US4500660A
Expired / Lapsed
US
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Epoxy resin composition
Assignee: NIPPON GIJUTSU BOEKI CO Ltd
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Filing: 1983-04-18
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Granted: 1985-02-19
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Expires: 2003-04-18
Abstract
Abstract An epoxy resin composition having excellent adhesive and high mechanical strength is disclosed. The composition comprises: (A) a bisphenol A type epoxy resin present in an amount of at least 45 wt % of the total epoxy resin; (B) a novolak type epoxy resin present in an amount of at least 8 wt % of the total epoxy resin; (C) a glycidyl amine type epoxy resin (including the one used in (D)) present in an amount of at least 15 wt % of the total epoxy resin; (D) a reaction product of a butadiene-acrylonitrile copolymer having carboxyl groups on at least both ends of the molecule and a glycidyl amine type epoxy resin, said butadiene-acrylonitrile copolymer being present in an amount of 1.5 to 15 parts by weight per 100 parts by weight of the total epoxy resin; (E) nitrile rubber present in an amount of 2 to 8 parts by weight per 100 parts by weight of the total epoxy resin; wherein the total epoxy resin is the total amount of epoxy resins (A), (B) and (C), as well as the glycidyl amine type epoxy resin used in preparing component (D); (F) a curing agent consisting of dicyandiamide; (G) a curing accelerator, and (H) a reinforcing fiber to form a composition which exhibits good performance when it is used as a prepreg for composite.
Inventors
- 👤 Tsuyoshi Minamisawa
- 👤 Yasuo Kogo
- 👤 Yasuhisa Nagata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 09:31
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/02; C08G59/12; C08G59/18; C08G59/20; C08G59/22; C08G59/226; C08G59/32; C08G59/38; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/243; C08L; C08L63/00; C08J2363/00; Y; Y10; Y10S; Y10S525/00; Y10S525/911
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
233 words
An epoxy resin composition comprising: (A) a condensation product of bisphenol A and epichlorohydrine present in an amount of at least 45 wt % of the total epoxy resin (B) a reaction product of novolak resin and epichlorohydrine present in an amount of at least 8 wt % of the total epoxy resin; (C) an epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin (including the one used in (D)) present in an amount of at least 15 wt % of the total epoxy resin; (D) a reaction product of a butadiene-acrylonitrile copolymer having carboxyl groups on at least both ends of the molecule and an epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin, said butadiene-acrylonitrile copolymer being present in an amount of 1.5 to 15 parts by weight per 100 parts by weight of the total epoxy resin; (E) nitrile rubber present in an amount of 2 to 8 parts by weight per 100 parts by weight of the total epoxy resin; wherein the total epoxy resin is the total amount of epoxy resins (A), (B) and (C), as well as the epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin used in preparing component (D); (F) a curing agent consisting of dicyandiamide; (G) a curing accelerator, and (H) a reinforcing carbon fiber.
Claim 2
Dependent Claim
233 words
An epoxy resin composition comprising: (A) a condensation product of bisphenol A and epichlorohydrine present in an amount of at least 45 wt % of the total epoxy resin (B) a reaction product of novolak resin and epichlorohydrine present in an amount of at least 8 wt % of the total epoxy resin; (C) an epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin (including the one used in (D)) present in an amount of at least 15 wt % of the total epoxy resin; (D) a reaction product of a butadiene-acrylonitrile copolymer having carboxyl groups on at least both ends of the molecule and an epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin, said butadiene-acrylonitrile copolymer being present in an amount of 1.5 to 15 parts by weight per 100 parts by weight of the total epoxy resin; (E) nitrile rubber present in an amount of 2 to 8 parts by weight per 100 parts by weight of the total epoxy resin; wherein the total epoxy resin is the total amount of epoxy resins (A), (B) and (C), as well as the epoxy resin having at least one N,N-diglycidylamine group in a molecule of the epoxy resin used in preparing component (D); (F) a curing agent consisting of dicyandiamide; (G) a curing accelerator, and (H) a reinforcing carbon fiber.
Claim 3
Dependent Claim
31 words
An epoxy resin composition as claimed in claim 1 wherein the condensation product of bisphenol A and epichlorohydrine is nonbrominated and has an average epoxy equivalent of from 150 to 1,000.
Claim 4
Dependent Claim
30 words
An epoxy resin composition as claimed in claim 1 wherein the condensation product of bisphenol A and epichlorohydrine is brominated and has an average epoxy equivalent of 200 to 600.
Claim 5
Dependent Claim
41 words
An epoxy resin composition as claimed in claim 1 wherein the reaction product of novolak resin and epichlorohydrine further comprises at least one resin selected from the group consisting of a phenolic novolak epoxy resin and a cresol novolak epoxy resin.
Claim 6
Dependent Claim
24 words
An epoxy resin composition as claimed in claim 4 wherein the phenolic novolak resin has an average epoxy equivalent of from 160 to 200.
