Photoconductive devices containing perylene dye compositions

Claim 2

An improved photoresponsive device comprised in the order stated of (1) a supporting substrate, and (2) a photoconductive layer comprised of perylene dye compositions of the following formula: ##STR10## wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of alkyl groups and aryl groups.

Claim 3

An improved photoresponsive device comprised in the order stated of (1) a supporting substrate, (2) a photoconductive layer comprised of the perylene compositions of claim 1, and (3) a diamine hole transport layer.

Claim 4

An improved photoresponsive device comprised in the order stated of (1) a supporting substrate, (2) a diamine hole transport layer, and (3) a photoconductive layer comprised of the perylene compositions of claim 1.

Claim 5

An improved photoresponsive device in accordance with claim 1 wherein the perylene composition is N,N'-di(2,4,6-trimethylphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 6

An improved photoresponsive device in accordance with claim 1 wherein the perylene composition is N,N'-di(4-dimethylaminophenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 7

An improved photoresponsive device in accordance with claim 1 wherein the perylene composition is N,N'-di(2,6-dimethylphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 8

An improved photoresponsive device in accordance with claim 2 wherein the perylene composition is N,N'-di(2-tertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 9

An improved photoresponsive device in accordance with claim 2 wherein the perylene composition is N,N'-di(5-dichlorophenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 10

An improved photoresponsive device in accordance with claim 2 wherein the perylene composition is N,N'-di(2-methyl-4-chlorophenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 11

An improved photoresponsive device in accordance with claim 3 wherein the perylene composition is N,N'-di(2,6-dimethyl-4-tertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 12

An improved photoresponsive device in accordance with claim 3 wherein the perylene composition is N,N'-di(2,5-ditertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 13

An improved photoresponsive device in accordance with claim 3 wherein the perylene composition is N,N'-di(2,4,6-trimethoxyphenyl)perylene3,4,9,10tetracarboxyldiimide.

Claim 14

A photoresponsive device in accordance with claim 2 wherein the supporting substrate is comprised of a conductive metallic substance, or an insulating polymeric composition.

Claim 15

A photoconductive device in accordance with claim 3 wherein the supporting substrate is comprised of a conductive metallic substance, or an insulating polymeric composition.

Claim 16

A photoresponsive device in accordance with claim 13 wherein the substrate is aluminum.

Claim 17

A photoresponsive device in accordance with claim 14 wherein the conductive substrate is aluminum.

Claim 18

An improved photoresponsive device in accordance with claim 1 wherein the perylene composition is dispersed in a resinous binder in an amount of from about 5 percent by volume to about 95 percent by volume, and the diamine hole transport material is dispersed in a resinous binder in an amount of from about 10 percent by weight to about 75 percent by weight.

Claim 19

An improved photoresponsive device in accordance with claim 2 wherein the perylene composition is dispersed in a resinous binder in an amount of from about 5 percent by volume to about 95 percent by volume, and the diamine hole transport material is dispersed in a resinous binder in an amount of from about 10 percent by weight to about 75 percent by weight.

Claim 20

An improved photoresponsive device in accordance with claim 17 wherein the resinous binder for the perylene composition is a polyester, polyvinylcarbazole, polyvinylbutyral, a polycarbonate, or a phenoxy resin, and the resinous binder for the diamine hole transport material is a polycarbonate, a polyester, or a vinyl polymer.

Claim 21

A photoresponsive device in accordance with claim 18 wherein the resinous binder for the perylene composition is a polyester, polyvinylcarbazole, polyvinylbutyral, polycarbonate, or a phenoxy resin, and the resinous binder for the diamine hole transport material is a polycarbonate, a polyester, or vinyl polymer.

Claim 22

A photoresponsive device in accordance with claim 3 wherein the diamine charge transporting substance composition comprises molecules of the formula: ##STR11## dispersed in a highly insulating and transparent organic resinous material wherein X is selected from the group consisting of ortho (CH 3 ), meta (CH 3 ), para (CH 3 ), ortho (Cl), meta (Cl), para (Cl).

Claim 23

A photoresponsive device in accordance with claim 2 wherein the diamine charge transporting diamine composition comprises molecules of the formula: ##STR12## dispersed in a highly insulating and transparent organic resinous material wherein X is selected from the group consisting of ortho(CH 3 ), meta(CH 3 ), para(CH 3 ), ortho(Cl), meta(Cl), para(Cl).

Claim 24

a photoresponsive device in accordance with claim 21 wherein the diamine is comprised of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine.

Claim 25

A photoresponsive device in accordance with claim 22 wherein the diamine is comprised of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine.

Claim 26

An improved photoresponsive imaging member consisting essentially of a supporting substrate, a photoconductive layer comprised of the perylene compositions of claim 1, and a diamine hole transport layer containing molecules of the formula ##STR13## dispersed in a highly insulating and transparent organic resinous material wherein X is selected from the group consisting of ortho (CH 3 ), meta (CH 3 ), para (CH 3 ), ortho (Cl), meta (Cl) and para (Cl).

Claim 27

A photoresponsive imaging member in accordance with claim 25 wherein the perylene dye is selected from the group consisting of N,N'-di(2,4,6,-trimethylphenyl)perylene3,4,9,10tetracarboxylidiimide; N,N'-di(4,-dimethylaminophenyl)perylene3,4,9,10tetracarboxyldiimide; N,N'-di(2,6-dimethylphenyl)perylene3,4,9,10tetracarboxyldiimide; N,N'-di(2-tertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide; N,N'-di(5-dichlorophenyl)perylene3,4,9,10tetracarboxyldiimide; N,N'-di(2-methyl-4-chlorophenyl)perylene3,4,9,10tetracarboxyldiimide; N,N'-di(2,6-dimethyl-4-tertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide; and N,N'-di(2,5-ditertiarybutylphenyl)perylene3,4,9,10tetracarboxyldiimide.