One-part moisture-curable polyurethane adhesive, coating, and sealant compositions

Claim 2

Compositions, comprising: (a) isocyanate-functional prepolymer(s) derived from 4,4'-diphenylmethane diisocyanate (or isocyanate functional derivatives of 4,4'-diphenylmethane diisocyanate) and polyol(s) containing hydroxyl groups about 25 to 100 weight percent of which are primary hydroxyl groups, and (b) bis[2-(N,N-dialkylamino)alkyl]ether(s), in an amount effective to provide moisture curability of said prepolymer(s).

Claim 3

Compositions according to claim 1, wherein said polyol(s) have a hydroxyl equivalent weight from about 45 to about 2500, and a pH from about 5.5 to about 7.

Claim 4

Compositions according to claim 1, wherein said polyol(s) comprise polytetramethylene oxide glycols, ethylene oxide-terminated polypropylene glycols, or polycaprolactone polyols.

Claim 5

Compositions according to claim 1, wherein said prepolymer(s) are derived from two or more polyols, with about 25 to 100 weight percent of said polyols having primary hydroxyl groups, and about 75 to 0 weight percent of said polyols having secondary hydroxyl groups.

Claim 6

Compositions according to claim 4, wherein about 40 to about 80 weight percent of said polyols have primary hydroxyl groups, and about 60 to about 20 weight percent of said polyols have secondary hydroxyl groups.

Claim 7

Compositions according to claim 1, wherein said prepolymer(s) are the reaction product of isocyanate and hydroxyl-containing polyols combined at an NCO:OH equivalent ratio from about 1.2:1 to about 3.5:1.

Claim 8

Compositions according to claim 6, wherein said ratio is from about 1.8:1 to about 2.2:1.

Claim 9

Compositions according to claim 1, wherein said bis[2-(N,N-dialkylamino)alkyl]ether(s) comprise bis[2-(N,N-dimethylamino)ethyl]ether.

Claim 10

Adhesive, coating, or sealant compositions, comprising a composition according to claim 1, together with filler, solvent, and plasticizer.

Claim 11

Adhesive, coating, or sealant compositions, comprising a composition according to claim 3, together with filler, solvent, and plasticizer.

Claim 12

Adhesive, coating, or sealant compositions, comprising a composition according to claim 5, together with filler, solvent, and plasticizer.

Claim 13

Cured assemblies, comprising an article and a substrate, with a layer comprising a composition according to claim 1 therebetween.

Claim 14

A method for bonding articles to substrates, comprising the step of applying therebetween a layer comprising a composition according to claim 1.

Claim 15

Compositions, comprising (a) isocyanate-functional prepolymer(s) derived from 4,4'-diphenylmethane diisocyanate and two or more polyols, wherein about 40 to 80 weight percent of said polyols comprise polytetramethylene oxide glycols having a molecular weight of about 650 to about 2000, and about 60 to about 20 weight percent of said polyols comprise propylene oxide-terminated ethylene oxide glycols or polypropylene glycols, and (b) about 0.05 to about 0.5 weight percent, based upon the weight of said prepolymer, of bis[2-(N,N-dimethylamino)ethyl]ether.

Claim 16

Compositions, comprising (a) isocyanate-functional prepolymer(s) derived from 4,4'-diphenylmethane diisocyanate and two or more polyols, wherein about 40 to 80 weight percent of said polyols comprise polytetramethylene oxide glycols having a molecular weight of about 650 to about 2000, and about 60 to about 20 weight percent of said polyols comprise propylene oxide-terminated ethylene oxide glycols or polypropylene glycols, and (b) about 0.05 to about 0.5 weight percent, based upon the weight of said prepolymer, of bis[2-(N,N-dimethylamino)ethyl]ether.

Claim 17

Adhesive, coating, or sealant compositions, comprising a composition according to claim 9, together with filler, solvent, and plasticizer.

Claim 18

Bonded windshield or backlight assemblies, comprising a windshield or backlight of laminated safety glass, a vehicle, a layer comprising silane-containing primer on the inside perimeter of said glass, and a layer comprising a composition according to claim 9 between said primer layer and said vehicle.

Claim 19

A method for bonding articles to substrates, comprising the step of applying therebetween a layer comprising a composition according to claim 9.

Claim 20

Compositions, comprising compounds of the formula ##STR4## where m is 2 or more, n is greater than or equal to zero, and B is a radical of a polyvalent polyol containing hydroxyl groups about 25 to 100 weight percent of which are primary hydroxyl groups and having a backbone selected from divalent aliphatic, olefinic, ether, ester, thioether, urethane, or urea radicals, together with bis[2-(N,N-dialkylamino)alkyl]ether(s) in an amount effective to provide moisture curability of said compounds.

Claim 21

Compositions, comprising compounds of the formula ##STR4## where m is 2 or more, n is greater than or equal to zero, and B is a radical of a polyvalent polyol containing hydroxyl groups about 25 to 100 weight percent of which are primary hydroxyl groups and having a backbone selected from divalent aliphatic, olefinic, ether, ester, thioether, urethane, or urea radicals, together with bis[2-(N,N-dialkylamino)alkyl]ether(s) in an amount effective to provide moisture curability of said compounds.

Claim 22

Compositions according to claim 18, comprising compounds of the formula ##STR5## where B is a divalent polyether radical, together with bis[2-(N,N-dimethylamino)ethyl]ether.

Claim 23

Adhesive, coating, or sealant compositions, comprising a composition according to claim 11, together with filler, solvent, and plasticizer.