Claim 7
Dependent Claim
24 words
An epoxy resin composition as claimed in claim 4 wherein the cresol novolak epoxy resin has an epoxy equivalent of from 180 to 260.
Claim 8
Dependent Claim
25 words
An epoxy resin composition as claimed in claim 1 wherein the glycidylamine type epoxy resin has at least one N,N-diglycidylamino group in a molecule thereof.
Claim 9
Dependent Claim
32 words
An epoxy resin composition as claimed in claim 1 wherein the epoxy resin having at least one N,N-diglycidylamino group in a molecule has an average epoxy equivalent of from 110 to 150.
Claim 10
Dependent Claim
39 words
An epoxy resin composition as claimed in claim 1, wherein the epoxy resin having at least one N,N-diglycidylamino group in a molecule is a resin selected from the group consisting of N,N,N',N'-tetraglycidyldiaminodiphenylmethane N,N-diglycidylmethaaminophenol glycidyl ether and N,N-diglycidylparaaminophenol glycidyl ether.
Claim 11
Dependent Claim
18 words
An epoxy resin composition as claimed in claim 1 wherein the butadiene-acrylonitrile copolymer in component (D) is liquid.
Claim 12
Dependent Claim
24 words
An epoxy resin composition as claimed in claim 10 wherein said copolymer has a viscosity of from 500 to 8,000 poise at 27° C.
Claim 13
Dependent Claim
24 words
An epoxy resin composition as claimed in claim 1 wherein the butadiene-acrylonitrile copolymer has an acrylonitrile content of from 10 to 35 wt %.
Claim 14
Dependent Claim
34 words
An epoxy resin composition as claimed in claim 1 wherein the nitrile rubber has a Mooney viscosity of 40 to 110 at 100° C. and an acrylonitrile content of 20 to 45 wt %.
Claim 15
Dependent Claim
41 words
An epoxy resin composition as claimed in claim 1 wherein the nitrile rubber is a carboxyl modified nitrile rubber having not more that 2 wt % of at least one acid selected from the group consisting acrylic acid and methacrylic acid.
Claim 16
Dependent Claim
29 words
An epoxy resin composition as claimed in claim 1, wherein said bisphenol A is contained in an amount of 45 to 65 wt % of the total epoxy resin.
Claim 17
Dependent Claim
34 words
An epoxy resin composition as claimed in claim 1, wherein said reaction product of novolak resin and epichlorohydrine is contained in an amount of 8 to 30 wt % of the total epoxy resin.
Claim 18
Dependent Claim
38 words
An epoxy resin composition as claimed in claim 1, wherein said epoxy resin having at least one N,N-diglycidylamino group in a molecule is contained in an amount of 15 to 35 wt % of the total epoxy resin.
Claim 19
Dependent Claim
41 words
An epoxy resin composition as claimed in claim 1, wherein said condensation product of bisphenol A and epichlorohydrine further comprises 25-70 wt % of a non-brominated bisphenol A epoxy resin and 75-30 wt % of a brominated bisphenol A epoxy resin.
Claim 20
Dependent Claim
33 words
An epoxy resin composition as claimed in claim 1 wherein said dicyandiamide is used in an amount of 2 to 8 parts by weight per 100 parts by weight of the resin composition.
Claim 21
Dependent Claim
34 words
An epoxy resin composition as claimed in claim 1 wherein the accelerator is used in an amount of from 2 to 8 parts by weight per 100 parts by weight of the resin composition.
Claim 22
Dependent Claim
28 words
An epoxy resin composition as claimed in claim 1 which contains fine particles of at least one of materials selected from the group consisting silica and glass particles.
Claim 23
Dependent Claim
15 words
An epoxy resin composition as claimed in claim 1 which contains fine antimony trioxide particles.
Claim 24
Dependent Claim
16 words
An epoxy resin composition as claimed in claim 1 which contains at least one metal borate.
Claim 25
Dependent Claim
17 words
An epoxy resin composition as claimed in claim 1 which contains at least one flow controlling agent.
Claim 26
Dependent Claim
32 words
An epoxy resin composition as claimed in claim 1, wherein the fiber is contained in an amount of 40 to 80 wt % based on the total weight of the resin composition.
Claim 27
Dependent Claim
26 words
An epoxy resin composition as claimed in claim 1, wherein said reaction product of novolak resin and epichlorohydrine has a molecular weight of 400 to 900.
References Cited (Backward Citations)
US3894113A
Cited
US3655818A
Cited
US3894112A
Cited
US3707583A
Cited
US3926904A
Cited
JPS53102996A
Cited
JPS5721450A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-19 | 1988-08-20 | 1989-02-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-19 | 1992-08-20 | 1993-02-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-19 | 1996-08-20 | 1997-02-19 | $7700.00 | Window Closed / Lapsed |