US4507563A — Radiographic image conversion screens

Claim 1

Independent Claim 357 words

A radiographic image conversion screen, having a speed and/or an image quality at least equal to that of a conventional radiographic image conversion screen which has only a green emitting rare earth phosphor layer, consisting essentially of: (a) a support; (b) a first fluorescent layer formed on said support and consisting essentially of a blue emitting phosphor which is selected from the group consisting of: (I) an alkaline earth metal complex halide phosphor represented by the formula: MeF.sub.2.pMe'X.sub.2.qKX'.rMe"SO.sub.4 :mEu.sup.2+,nTb.sup.3+ where Me is at least one element selected from the group consisting of magnesium, calcium, strontium and barium, each of Me' and Me" being at least one element selected from the group consisting of calcium, strontium and barium, each of X and X' being at least one element selected from the group consisting of chlorine and bromine, and p, q, r, m and n are numbers within the ranges of 0.80≦p≦1.5, 0≦q≦2.0, 0≦r≦1.0, 0.001≦m≦0.10 and 0≦n≦0.05, respectively; (II) a divalent metal tungstate phosphor represented by the formula: M.sup.II WO.sub.4 where M II is at least one element selected from the group consisting of magnesium, calcium, zinc and cadmium; (III) a zinc sulfide or zinc-cadmium sulfide phosphor represented by the formula: (Zn.sub.1-j, Cd.sub.j)S:Ag where j is a number within the range of 0≦j≦0.4; and (IV) a rare earth tantalate or tantalum-niobate phosphor represented by the formula: (Ln".sub.1-v,Tm.sub.v)(Ta.sub.1-w,Nb.sub.w)O.sub.4 where Ln" is at least one element selected from the group consisting of lanthanum, yttrium, gadolinium and lutetium, and v and w are numbers within the ranges of 0≦v≦0.1 and 0≦w≦0.3, respectively; and (c) a second fluorescent layer formed on said first fluorescent layer and consisting essentially of a green emitting rare earth oxysulfide phosphor represented by the formula: (Ln.sub.1-a-b,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where L is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and a and b are numbers within the ranges of 0.0005≦a≦0.09 and 0≦b≦0.01, respectively, or the formula: (Y.sub.1-i-a-b,Ln.sub.i,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and i, a and b are numbers within the ranges of 0.65≦i≦0.95, 0.0005≦a≦0.09 and 0≦b≦0.01, respectively.

Claim 2

Dependent Claim 357 words

A radiographic image conversion screen, having a speed and/or an image quality at least equal to that of a conventional radiographic image conversion screen which has only a green emitting rare earth phosphor layer, consisting essentially of: (a) a support; (b) a first fluorescent layer formed on said support and consisting essentially of a blue emitting phosphor which is selected from the group consisting of: (I) an alkaline earth metal complex halide phosphor represented by the formula: MeF.sub.2.pMe'X.sub.2.qKX'.rMe"SO.sub.4 :mEu.sup.2+,nTb.sup.3+ where Me is at least one element selected from the group consisting of magnesium, calcium, strontium and barium, each of Me' and Me" being at least one element selected from the group consisting of calcium, strontium and barium, each of X and X' being at least one element selected from the group consisting of chlorine and bromine, and p, q, r, m and n are numbers within the ranges of 0.80≦p≦1.5, 0≦q≦2.0, 0≦r≦1.0, 0.001≦m≦0.10 and 0≦n≦0.05, respectively; (II) a divalent metal tungstate phosphor represented by the formula: M.sup.II WO.sub.4 where M II is at least one element selected from the group consisting of magnesium, calcium, zinc and cadmium; (III) a zinc sulfide or zinc-cadmium sulfide phosphor represented by the formula: (Zn.sub.1-j, Cd.sub.j)S:Ag where j is a number within the range of 0≦j≦0.4; and (IV) a rare earth tantalate or tantalum-niobate phosphor represented by the formula: (Ln".sub.1-v,Tm.sub.v)(Ta.sub.1-w,Nb.sub.w)O.sub.4 where Ln" is at least one element selected from the group consisting of lanthanum, yttrium, gadolinium and lutetium, and v and w are numbers within the ranges of 0≦v≦0.1 and 0≦w≦0.3, respectively; and (c) a second fluorescent layer formed on said first fluorescent layer and consisting essentially of a green emitting rare earth oxysulfide phosphor represented by the formula: (Ln.sub.1-a-b,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where L is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and a and b are numbers within the ranges of 0.0005≦a≦0.09 and 0≦b≦0.01, respectively, or the formula: (Y.sub.1-i-a-b,Ln.sub.i,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and i, a and b are numbers within the ranges of 0.65≦i≦0.95, 0.0005≦a≦0.09 and 0≦b≦0.01, respectively.

