US4504573A
Expired / Lapsed
US
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Photopolymerizable compositions
Assignee: Fujifilm Holdings Corp
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Filing: 1984-03-22
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Granted: 1985-03-12
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Expires: 2004-03-22
Abstract
Abstract A high sensitivity photopolymerizable composition is disclosed. The composition includes a polymerizable compound having an ethylenically unsaturated bond and a photopolymerizable initiator represented by the general formula (I). ##STR1## The substituents within general formula (I) are defined within the specification. The composition has improved sensitivity and the initiator provides an increased polymerization rate. The composition may further include Michler's ketone and a N-methyl-2-benzoyl-β-naphthothiazolin.
Inventors
- 👤 Shun-ichi Ishikawa
- 👤 Teruo Nagano
- 👤 Koji Tamoto
- 👤 Fumiaki Shinozaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:36
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/116; Y10S430/12; Y10S430/121; Y10S430/122; Y10S430/127
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
193 words
A photopolymerizable composition comprising a polymerizable compound having an ethylenically unsaturated bond and a photopolymerization initiator represented by general formula (I) ##STR10## wherein R 1 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; R 2 represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a heterocyclic ring, or a substituted heterocyclic ring; R 3 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; R 4 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a cyano group, a halogen atom, an alkoxy group, or an alkoxycarbonyl group; and R 5 , R 6 , R 7 and R 8 are independently a hydrogen atom, an alkyl group, or a substituted alkyl group, an aryl group, a substituted aryl group, a halogen atom, or an alkoxy group; or said R 5 and R 6 , said R 6 and R 7 , or said R 7 and R 8 are capable of combining with each other to form a benzene ring.
Claim 2
Dependent Claim
193 words
A photopolymerizable composition comprising a polymerizable compound having an ethylenically unsaturated bond and a photopolymerization initiator represented by general formula (I) ##STR10## wherein R 1 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; R 2 represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a heterocyclic ring, or a substituted heterocyclic ring; R 3 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; R 4 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a cyano group, a halogen atom, an alkoxy group, or an alkoxycarbonyl group; and R 5 , R 6 , R 7 and R 8 are independently a hydrogen atom, an alkyl group, or a substituted alkyl group, an aryl group, a substituted aryl group, a halogen atom, or an alkoxy group; or said R 5 and R 6 , said R 6 and R 7 , or said R 7 and R 8 are capable of combining with each other to form a benzene ring.
Claim 3
Dependent Claim
71 words
A photopolymerizable composition as claimed in claim 1, wherein the alkyl group and the alkyl groups for the substituted alkyl group represented by R 1 , R 2 , R 3 and R 4 contain 1 to 8 carbon atoms, the aryl group and the aryl groups for the substituted aryl group represented by R 1 , R 2 , R 3 and R 4 contain 6 to 12 carbon atoms.
Claim 4
Dependent Claim
72 words
A photopolymerizable composition as claimed in claim 1, wherein the alkyl group and the alkyl group for the substituted alkyl group represented by R 5 , R 6 , R 7 and R 8 contain 1 to 2 carbon atoms and the aryl group and the aryl group for the substituted aryl group represented by R 5 , R 6 , R 7 and R 8 contain 6 to 12 carbon atoms.
Claim 5
Dependent Claim
42 words
A photopolymerizable composition as claimed in claim 1, wherein the substituent for the substituted alkyl group of R 1 , R 2 , R 3 and R 4 is a halogen atom or an alkoxy group having 1 to 2 carbon atoms.
Claim 6
Dependent Claim
51 words
A photopolymerizable composition as claimed in claim 1, wherein the substituent for the substituted aryl group of R 1 , R 2 , R 3 and R 4 is an alkyl group having 1 to 2 carbon atoms, an alkoxy group having 1 to 2 carbon atoms or a halogen atom.
Claim 7
Dependent Claim
39 words
A photopolymerizable composition as claimed in claim 1, wherein the alkoxy group represented by R 4 and R 5 contains 1 to 2 carbon atoms and the alkoxycarbonyl group represented by R 4 contains 2 to 3 carbon atoms.
Claim 8
Dependent Claim
57 words
A photopolymerizable composition as claimed in claim 1, wherein the heterocyclic ring of R 2 is a monocyclic ring containing O or S as a hetero-atom and the substituent for the substituted heterocyclic ring of R 2 is an alkyl group having 1 to 2 carbon atoms or an alkoxy group having 1 to 2 carbon atoms.
Claim 9
Dependent Claim
19 words
A photopolymerizable composition as claimed in claim 1, wherein the R 2 of the initiator is a monocyclic ring.
Claim 10
Dependent Claim
19 words
A photopolymerizable composition as claimed in claim 1, wherein the R 3 of the initiator is an alkyl group.
Claim 11
Dependent Claim
31 words
A photopolymerizable composition as claimed in claim 1, wherein the R 5 , R 6 , R 7 and R 8 independently represent alkyl groups containing 1 to 2 carbon atoms.
Claim 12
Dependent Claim
48 words
A photopolymerizable composition as claimed in claim 1, wherein the polymerizable compound is a compound selected from the group consisting of unsaturated carboxylic acids, salts of unsaturated carboxylic acids, esters of unsaturated carboxylic acids and aliphatic polyhydric alcohols, amides of unsaturated carboxylic acids and aliphatic polyvalent amine compounds.
Claim 13
Dependent Claim
12 words
A photopolymerizable composition as claimed in claim 1, further comprising a sensitizer.
Claim 14
Dependent Claim
15 words
A photopolymerizable composition as claimed in claim 12 wherein, the sensitizer is a merocyanine dye.
Claim 15
Dependent Claim
14 words
A photopolymerizable composition as claimed in claim 12, wherein the sensitizer is Michler's ketone.
Claim 16
Dependent Claim
13 words
A photopolymerizable composition as claimed in claim 12, wherein the sensitizer is N-methyl-2-benzoyl-β-naphthothiazoline.
Claim 17
Dependent Claim
34 words
A photopolymerizable composition as claimed in claim 1, wherein the photopolymerization initiator is used in an amount of 0.01 to 50 parts by weight based on 100 parts by weight of the polymerizable compound.
Claim 18
Dependent Claim
32 words
A photopolymerizable composition as claimed in claim 1, wherein sensitizer is present in an amount of 0 to 100 parts by weight based on 100 parts by weight of the polymerizable compound.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-03-11 | 1988-09-10 | 1989-03-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-03-11 | 1992-09-10 | 1993-03-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-03-11 | 1996-09-10 | 1997-03-12 | $7700.00 | Window Closed / Lapsed |