US4501856A
Expired / Lapsed
US
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Composite containing polyolefin fiber and polyolefin polymer matrix
Assignee: Honeywell International Inc
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Filing: 1982-03-19
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Granted: 1985-02-26
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Expires: 2002-03-19
Abstract
Abstract A composite containing a network of ultrahigh molecular weight polyethylene or polypropylene fibers of high tenacity and modulus and a matrix which has ethylene or propylene crystallinity, e.g. polyethylene, polypropylene or copolymers. The composite can be formed by heating the matrix to its melting or sticking temperature around the fibers. The composite retains a high proportion of the tenacity of the fiber.
Inventors
- 👤 Gary A. Harpell
- 👤 Sheldon Kavesh
- 👤 Igor Palley
- 👤 Dusan C. Prevorsek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 19:05
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; C; C08; C08J; C08J5/00; C08J5/04; C08L; C08L23/00; C08L23/02; C08J2323/00; C08J2323/02; Y; Y10; Y10S; Y10S428/00; Y10S428/911; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/249942; Y10T428/249947
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
130 words
A composite structure comprising: (a) a network of polyolefin fibers selected from the group consisting of polyethylene and polypropylene fibers having a weight average molecular weight of at least about 500,000, a tenacity of at least about 15 g/denier and a main melting point of at least about 140° C. for polyethylene fiber, and a tenacity of at least about 11 g/denier and a main melting point of at least about 168° C. for polypropylene fiber; and (b) a matrix comprising a polymer having polyethylene or polypropylene crystallinity with a melting or sticking point at least 3° C. lower than the melting point of the polyolefin fiber; said composite structure having a tenacity at least 75% of the volume average tenacity of the polyolefin fiber network and the polymer matrix.
Claim 2
Dependent Claim
130 words
A composite structure comprising: (a) a network of polyolefin fibers selected from the group consisting of polyethylene and polypropylene fibers having a weight average molecular weight of at least about 500,000, a tenacity of at least about 15 g/denier and a main melting point of at least about 140° C. for polyethylene fiber, and a tenacity of at least about 11 g/denier and a main melting point of at least about 168° C. for polypropylene fiber; and (b) a matrix comprising a polymer having polyethylene or polypropylene crystallinity with a melting or sticking point at least 3° C. lower than the melting point of the polyolefin fiber; said composite structure having a tenacity at least 75% of the volume average tenacity of the polyolefin fiber network and the polymer matrix.
Claim 3
Dependent Claim
29 words
The composite structure of claim 1 comprising between about 5 and about 99 weight % polyolefin fiber network and between about 1 and about 95 weight % polymer matrix.
Claim 4
Dependent Claim
15 words
The composite structure of claim 1 or 2 wherein said polyolefin fiber is polyethylene fiber.
Claim 5
Dependent Claim
14 words
The composite structure of claim 3 wherein said polymer matrix is an ethylene copolymer.
Claim 6
Dependent Claim
13 words
The composite structure of claim 3 wherein said polymer matrix is polyethylene polymer.
Claim 7
Dependent Claim
16 words
The composite structure of claim 5 wherein said polyethylene polymer has a specific gravity of 0.90-0.94.
Claim 8
Dependent Claim
16 words
The composite structure of claim 5 wherein said polyethylene polymer has a specific gravity of 0.94-0.98.
Claim 9
Dependent Claim
42 words
The composite structure of claim 5 wherein said polyethylene fiber has a main melting point at 10° C./min between about 140° C. and about 151° C. and said polyethylene polymer has a melting point between about 108° C. and about 126° C.
Claim 10
Dependent Claim
26 words
The composite structure of claim 5 wherein said polyethylene polymer has a main melting point at 10° C./min between about 126° C. and about 136° C.
Claim 11
Dependent Claim
28 words
The composite structure of claim 5 having a tensile strength at least 90% of the volume average tenacity of the polyethylene fiber network and the polyethylene polymer matrix.
Claim 12
Dependent Claim
40 words
The composite structure of claim 5 wherein said polyethylene fiber has a weight average molecular weight of at least about 1,000,000 a tenacity of at least about 25 g/denier and a tensile modulus of at least about 750 g/ denier.
Claim 13
Dependent Claim
29 words
The composite structure of claim 11 wherein said polyethylene fiber has a tenacity of at least about 30 g/denier and a tensile modulus of at least about 1000 g/denier.
Claim 14
Dependent Claim
26 words
The composite structure of claim 1 having about 0.1 to about 99 volume percent fiber network and about 99.9 to about 1 volume percent polymer matrix.
Claim 15
Dependent Claim
16 words
The composite structure of claim 13 having about 1 to about 95 volume percent fiber network.
Claim 16
Dependent Claim
16 words
The composite structure of claim 14 having about 40 to about 90 volume percent fiber network.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-26 | 1988-08-27 | 1989-02-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-26 | 1992-08-27 | 1993-02-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-26 | 1996-08-27 | 1997-02-26 | $7700.00 | Window Closed / Lapsed |