Claim 3

Dependent Claim 99 words

The radiographic image conversion screen according to claim 1, wherein the phosphor in the blue emitting phosphor layer has a mean grain size of from 2 to 10μ, a standard deviation (quartile deviation) of the grain size of from 0.20 to 0.50 and a coating weight of from 2 to 100 mg/cm 2 , and the phosphor in the green emitting phosphor layer has a mean grain size of from 5 to 20μ, a standard deviation (quartile deviation) of the grain size of from 0.15 to 0.40 and a coating weight of from 5 to 100 mg/cm 2 .

Claim 4

Dependent Claim 99 words

The radiographic image conversion screen according to claim 2, wherein the phosphor in the blue emitting phosphor layer has a mean grain size of from 3 to 6μ, a standard deviation (quartile deviation) of the grain size of from 0.30 to 0.45 and a coating weight of from 3 to 50 mg/cm 2 , and the phosphor in the green emitting phosphor layer has a mean grain size of from 6 to 12μ, a standard deviation (quartile deviation) of the grain size of from 0.20 to 0.35 and a coating weight of from 20 to 80 mg/cm 2 .

Claim 5

Dependent Claim 49 words

The radiographic image conversion screen according to claim 1, wherein the blue emitting phosphor layer has a grain size distribution of the phosphor grains such that the grains size gradually becomes smaller from the side facing the green emitting rare earth phosphor layer to the side facing the support.

Claim 6

Dependent Claim 23 words

The radiographic image conversion screen according to claim 4, wherein a reflective layer is interposed between the support and the first fluorescent layer.

Claim 7

Dependent Claim 23 words

The radiographic image conversion screen according to claim 4, wherein an absorptive layer is interposed between the support and the first fluorescent layer.

Claim 8

Dependent Claim 23 words

The radiographic image conversion screen according to claim 4, wherein a metal foil is interposed between the support and the first fluorescent layer.

Claim 9

Independent Claim 383 words

A method of obtaining a radiographic image of a subject with a radiographic apparatus, comprising: obtaining a radiographic image of said subject with said radiographic device in which the image conversion screen, having a speed and/or an image quality at least equal to that of a conventional radiographic image conversion screen which has only a green emitting rare earth phosphor layer, consists essentially of: (a) a support; (b) a first fluorescent layer formed on said support and consisting essentially of a blue emitting phosphor which is selected from the group consisting of: (I) an alkaline earth metal complex halide phosphor represented by the formula: MeF.sub.2.pMe'X.sub.2.qKX'.rMe"SO.sub.4 :mEu.sup.2+,nTb.sup.3+ where Me is at least one element selected from the group consisting of magnesium, calcium, strontium and barium, each of Me' and Me" being at least one element selected from the group consisting of calcium, strontium and barium, each of X and X' being at least one element selected from the group consisting of chlorine and bromine, and p, q, r, m and n are numbers within the range of 0.80≦p≦1.5, 0≦q≦2.0, 0≦r≦1.0, 0.001≦m≦0.10 and 0≦n≦0.05, respectively, (II) a divalent metal tungstate phosphor represented by the formula: M.sup.II WO.sub.4 where M II is at least one element selected from the group consisting of magnesium, calcium, zinc and cadmium; (III) a zinc sulfide or zinc-cadmium sulfide phosphor represented by the formula: (Zn.sub.1-j,Cd.sub.j)S:Ag where j is a number within the range of 0≦j≦0.4; and (IV) a rare earth tantalate or tantalum-niobate phosphor represented by the formula: (Ln".sub.1-v,Tm.sub.v)(Ta.sub.1-w,Nb.sub.w)O.sub.4 where Ln" is at least one element selected from the group consisting of lanthanum, yttrium, gadolinium and lutetium, and v and w are numbers within the ranges of 0≦v≦0.1 and 0≦w≦0.3, respectively; and (c) a second fluorescent layer formed on said first fluorescent layer and consisting essentially of a green emitting rare earth oxysulfide phosphor represented by the formula: (Ln.sub.1-a-b,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and a and b are numbers within the ranges of 0.0005≦a≦0.09 and 0≦b≦0.01, respectively, or the formula: (Y.sub.1-i-a-b,Ln.sub.i,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and i, a and b are numbers within the ranges of 0.65≦i≦0.95, 0.0005≦a≦0.09 and 0≦b≦0.01, respectively.

