US4507437A
Expired / Lapsed
US
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Curable composition
Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1983-12-23
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Granted: 1985-03-26
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Expires: 2003-12-23
Abstract
Abstract A moisture curable composition comprising (I) a hydrolyzable silyl group-containing vinyl polymer and (II) a combined curing catalyst system of (a) an organic phosphorus-containing compound such as an organic acid phosphate, an organic acid phosphite, or an acid titanium phosphate such as those known as titanate coupling agent and (b) an amine compound. The composition has well balanced pot life and curability and provides a cured product having an excellent appearance, and the curability can be arbitrarily controlled according to the purposes by selecting the ratio of the components (a) and (b).
Inventors
- 👤 Yasushi Kato
- 👤 Hisao Furukawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:03
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/52; C08K5/521
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
185 words
A curable composition comprising (I) a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer, and (II) a hardener containing (a) at least one organic phosphorus-containing compound having a P--OH linkage in the molecular and being selected from the group consisting of organic acid phosphates of the general formulas: ##STR8## wherein R 3 and R 4 are an organic group, m is 0 or 1, and x and y are 0, 1 or 2 provided that the sum of x and y is 1 or 2; organic acid phosphites of the general formulas: (R.sup.3 O).sub.x (R.sup.4 O).sub.y P(OH).sub.2-m and R.sub.x.sup.3 R.sub.y.sup.4 P(OH).sub.2-m wherein R 3 , R 4 , m, x and y are as defined above, and an organic acid titanium phosphate containing a ##STR9## linkage between organic groups and (b) an amine compound reactable with the at least one organic phosphorus-containing compound.
Claim 2
Dependent Claim
185 words
A curable composition comprising (I) a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer, and (II) a hardener containing (a) at least one organic phosphorus-containing compound having a P--OH linkage in the molecular and being selected from the group consisting of organic acid phosphates of the general formulas: ##STR8## wherein R 3 and R 4 are an organic group, m is 0 or 1, and x and y are 0, 1 or 2 provided that the sum of x and y is 1 or 2; organic acid phosphites of the general formulas: (R.sup.3 O).sub.x (R.sup.4 O).sub.y P(OH).sub.2-m and R.sub.x.sup.3 R.sub.y.sup.4 P(OH).sub.2-m wherein R 3 , R 4 , m, x and y are as defined above, and an organic acid titanium phosphate containing a ##STR9## linkage between organic groups and (b) an amine compound reactable with the at least one organic phosphorus-containing compound.
Claim 3
Dependent Claim
16 words
The composition of claim 1, wherein said amine compound (b) is a secondary or tertiary amine.
Claim 4
Dependent Claim
14 words
The composition of claim 1, wherein said amine compound (b) is an amino-substituted organoalkoxysilane.
Claim 5
Dependent Claim
23 words
The composition of claim 1, wherein said amine compound (b) is a reaction product of an amino-substituted organoalkoxysilane with an epoxy-containing silane compound.
Claim 6
Dependent Claim
31 words
The composition of claim 1, wherein said hardener (II) is present in an amount of 0.01 to 20 parts by weight per 100 parts by weight of the vinyl polymer (I).
Claim 7
Dependent Claim
23 words
The composition of claim 5, wherein the ratio of the component (b) to the component (a) is from 0.05 to 20 by equivalent.
Claim 8
Dependent Claim
101 words
A composition of claim 6, wherein said silyl group is represented by the following formula: ##STR10## wherein X is a hydrolyzable group selected from the group consisting of a halogen, an alkoxyl group, an alkoxyalkoxyl group, an acyloxyl group, a ketoxymate group, an amino group, an acid amide group, an aminoxy group, a mercapto group and an alkenyloxy group, R 1 and R 2 are hydrogen or a hydrocarbon group having 1 to 10 carbon atoms selected from the group consisting of an alkyl group, an aryl group and an aralkyl group, and n is an integer of 1 to 3.
Claim 9
Dependent Claim
18 words
A composition of claim 1, wherein said organic phosphorus-containing compound is selected from the group consisting of: ##STR11##
Claim 10
Dependent Claim
62 words
The composition of claim 8, wherein said amine compound is selected from the group consisting of methylamine, ethylamine, butylamine, hexylamine, laurylamine, hexamethylenediamine, ##STR12## aniline, diethylamine, dibutylamine, piperidine, piperazine, diethanolamine, triethylamine, tributylamine, N,N-dimethyldodecylamine, N,N-dimethylbenzylamine, N,N,N',N-tetramethyl-1,6-hexanediamine, triethylenediamine, triethanolamine, pyridine, diethylene-triamine, triethylenetetramine, tetraethylenepentamine, adducts of primary or secondary amines and epoxy compounds, γ-aminopropyltrimethoxysilane, γ-aminopropyltriethoxysilane, N-β-aminoethyl-γ-aminopropyltrimethoxysilane and reaction products of amino-substituted organoalkoxysilanes with epoxy-containing silane compounds.
Claim 11
Dependent Claim
19 words
A composition of claim 1, wherein said organic acid titanium phosphate is selected from the group consisting of ##STR13##
Claim 12
Dependent Claim
60 words
The composition of claim 1, wherein the amine compound is selected from the group consisting of a primary amine, a secondary amine, a tertiary amine, a polyfunctional amine compound containing primary and secondary amino groups, and adduct of primary or secondary amine and an epoxy compound, an amino-substituted organoalkoxysilane, and a reaction product of amino-substituted organoalkoxysilane and epoxy-containing silane compound.
Claim 13
Dependent Claim
35 words
The composition of claim 1, wherein the organic phosphorus-containing compound is selected from the group consisting of dioctylphosphate and dibutylphosphate and the amine compound is selected from the group consisting of N,N-dimethyldodecylamine, laurylamine and piperidine.
Claim 14
Dependent Claim
23 words
The composition of claim 1, wherein the ratio of the component (b) to the component (a) is from 0.05 to 20 by equivalent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-03-25 | 1988-09-24 | 1989-03-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-03-25 | 1992-09-24 | 1993-03-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-03-25 | 1996-09-24 | 1997-03-26 | $7700.00 | Window Closed / Lapsed |