US4504790A
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Apparatus and method for determining the water content of a water-containing mixture
Assignee: Schneider Electric Systems USA Inc
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Filing: 1981-10-05
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Granted: 1985-03-12
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Expires: 2001-10-05
Abstract
Abstract An apparatus for determining the proportion of water within a mixture of water and a water-miscible solvent includes means for increasing the electrical conductivity of the mixture in proportion to the amount of water contained therein. In a particular embodiment this is done by passing a component stream of the sample through a replenishable bed of a salt, which salt is easily soluble in water but is relatively insoluble in the solvent. The dissolving of the salt introduces an appreciable number of conductive ions into the mixture, thereby enhancing its overall conductivity. A conventional detecting scheme measures the enhanced conductivity of the mixture, and means is provided for correlating this conductivity measurement to the proportion of water within the mixture.
Inventors
- 👤 Martin S. Frant
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 22:30
CPC Classifications
G; G01; G01N; G01N33/00; G01N33/26; G01N33/28; G01N33/2835; G01N33/2847; G01N27/00; G01N27/02; G01N27/04; G01N27/06
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
117 words
Apparatus for determining the proportion of water within a mixture containing water and ethanol, comprising: a housing containing a bed of an ionizable, water-soluble salt, said salt being relatively insoluble in ethanol, relative to its solubility in water, and said housing having inlet and outlet ports to permit said mixture to flow through said salt; a spring-biased piston located within said housing and disposed to bear against said bed of salt, so as to keep said salt tightly compacted; means coupled to said outlet port for measuring the electrical conductivity of said mixture after it has flowed through said bed of salt; and means for relating the measured conductivity to the proportion of water in the mixture.
Claim 2
Dependent Claim
117 words
Apparatus for determining the proportion of water within a mixture containing water and ethanol, comprising: a housing containing a bed of an ionizable, water-soluble salt, said salt being relatively insoluble in ethanol, relative to its solubility in water, and said housing having inlet and outlet ports to permit said mixture to flow through said salt; a spring-biased piston located within said housing and disposed to bear against said bed of salt, so as to keep said salt tightly compacted; means coupled to said outlet port for measuring the electrical conductivity of said mixture after it has flowed through said bed of salt; and means for relating the measured conductivity to the proportion of water in the mixture.
Claim 3
Dependent Claim
39 words
Apparatus as set forth in claim 1, wherein said relating means comprises means for deriving from a conductivity-versus-water percentage calibration curve for the combination of said mixture and said salt a water percentage value corresponding to said measured conductivity.
Claim 4
Dependent Claim
14 words
Apparatus as set forth in claim 2, wherein said salt is potassium chloride (KCl).
Claim 5
Dependent Claim
14 words
Apparatus as set forth in claim 2, wherein said salt is sodium chloride (NaCl).
Claim 6
Dependent Claim
16 words
Apparatus as set forth in claim 2, wherein said salt is potassium nitrate (KNO 3 ).
Claim 7
Dependent Claim
65 words
Apparatus for determining the proportion of water within a mixture containing water, ethanol, and benzene, comprising: means for increasing the electrical conductivity of the mixture by introducing sodium-EDTA salt into the mixture, thereby increasing the ion population of the water; means for measuring the increased electrical conductivity of the mixture; and means for relating the measured conductivity to the proportion of water in the mixture.
Claim 8
Dependent Claim
65 words
Apparatus for determining the proportion of water within a mixture containing water, ethanol, and benzene, comprising: means for increasing the electrical conductivity of the mixture by introducing sodium-EDTA salt into the mixture, thereby increasing the ion population of the water; means for measuring the increased electrical conductivity of the mixture; and means for relating the measured conductivity to the proportion of water in the mixture.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-03-11 | 1988-09-10 | 1989-03-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-03-11 | 1992-09-10 | 1993-03-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-03-11 | 1996-09-10 | 1997-03-12 | $7700.00 | Window Closed / Lapsed |