Claim 10

Independent Claim 383 words

A method of obtaining a radiographic image of a subject with a radiographic apparatus, comprising: obtaining a radiographic image of said subject with said radiographic device in which the image conversion screen, having a speed and/or an image quality at least equal to that of a conventional radiographic image conversion screen which has only a green emitting rare earth phosphor layer, consists essentially of: (a) a support; (b) a first fluorescent layer formed on said support and consisting essentially of a blue emitting phosphor which is selected from the group consisting of: (I) an alkaline earth metal complex halide phosphor represented by the formula: MeF.sub.2.pMe'X.sub.2.qKX'.rMe"SO.sub.4 :mEu.sup.2+,nTb.sup.3+ where Me is at least one element selected from the group consisting of magnesium, calcium, strontium and barium, each of Me' and Me" being at least one element selected from the group consisting of calcium, strontium and barium, each of X and X' being at least one element selected from the group consisting of chlorine and bromine, and p, q, r, m and n are numbers within the range of 0.80≦p≦1.5, 0≦q≦2.0, 0≦r≦1.0, 0.001≦m≦0.10 and 0≦n≦0.05, respectively, (II) a divalent metal tungstate phosphor represented by the formula: M.sup.II WO.sub.4 where M II is at least one element selected from the group consisting of magnesium, calcium, zinc and cadmium; (III) a zinc sulfide or zinc-cadmium sulfide phosphor represented by the formula: (Zn.sub.1-j,Cd.sub.j)S:Ag where j is a number within the range of 0≦j≦0.4; and (IV) a rare earth tantalate or tantalum-niobate phosphor represented by the formula: (Ln".sub.1-v,Tm.sub.v)(Ta.sub.1-w,Nb.sub.w)O.sub.4 where Ln" is at least one element selected from the group consisting of lanthanum, yttrium, gadolinium and lutetium, and v and w are numbers within the ranges of 0≦v≦0.1 and 0≦w≦0.3, respectively; and (c) a second fluorescent layer formed on said first fluorescent layer and consisting essentially of a green emitting rare earth oxysulfide phosphor represented by the formula: (Ln.sub.1-a-b,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and a and b are numbers within the ranges of 0.0005≦a≦0.09 and 0≦b≦0.01, respectively, or the formula: (Y.sub.1-i-a-b,Ln.sub.i,Tb.sub.a,Tm.sub.b).sub.2 O.sub.2 S where Ln is at least one element selected from the group consisting of lanthanum, gadolinium and lutetium, and i, a and b are numbers within the ranges of 0.65≦i≦0.95, 0.0005≦a≦0.09 and 0≦b≦0.01, respectively.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1988-03-25	1988-09-24	1989-03-26	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1992-03-25	1992-09-24	1993-03-26	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1996-03-25	1996-09-24	1997-03-26	$7700.00	Window Closed / Lapsed

Radiographic image conversion screens

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