyzed to glucose, said glucose being dissolved in said second solution.
Claim 3
Dependent Claim
25 words
A process according to claim 1, further comprising after step (a) vacuum distilling said first solution such that said lignin separates from said first solution.
Claim 4
Dependent Claim
39 words
A process according to claim 1, further comprising after step (c) the steps of (d) separating at least said acetone from said second solution to form an aqueous solution containing said glucose and (e) fermenting said glucose to alcohol.
Claim 5
Dependent Claim
20 words
A process according to claim 3, wherein step (d) comprises separating said acetone and said acid from said second solution.
Claim 6
Dependent Claim
33 words
A process according to claim 1, wherein step (a) is carried out at a temperature between about 180° and about 200° C., and for a period between about 5 and about 30 minutes.
Claim 7
Dependent Claim
34 words
A process according to claim 1, wherein step (c) is carried out at a temperature between about 180° and about 210° C., and for a period of between about 5 and about 60 minutes.
Claim 8
Dependent Claim
40 words
A process according to claim 1, wherein said concentration of said acid in said first solution is between about 0.01 and about 0.5N, and said concentration of said acid in said second solution is between about 0.01 and about 0.1N.
Claim 9
Dependent Claim
36 words
A process according to claim 1, wherein step (c) comprises stepwise treating said residue in a plurality of separate volumes of said second solution by replacing said solution with fresh solution every 3 to 15 minutes.
Claim 10
Dependent Claim
19 words
A process according to claim 8, wherein said replacing of said solution is carried out in a continuous manner.
Claim 11
Dependent Claim
34 words
A process according to claim 1, wherein said acid in each of said first and second solutions is separately selected from the group consisting of nitric acid, phosphoric acid, sulfuric acid, and hydrochloric acid.
Claim 12
Dependent Claim
15 words
A process according to claim 10, wherein said acid is hydrochloric acid or sulfuric acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1988-05-27 | 1988-11-26 | 1989-05-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-05-27 | 1992-11-26 | 1993-05-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-05-27 | 1996-11-26 | 1997-05-28 | $7700.00 | Window Closed / Lapsed |