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US4519825A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for recovering C4 + hydrocarbons using a dephlegmator

Assignee: Air Products and Chemicals Inc
•
Filing: 1983-04-25
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Granted: 1985-05-28
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Expires: 2003-04-25
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Abstract

Abstract A process is described for separating C 4 + hydrocarbons in high recovery and high purity from a feed gas comprising about 0-5% C 5 and heavier hydrocarbons, 1-10% C 4 hydrocarbons, 0-10% C 3 hydrocarbons, 0-10% C 2 hydrocarbons and the balance CH 4 and light inerts. Efficient separation is effected by using a dephlegmator cycle employing only internal refrigeration.

Inventors

  • 👤 Dennis P. Bernhard
  • 👤 Howard C. Rowles
  • 👤 Robert L. Teichman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 05:11
CPC Classifications
C; C07; C07C; C07C7/00; C07C7/09; F; F25; F25J; F25J3/00; F25J3/02; F25J3/0204; F25J3/0219; F25J3/0228; F25J3/0247; F25J3/0252; F25J2200/00; F25J2200/80; F25J2210/00; F25J2210/12; F25J2270/00; F25J2270/04

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 239 words
A process for separating C 4 and heavier hydrocarbons in high recovery and a purity of at least 60 mole %, from a feed gas comprising about 0-5 mole % C 5 and heavier hydrocarbons, 1-10% C 4 hydrocarbons, 0-10% C 3 hydrocarbons, 0-10% C 2 hydrocarbons, and the balance CH 4 and light inerts, which comprises: (a) pressurizing the feed gas to a level from 10 to 40 atmospheres if not at said level; (b) establishing and maintaining said feed gas at a temperature of from 2° to 38° C.; (c) passing said feed gas, prior to fractionation, to a dephlegmator, thereby cooling said feed gas to a preselected overhead temperature, within the range from -52° to -76° C., for forming a liquid condensate containing C 4 + hydrocarbons of a purity of at least 60 mole % and an overhead vapor fraction; (d) withdrawing said liquid condensate from the dephlegmator; (e) withdrawing said overhead vapor fraction from said dephlegmator and warming by indirect heat exchange against the feed in said dephlegmator; (f) work expanding the resulting warmed overhead vapor fraction in an expander to a pressure sufficient to generate a cold fraction having the required refrigeration value and having a temperature from about 2° to 15° C. below the preselected overhead temperature in said dephlegmator; and (g) withdrawing said cold fraction from the expander and again warming by indirect heat exchange against the feed in said dephlegmator.
Claim 2
Dependent Claim 239 words
A process for separating C 4 and heavier hydrocarbons in high recovery and a purity of at least 60 mole %, from a feed gas comprising about 0-5 mole % C 5 and heavier hydrocarbons, 1-10% C 4 hydrocarbons, 0-10% C 3 hydrocarbons, 0-10% C 2 hydrocarbons, and the balance CH 4 and light inerts, which comprises: (a) pressurizing the feed gas to a level from 10 to 40 atmospheres if not at said level; (b) establishing and maintaining said feed gas at a temperature of from 2° to 38° C.; (c) passing said feed gas, prior to fractionation, to a dephlegmator, thereby cooling said feed gas to a preselected overhead temperature, within the range from -52° to -76° C., for forming a liquid condensate containing C 4 + hydrocarbons of a purity of at least 60 mole % and an overhead vapor fraction; (d) withdrawing said liquid condensate from the dephlegmator; (e) withdrawing said overhead vapor fraction from said dephlegmator and warming by indirect heat exchange against the feed in said dephlegmator; (f) work expanding the resulting warmed overhead vapor fraction in an expander to a pressure sufficient to generate a cold fraction having the required refrigeration value and having a temperature from about 2° to 15° C. below the preselected overhead temperature in said dephlegmator; and (g) withdrawing said cold fraction from the expander and again warming by indirect heat exchange against the feed in said dephlegmator.
Claim 3
Dependent Claim 18 words
A process in accordance with claim 1 wherein the feed gas is dried prior to entering the dephlegamator.
Claim 4
Dependent Claim 22 words
A process in accordance with claim 1 wherein the liquid condensate withdrawn from the dephlegmator is subsequently passed through a depropanizer column.
Claim 5
Dependent Claim 23 words
A process in accordance with claim 1 wherein the feed gas is a refinery-type stream, or a stream generated by a dehydrogenation process.
Claim 6
Dependent Claim 30 words
A process in accordance with claim 1 wherein said C 4 and heavier hydrocarbons are selected from the group consisting of iso-paraffins, olefins, diolefins, cycloparaffins, aromatics, or any combination thereof.
Claim 7
Dependent Claim 27 words
A process in accordance with claim 1 wherein recovery of at least 95% of said C 4 and heavier hydrocarbons, and preferably at least 98%, is achieved.
Claim 8
Dependent Claim 30 words
A process in accordance with claim 1 wherein the purity of the combined C 4 and heavier hydrocarbon liquid condensate withdrawn from said dephlegmator is at least 75 mole %.
Claim 9
Dependent Claim 31 words
A process in accordance with claim 1 wherein said established temperature of said feed stream is less than or equal to 20° C. above the hydrocarbon dewpoint of said feed stream.

References Cited (Backward Citations)

US3274102A Cited
US4002042A Cited
US4140504A Cited
US4270940A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-27 1988-11-26 1989-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-27 1992-11-26 1993-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-27 1996-11-26 1997-05-28 $7700.00 Window Closed / Lapsed

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